Skip to main content
SpringerLink
Log in

Carbosilane Dendrimers

  • Chapter
Silicon-Containing Dendritic Polymers

Part of the book series: Advances in Silicon Science ((ADSS,volume 2))

The concept of highly symmetrical, perfectly branched macromolecules prepared in a generational fashion was introduced in 1978 [1]. The synthesis of polylysine dendrimers [2] and the seminal research by Tomalia and Newkome in the mid-1980s established that such molecules could indeed be prepared [3, 4]. Tomalia et al. used trifunctional nitrogen branch points and Newkome chose tetrafunctional carbon branch points. These dendrimers contained ether, ester, amine and amide polar bonds

Carbosilane dendrimers with a silicon branch point in an exclusively carbon–silicon skeleton are non-polar, inert, neutral and thermally and hydrolytically stable compounds. The absence of polar bonds facilitates the use of many derivatization reactions and creates the possibility of strong physico-chemical contrast between the core and the outer corona. The synthesis of carbosilane dendrimers is almost always by a divergent process from the core to the interior generations and to the periphery, with the number of reactions per dendrimer increasing geometrically with each generation (see Chapter 1). The divergent synthesis of carbosilane dendrimers consists of the generational repetition of a sequence of two clean, high-yield reactions: (a) hydrosilylation and (b) nucleophilic substitution by Grignard or organolithium reagents. The hydrosilylation reaction 3.1 introduces the branch juncture and creates the next generation

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Log in via an institution
Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 129.00
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 169.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 169.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. Buhleier E, Wehner W, Vögtle F (1978) Synthesis 155–158

    Google Scholar 

  2. Denkewalter RG, Kolc J, Lukasavage WJ (1981) US Patent 4,289,872

    Google Scholar 

  3. Tomalia DA, Baker H, Dewald J, Hall M, Kallos G, Martin S, Roeck J, Ryder J, Smith P (1985) Polym J (Tokyo) 17: 117–132

    CAS  Google Scholar 

  4. Newkome GR, Yao ZQ, Baker GR, Gupta VK (1985) J Org Chem 50: 2003–2004

    Article  CAS  Google Scholar 

  5. Hadjichristidis N, Guyot A, Fetters LJ (1978) Macromolecules 11: 668–672

    Article  CAS  Google Scholar 

  6. Hadjichristidis N, Fetters LJ (1980) Macromolecules 13: 191–193

    Article  CAS  Google Scholar 

  7. Zhou LL, Roovers J (1993) Macromolecules 26: 963–968

    Article  CAS  Google Scholar 

  8. van der Made AW, van Leeuwen PWNM (1992) J Chem Soc Chem Commun 1400–1401

    Google Scholar 

  9. van der Made AW, van Leeuwen PWNM, de Wilde JC, Brandes RAC (1993) Adv Mat 5: 466–468

    Article  Google Scholar 

  10. Muzafarov AM, Gorbatsevich OB, Rebrov EA, Ignat'eva GM, Chenskaya TB, Myakushev VD, Bulkin AF, Papkov VS (1993) Polym Sci (USSR) 35: 1575–1580

    Google Scholar 

  11. Ignat'eva GM, Rebrov EA, Myakushev VD, Muzafarov AM, Il'ina MN, Dubovik II, Papkov VS (1997) Polym Sci Ser A 39: 874–881

    Google Scholar 

  12. Schlenk C, Frey H (1999) Monatsh Chem 130: 3–14

    CAS  Google Scholar 

  13. Frey H, Schlenk C (2000) Top Curr Chem 210: 70–123

    Google Scholar 

  14. Majoral JP, Caminade AM (1999) Chem Rev 99: 845–880

    Article  CAS  Google Scholar 

  15. Lukevics E, Arsenyan P, Pudova O (2002) Main Group Metal Chem 25: 135–154

    CAS  Google Scholar 

  16. Cuadrado I, Morán M, Losada J, Casado CM, Pascual C, Alonso B, Lobete F (1996) In: Newkome GR (ed) Advances in Dendritic Macromolecules, vol. 3, JAI Press, Greenwich, CT, pp. 151–195

    Chapter  Google Scholar 

  17. Krska SW, Son DY, Seyferth D (2000) In: Jones RG, Ando W, Chojnowski J (eds) Silicon-Containing Polymers, Kluwer, Dordrecht, pp. 615–641

