Abstract
Recent studies suggest that emissions, heterogeneous reactions, and surface photolysis of adsorbed nitric acid may produce additional nitrous acid in the atmosphere. The effects of these sources on nitrous acid formation are evaluated using the Community Multiscale Air Quality modeling system. Predicted nitrous acid with and without these sources are compared with observed data from northeast Philadelphia. The incorporation of these sources greatly improves the model performance for nitrous acid. It also increases the average hydroxyl radical and ozone by 10% and 1.7 ppbv, respectively.
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References
Acker K, Möller D, Wieprecht W, Meixner FX, Bohn B, Gilge S, Plass-Dülmer C, Berresheim H (2006) Strong daytime production of OH from HNO2 at a rural mountain site, Geophys. Res. Lett., 33, L02809, doi:10.1029/2005GL024643.
Alicke B, Platt U, Stutz J (2002) Impact of nitrous acid photolysis on the total hydroxyl radical budget during the limitation of oxidant production/Pianura Padana Produzione di Ozono study in Milan, Â J. Geophys. Res., 107, Â doi:10.1029/2000JD000075.
Alicke B, Geyer A, Hofzumahaus A, Holland F, Konrad S, Pätz HW, Schäfer J, Stutz J, Volz-Thomas A, Platt U (2003) OH formation by HONO photolysis during the BERLIOZ experiment, J. Geophys. Res.,  108,  8247, doi:10.1029/ 2001JD000579.
Aumont B, Chervier F, Laval S (2003) Contribution of HONO sources to the NOx/HOx/O3 chemistry in the polluted boundary layer, Atmos. Environ., 37, 487-498.
Binkowski FS, Roselle SJ (2003) Community Multiscale Air Quality (CMAQ) model aerosol component, I: Model description, J. Geophys. Res., Â 108(D6): 4183, doi:10.1029/2001JD001409.
Byun D, Schere KL (2006) Review of the governing equations, computational algorithms, and other components of the Models-3 Community Multiscale Air Quality (CMAQ) modeling system, Appl. Mech. Rev., 59, 51-77.
Cai C, Hogrefe C, Schwab JJ, Katsafados P, Kallos G, Ren X, Brune WH, Zhou X, He Y, Demerjian KL (2007) Performance evaluation of an air quality forecast modeling system for a summer and winter season - Part II: HONO formation processes and their implications for HOx budgets, J. Geophys. Res., in review.
Carter, WPL (2000) Implementation of the SAPRC-99 chemical mechanism into the Models-3 Framework, report to the United States Environmental Protection Agency. Available at http://www.cert.ucr.edu/∼carter/absts.htm#s99mod3
Finlayson-Pitts BJ, Pitts JN Jr (2000) Chemistry of the Upper Lower Atmosphere, Theory, Experiments and Applications, Academic, San Diego, CA.
Gery MW, Whitten GZ, Killus JP, Dodge MC (1989) A photochemical kinetics mechanism for urban and regional scale computer modeling. J. Geophys. Res., 94 (D10), 12925-12956.
Grell G, Dudhia J, Stauffer D (1994) A description of the fifth-generation Penn State/NCAR Mesoscale model (MM5), NCAR Tech. Note NCAR/TN-398+STR.
Jones MR (2006) Ammonia deposition to semi-natural vegetation, PhD dissertation, University of Dundee, Scotland.
Kirchstetter TW, Â Littlejohn D (1996) Measurements of nitrous acid in motor vehicle exhaust, Environ. Sci. Technol., 30, 2843-2849.
Kurtenbach R, Becker KH, Gomes JAG, Kleffmann J, Lorzer JC, Spittler M, Wiesen P, Ackermann R, Geyer A, Platt U (2001) Investigations of emissions and heterogeneous formation of HONO in a road traffic tunnel, Atmos. Environ., 35, 3385-3394.
Pleim JE (2007) A combined local and nonlocal closure model for the atmospheric boundary layer. part I: model description and testing, J. Appl. Meteor. Clim., 46, 1383-1395.
Sarwar G, Luecken V, Yarwood G, Whitten G, Carter WPL (2007) Impact of an updated carbon bond mechanism on predictions from the Community Multiscale Air Quality (CMAQ) modeling system: preliminary assessment, J. Appl. Meteor. Clim., accepted.
Svensson R, Ljungstrom E, Lindqvist O (1987) Kinetics of the reaction between nitrogen dioxide and water vapour, Atmos. Environ., 21, 1529-1539.
Vogel B, Vogel H, Kleffmann J, Kurtenbach R (2003) Measured and simulated vertical profiles of nitrous acid - Part II, model simulations and indications for a photolytic source, Atmos. Environ., 37, 2957-2966.
Winer AM, Biermann HW (1994) Long pathlength differential optical absorption spectroscopy (DOAS) measurements of gaseous HONO, NO2 and HCHO in the California South Coast Air Basin. Res. Chem. Intermed., 20, 423-445.
Yarwood G, Rao S, Yocke M, Whitten G (2005) Updates to the Carbon Bond Chemical Mechanism: CB05, Â Final Report to the US EPA, Â RT-0400675, Available at http://www.camx.com/publ/pdfs/CB05_Final_Report_120805.pdf
Zhou X, Â Civerolo K, Â Dai H, Â Huang G, Â Schwab JJ, Â Demerjian KL (2002) Summertime nitrous acid chemistry in the atmospheric boundary layer at a rural site in New York State, Â J. Geophys. Res., 107 (D21), 4590, Â doi:10.1029/ 2001JD001539.
Zhou X, Gao H, He Y, Huang G, Bertman SB, Civerolo K, Schwab J (2003) Nitric acid photolysis on surfaces in low-NOx environments: significant atmospheric implications, Geophys. Res. Lett., 30(23), 2217, doi:10.1029/2003GL018620.
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Sarwar, G., Dennis, R.L., Vogel, B. (2008). The Effect of Heterogeneous Reactions on Model Performance for Nitrous Acid. In: Borrego, C., Miranda, A.I. (eds) Air Pollution Modeling and Its Application XIX. NATO Science for Peace and Security Series Series C: Environmental Security. Springer, Dordrecht. https://doi.org/10.1007/978-1-4020-8453-9_38
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DOI: https://doi.org/10.1007/978-1-4020-8453-9_38
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