    Google Scholar 

  18. Roovers J, Toporowski PM, Zhou LL (1992) Polym Preprints 33(1): 182–183

    CAS  Google Scholar 

  19. Allgaier J, Martin K, Räder HJ, Müllen K (1999) Macromolecules 32: 3190–3194

    Article  CAS  Google Scholar 

  20. Munam A (2007) Ph.D. thesis, University of Waterloo, Waterloo Ontario, Canada

    Google Scholar 

  21. Seyferth D, Son DY, Rheingold AL, Ostrander RL (1994) Organometallics 13: 2682–2690

    Article  CAS  Google Scholar 

  22. Lorenz K, Mülhaupt R, Frey H, Rapp U, Mayer-Posner FJ (1995) Macromolecules 28: 6657–6661

    Article  CAS  Google Scholar 

  23. Kim C, Park E, Kang E (1995) J Korean Chem Soc 39: 799–805

    CAS  Google Scholar 

  24. Kim C, Park E, Kang E (1996) Bull Korean Chem Soc 17: 592–595

    CAS  Google Scholar 

  25. Kim C, Jeong Y (1998) Main Group Met Chem 21: 593–599

    CAS  Google Scholar 

  26. Kim C, An K (1997) Bull Korean Chem Soc 18: 164–170

    CAS  Google Scholar 

  27. Kim C, Choi SK (1997) Main Group Met Chem 20: 143–150

    CAS  Google Scholar 

  28. Kim C, An K (1997) J Organomet Chem 547: 55–63

    Article  CAS  Google Scholar 

  29. Kim C, Park E (1998) J Korean Chem Soc 42: 277–284

    CAS  Google Scholar 

  30. Zhang X, Haxton KJ, Ropartz L, Cole-Hamilton DJ, Morris RE (2001) Dalton Trans 3261–3268

    Google Scholar 

  31. Kim C, Kim M (1998) J Organomet Chem 563: 43–51

    Article  CAS  Google Scholar 

  32. Kim C, Jeong K, Jung I (2000) J Polym Sci Part A: Polym Chem 38: 2749–2759

    Article  CAS  Google Scholar 

  33. Hawker CJ, Fréchet JMJ (1990) J Am Chem Soc 112: 7638–7647

    Article  CAS  Google Scholar 

  34. van Heerbeek R, Reek JNH, Kamer PCJ, van Leeuwen PWNM (1999) Tetrahedron Lett 40: 7127–7130

    Article  Google Scholar 

  35. Krasovskii VG, Sadovskii NA, Gorbatsevich OB, Muzafarov AM, Myakushev VD, Il'ina MN, Dubovik II, Strelkova TV, Papkov VS (1994) Polym Sci (USSR) 36: 589–594

    Google Scholar 

  36. Sluch MI, Scheblykin IG, Varnavsky OP, Vitukhnovsky AG, Krasovskii VG, Gorbatsevich OB, Muzafarov AM (1998) J Lumin 76–77: 246–251

    Article  Google Scholar 

  37. Kim C, Sung DD, Chung DI, Park E, Kang E (1995) J Korean Chem Soc 39: 789–798

    CAS  Google Scholar 

  38. Kim C, Kwon A (1998) Main Group Met Chem 21: 9–12

    CAS  Google Scholar 

  39. Tuchbreiter A, Werner H, Gade LH (2005) Dalton Trans 1394–1402

    Google Scholar 

  40. Andrés R, de Jesús E, de la Mata FJ, Flores JC, Gómez R (2005) Eur J Inorg Chem 3742–3749

    Google Scholar 

  41. Meder MB, Haller I, Gade LH (2005) Dalton Trans 1403–1415

    Google Scholar 

  42. Gossage RA, Muñoz-Martýnez E, van Koten G (1998) Tetrahedron Lett 39: 2397–2400

    Article  CAS  Google Scholar 

  43. Gossage RA, Muñoz-Martýnez E, Frey H, Burgath A, Lutz M, Spek AL, van Koten G (1999) Chem Eur J 5: 2191–2197

    Article  CAS  Google Scholar 

  44. Botman PNM, David O, Amore A, Dinkelaar J, Vlaar MT, Goubitz JF, Schenk H, Hiemstra H, van Maarseveen JH (2004) Angew Chem Int Ed 43: 3471–3473

    Article  CAS  Google Scholar 

  45. van Heerbeek R, Kamer PCJ, van Leeuwen PWNM, Reek JNH (2006) Org Biomol Chem 4: 211–223

    Article  CAS  Google Scholar 

  46. Oosterom GE, van Haaren RJ, Reek JNH, Kamer PCJ, van Leeuwen PWNM (1999) Chem Commun 1119–1120

    Google Scholar 

  47. Müller C, Ackerman LJ, Reek JNH, Kamer PCJ, van Leeuwen PWNM (2004) J Am Chem Soc 126: 14960–14963

    Article  CAS  Google Scholar 

  48. Oosterom GE, Steffens S, Reek JNH, Kamer PCJ, van Leeuwen PWNM (2002) Top Catal 19: 61–73

    Article  CAS  Google Scholar 

  49. Amore A, van Heerbeek R, Zeep N, van Esch J, Reek JNH, Hiemstra H, van Maarseveen JH (2006) J Org Chem 71: 1851–1860

    Article  CAS  Google Scholar 

  50. Marciniec B, Gulinski J et al. (1992) In: Marciniec B (ed) Comprehensive Handbook on Hydrosilylation, Pergamon, Oxford

    Google Scholar 

  51. Ojima I (1989) In: Patai S, Rappoport Z (eds) The Chemistry of Organic Silicon Compounds, vol. 2, Wiley Interscience, New York, pp. 1479–1526

    Chapter  Google Scholar 

  52. Musolf MC, Speier JL (1964) J Org Chem 29: 2519–2524

    Article  CAS  Google Scholar 

  53. Iovel IG, Goldberg YS, Shymanska M V, Lukevics E (1987) Organometallics 6: 1410–1413

    Article  CAS  Google Scholar 

  54. Ponomarenko SA, Rebrov EA, Bobrovsky AY Boiko NI, Muzafarov AM, Shibaev VP (1996) Liq Crystals 21: 1–12

    Article  CAS  Google Scholar 

  55. Karstedt BD (1973) US Patent 3,775,452

    Google Scholar 

  56. Boysen MMK, Lindhorst TK (2003) Tetrahedron 59: 3985–3988

    Article  CAS  Google Scholar 

  57. Lewis LN (1990) J Am Chem Soc 112: 5998–6004

    Article  CAS  Google Scholar 

  58. Stein J, Lewis LN, Gao Y, Scott RA (1999) J Am Chem Soc 121: 3693–3703

    Article  CAS  Google Scholar 

  59. Faglioni F, Blanco M, Goddard III WA, Saunders D (2002) J Phys Chem B 106: 1714–1721

    Article  CAS  Google Scholar 

  60. Rebrov EA, Ignat'eva GM, Lysachkov AI, Demchenko NV, Muzafarov AM (2007) Polym Sci Ser A 49: 483–495

    Article  Google Scholar 

  61. Garcia B, Casado CM, Cuadrado I, Alonso B, Morán M, Losada J (1999) Organometallics 18: 2349–2356

    Article  CAS  Google Scholar 

  62. Krska SW, Seyferth D (1998) J Am Chem Soc 120: 3604–3612

    Article  CAS  Google Scholar 

  63. Kriesel JW, Tilley TD (2001) Adv Mater 13: 1645–1648

    Article  CAS  Google Scholar 

  64. Gossage RA, Hooper R, Stobart SR (1999) Unpublished results

    Google Scholar 

  65. Rodrýguez LI, Rossell O, Seco M, Grabulosa A, Muller G, Rocamora M (2006) Organometallics 25: 1368–1376

    Article  CAS  Google Scholar 

  66. Rodrýguez LI, Rossell O, Seco M, Muller G (2007) J Organomet Chem 692: 851–858

    Article  CAS  Google Scholar 

  67. Comanita B, Roovers J (1999) Des Monom Polym 2: 111–124

    Article  CAS  Google Scholar 

  68. Wakefield B (1995) Organomagnesium Methods in Organic Chemistry, Academic Press, London, pp. 219–222

    Google Scholar 

  69. Tatarinova EA, Rebrov EA, Myakushev VD, Meshkov IB, Demchenko NV, Bystrova AV, Lebedeva OV, Muzafarov AM (2004) Russ Chem Bull Int Ed 53: 2591–2600

    Article  CAS  Google Scholar 

  70. Kim C, Jung I (2000) J Organomet Chem 599: 208–215

    Article  CAS  Google Scholar 

  71. Kim C, Choi SK, Kim B (2000) Polyhedron 19: 1031–1036

    Article  CAS  Google Scholar 

  72. Kim C, Son S (2000) J Organomet Chem 599: 123–127

    Article  CAS  Google Scholar 

  73. Vodop'yanov EA, Tatarinova EA, Rebrov EA, Muzafarov AM (2004) Russ Chem Bull Int Ed 53: 358–363

    Article  Google Scholar 

  74. Casado MA, Stobart SR (2000) Org Lett 2: 1549–1552

    Article  CAS  Google Scholar 

  75. Nakayama J, Lin JS (1997) Tetrahedron Lett 38: 6043–6046

    Article  CAS  Google Scholar 

  76. Matsuo T, Uchida K, Sekiguchi A (1999) Chem Commun 1799–1800

    Google Scholar 

  77. Kowaleska A, Stańczyk WA (2006) ARKIVOC 110–115

    Google Scholar 

  78. Zhou M, Roovers J, Robertson GP, Grover CP (2001) Anal Chem 75: 6708–6717

    Article  CAS  Google Scholar 

  79. Yamada A, Hatano K, Matsuoka K, Koyama T, Esumi Y, Koshino H, Hino K, Nishikawa K, Natori Y, Terunuma D (2006) Tetrahedron 62: 5074–5083

    Article  CAS  Google Scholar 

  80. Omotowa BA, Keefer KD, Kirchmeier RL, Schreeve JM (1999) J Am Chem Soc 121: 11130–11138

    Article  CAS  Google Scholar 

  81. Chai M, Pi Z, Tessier C, Rinaldi PL (1999) J Am Chem Soc 121: 273–279

    Article  CAS  Google Scholar 

  82. Ramýrez-Oliva E, Cuadrado I, Casado CM, Losada J, Alonso B (2006) J Organomet Chem 691: 1131–1137

    Article  CAS  Google Scholar 

  83. Kriesel JW, König S, Freitas MA, Marchall AG, Leary JA, Tilley TD (1998) J Am Chem Soc 120: 12207–12215

    Article  CAS  Google Scholar 

  84. Seyferth D, Kugita T, Rheingold AL, Yap GPA (1995) Organometallics 14: 5362–5366

    Article  CAS  Google Scholar 

  85. Kim C, Jung I (1999) J Organomet Chem 588: 9–19

    Article  CAS  Google Scholar 

  86. Findeis RA, Gade LH (2002) Dalton Trans 3952–3960

    Google Scholar 

  87. Alonso B, Cuadrado I, Morán M, Losada J (1994) J. Chem Soc Chem Commun 2575–2576

    Google Scholar 

  88. Alonso B, Morán M, Casado M, Lobete F, Losada J, Cuadrado I (1995) Chem Mater 7: 1440–1442

    Article  CAS  Google Scholar 

  89. Cuadrado I, Casado CM, Alonso B, Morán M, Losada J, Belsky V (1997) J Am Chem Soc 119: 7613–7614

    Article  CAS  Google Scholar 

  90. Núñez R, González-Campo A, Viñas C, Teixidor F, Sillanpää R, Kivekäs R (2005) Organometallics 24: 6351–6357

    Article  CAS  Google Scholar 

  91. de Groot D, Eggeling EB, de Wilde JC, Kooijman H, van Haaren RJ, van der Made AW, Spek AL, Vogt D, Reek JNH, Kamer PCJ, van Leeuwen PWNM (1999) Chem Commun 1623–1624

    Google Scholar 

  92. de Groot D, Emmererink PG, Coucke C, Reek JNH, Kamer PCJ, van Leeuwen PWNM (2000) Inorg Chem Commun 3: 711–713

    Article  Google Scholar 

  93. Benito M, Rossell O, Seco M, Segalés G (1999) Inorg Chim Acta 291: 247–251

    Article  CAS  Google Scholar 

  94. Benito M, Rossell O, Seco M, Segalés G (1999) Organometallics 18: 5191–5193

    Article  CAS  Google Scholar 

  95. Benito M, Rossell O, Seco M, Segalés G (2001) J Organomet Chem 619: 245–251

    Article  CAS  Google Scholar 

  96. Angurell I, Lima JC, Rodrýguez LI, Rodrýguez L, Rossell O, Seco M (2006) New J Chem 30: 1004–1008

    Article  CAS  Google Scholar 

  97. de Groot D, Reek JNH, Kamer PCJ, van Leeuwen PWNM (2002) Eur J Org Chem 1085–1095

    Google Scholar 

  98. Angurell I, Muller G, Rocamora M, Rossell O, Seco M (2003) Dalton Trans 1194–2000

    Google Scholar 

  99. Angurell I, Muller G, Rocamora M, Rossell O, Seco M (2004) Dalton Trans 2450–2457

    Google Scholar 

  100. Wijkens P, Jastrzebski JTBH, van der Schaaf PA, Kolly R, Hafner A, van Koten G (2000) Org Lett 2: 1621–1624 [1093]

    Article  CAS  Google Scholar 

  101. Beerens HI, Wijkens P, Jastrzebski JTBH, Verpoort F, Verdonck L, van Koten G (2000) J Organomet Chem 603: 244–248

    Article  CAS  Google Scholar 

  102. Harder S, Meijboom R, Moss JR (2004) J Organomet Chem 689: 1095–1101

    Article  CAS  Google Scholar 

  103. Hovestad NJ, Eggeling EB, Heidbüchel HJ, Jastrzebski JTBH, Kragl U, Keim W, Vogt D, van Koten G (1999) Angew Chem Int Ed 38: 1655–1658

    Article  CAS  Google Scholar 

  104. Hovestad NJ, Ford A, Jastrzebski JTBH, van Koten G (2000) J Org Chem 65: 6338–6344

    Article  CAS  Google Scholar 

  105. Eggeling EB, Hovestad NJ, Jastrzebski JTBH, Vogt D, van Koten G (2000) J Org Chem 65: 8857–8865

    Article  CAS  Google Scholar 

  106. Hovestad NJ, Hoare JL, Jastrzebski JTBH, Canty AJ, Smeets WJJ, Spek AL, van Koten G (1999) Organometallics 18: 2970–2980

    Article  CAS  Google Scholar 

  107. Rodrýguez G, Lutz M, Spek AL, van Koten G (2002) Chem Eur J 8: 46–57

    Google Scholar 

  108. Dijkstra HP, Kruithof CA, Ronde N, van de Coevering R, Ramón DJ, Vogt D, van Klink GPM, van Koten G (2003) J Org Chem 66: 675–685

    Article  CAS  Google Scholar 

  109. Benito JM, de Jesús E, de la Mata FJ, Flores JC, Gómez R, Gómez-Sal P (2002) J Organomet Chem 664: 258–267

    Article  CAS  Google Scholar 

  110. Benito JM, de Jesús E, de la Mata FJ, Flores JC, Gómez R, Gómez-Sal P (2006) J Organomet Chem 691: 3602–3608

    Article  CAS  Google Scholar 

  111. Kleij AW, Kleijn H, Jastrzebski JTBH, Smeets WJJ, Spek AL, van Koten G (1999) Organometallics 18: 268–276

    Article  CAS  Google Scholar 

  112. Kleij AW, Gossage RA, Klein Gebbink RJM, Brinkmann N, Reijerse EJ, Kragl U, Lutz M, Spek AL, van Koten G (2000) J Am Chem Soc 122: 12112–12124

    Article  CAS  Google Scholar 

  113. Kleij AW, Klein Gebbink RJM, van den Nieuwenhuijzen PAJ, Kooijman H, Lutz M, Spek AL, van Koten G (2001) Organometallics 20: 634–637

    Article  CAS  Google Scholar 

  114. Kleij AW, Klein Gebbink RJM, Lutz M, Spek AL, van Koten G (2001) J Organomet Chem 621: 190–196

    Article  CAS  Google Scholar 

  115. Sato I, Hosoi K, Kodaka R, Soai K (2002) Eur J Org Chem 3115–3118

    Google Scholar 

  116. Sato I, Kodaka R, Hosoi K, Soai K (2002) Tetrahedron: Asymmetry 13: 805–808

    Article  CAS  Google Scholar 

  117. Slagt MQ, Jastrzebski JTBH, Klein Gebbink RJM, van Ramesdonk HJ, Verhoeven JW, Ellis DD, Spek AL, van Koten G (2003) Eur J Org Chem 1692–1703

    Google Scholar 

  118. Le Nôtre J, Firet JJ, Sliedregt LAJM, van Steen BJ, van Koten G, Klein Gebbink RJM (2005) Org Lett 7: 363–366

    Article  CAS  Google Scholar 

  119. Schenning APHJ, Arndt JD, Ito M, Stoddart A, Schreiber M, Siemsen P, Martin RE, Boudon C, Gisselbrecht JP, Gross M, Gramlich V, Diederich F (2001) Helv Chim Acta 84: 296–334

    Article  CAS  Google Scholar 

  120. Lobete F, Cuadrado I, Casado CM, Alonso B, Morán M, Losada J (1996) J Organomet Chem 509: 109–113

    Article  CAS  Google Scholar 

  121. Friedmann G, Guilbert Y, Wittmann JC (1997) Eur Polym J 33: 419–426

    Article  CAS  Google Scholar 

  122. Andrés R, de Jesús E, de la Mata FJ, Flores JC, Gómez R (2002) Eur J Inorg Chem 2281–2286

    Google Scholar 

  123. Casado MA, Roovers J, Stobart SR (2001) Chem Commun 313–314

    Google Scholar 

  124. Ponomarenko SA, Rebrov EA, Boiko NI, Muzafarov AM, Shibaev VP (1998) Polym Sci Ser A 40: 763–768

    Google Scholar 

  125. Lebedev BV, Kulagina TG, Ryabkov MV, Ponomarenko SA, Makeev EA, Boiko NI, Shibaev VP, Rebrov EA, Muzafarov AM (2003) J Therm Anal Calorimetry 71: 481–492

    Article  CAS  Google Scholar 

  126. Zhu XM, Vinokur RA, Ponomarenko SA, Rebrov EA, Muzafarov AM, Boiko NI, Shibaev VP (2000) Polym Sci Ser A 42: 1263–1271

    Google Scholar 

  127. Boiko N, Zhu X, Vinokur R, Rebrov E, Muzafarov A, Shibaev V (2000) Ferroelectrics 243: 59–66

    Article  CAS  Google Scholar 

  128. Boiko NI, Lysachkov AI, Ponomarenko SA, Shibaev SA, Richardson RM (2005) Coll Polym Sci 283: 1155–1162

    Article  CAS  Google Scholar 

  129. Kosata B, Tamba GM, Baumeister U, Pelz K, Diele S, Pelzl G, Galli G, Samaritani S, Agina EV, Boiko NI, Shibaev VP, Weissflog W (2006) Chem Mater 18: 691–701

    Article  CAS  Google Scholar 

  130. Boiko N, Zhu X, Bobrovsky A, Shibaev V (2001) Chem Mater 13: 1447–1452

    Article  CAS  Google Scholar 

  131. Bobrovsky A, Ponomarenko S, Boiko N, Shibaev E, Rebrov E, Muzafarov A, Stumpe J (2002) Macromol Chem Phys 203: 1539–1546

    Article  CAS  Google Scholar 

  132. Bobrovsky AY, Pakhomov AA, Zhu XM, Boiko NI, Shibaev VP (2001) Polym Sci Ser A 43: 431–437

    Google Scholar 

  133. Getmanova EV, Chenskaya TB, Gorbatsevich OB, Rebrov EA, Vasilenko NG, Muzafarov AM (1997) React Funct Polym 33: 289–297

    Article  CAS  Google Scholar 

  134. Getmanova EV, Tereshchenko AS, Ignat'eva EA, Tatarinova EA, Myakushev VD, Muzafarov AM (2004) Russ Chem Bull Int Ed 53: 137–143

    Article  CAS  Google Scholar 

  135. Newkome et al. reported on the divergent synthesis of dendrimers characterized by the −C(CH2−)3 branch points [4]. For a review of the many variants of such dendrimers: Newkome GR, Moorefield CN, Vögtle F (1996) Dendritic Molecules. Concept-Syntheses-Perspectives. VCH, Weinheim

    Google Scholar 

  136. Ignat'eva GM, Rebrov EA, Myakushev VD, Chenskaya TB, Muzafarov MA (1997) Polym Sci Ser A 39: 843–852

    Google Scholar 

  137. Comanita B, Noren B, Roovers J (1999) Macromolecules 32: 1069–1072

    Article  CAS  Google Scholar 

  138. Omotowa BA, Shreeve JM (2003) Macromolecules 36: 8336–8345

    Article  CAS  Google Scholar 

  139. Lorenz K, Frey H, Stühn B, Mülhaupt R (1997) Macromolecules 30: 6860–6868

    Article  CAS  Google Scholar 

  140. Camerano JA, Casado MA, Ciriano MA, Tejel C, Oro LA (2005) Dalton Trans 3092–3100

    Google Scholar 

  141. Miedaner A, Curtis CJ, Barkley RM, Dubois DL (1994) Inorg Chem 33: 5482–5490

    Article  CAS  Google Scholar 

  142. Ropartz L, Morris RE, Foster DF, Cole-Hamilton DJ (2002) J Mol Catal A: Chem 182–183: 99–105

    Article  Google Scholar 

  143. Frey H, Lorenz K, Mülhaupt R, Rapp U, Mayer-Posner FJ (1996) Macromol Symp 102: 19–26

    CAS  Google Scholar 

  144. Matsuoka K, Terabatake M, Esumi Y, Hatano K, Terunuma D, Kuzuhara H (2006) Biomacromolecules 7: 2284–2290 [928]

    Article  CAS  Google Scholar 

  145. Chung TC, Raate M, Berluche E, Schulz DN (1988) Macromolecules 21: 1903–1907

    Article  CAS  Google Scholar 

  146. Kim C, Son S, Kim B (1999) J Organomet Chem 588: 1–8

    Article  CAS  Google Scholar 

  147. Terunuma D, Kato T, Nishio R, Matsuoka K, Kuzuhara H, Aoki Y, Nohira H (1998) Chem Lett 59–60

    Google Scholar 

  148. Terunuma D, Nishio R, Aoki Y, Nohira H, Matsuoka K, Kuzuhara H (1999) Chem Lett 565–566

    Google Scholar 

  149. Matsuoka K, Terabatake M, Saito Y, Hagihara C, Esumi Y, Terunuma D, Kuzuhara H (1998) Bull Chem Soc Jpn 71: 2709–2713

    Article  CAS  Google Scholar 

  150. Matsuoka K, Kurosawa H, Esumi Y, Terunuma D, Kuzuhara H (2000) Carbohyd Res 329: 765–772

    Article  CAS  Google Scholar 

  151. Yamada A, Hatano K, Koyama T, Matsuoka K, Esumi Y, Terunuma D (2006) Carbohyd Res 341: 467–473

    Article  CAS  Google Scholar 

  152. Morán M, Casado CM, Cuadrado I, Losada J (1993) Organometallics 12: 4327–4333

    Article  Google Scholar 

  153. Casado CM, Cuadrado I, Morán M, Alonso B, Lobete F, Losada J (1995) Organometallics 14: 2618–2620

    Article  CAS  Google Scholar 

  154. Arévalo S, de Jesús E, de la Mata FJ, Flores JC, Gómez R, Gómez-Sal MP, Ortega P, Vigo S (2003) Organometallics 22: 5109–5113

    Article  CAS  Google Scholar 

  155. Arévalo S, Benito JM, de Jesús E, de la Mata FJ, Flores JC, Gómez R (2000) J Organomet Chem 602: 208–210

    Article  Google Scholar 

  156. Arévalo S, de Jesús E, de la Mata FJ, Flores JC, Gómez R (2001) Organometallics 20: 2583–2592

    Article  CAS  Google Scholar 

  157. Bermejo JF, Ortega P, Chonco L, Eritja R, Samaniego R, Müllner M, de Jesús E, de la Mata FJ, Flores JC, Gómez R, Muñoz-Fernandez A (2007) Chem Eur J 13: 483–495

    Article  CAS  Google Scholar 

  158. Hahn H, Keith C, Lang H, Amaranatha Reddy R, Tschierke C (2006) Adv Mater 18: 2629–2633

    Article  CAS  Google Scholar 

  159. Chandra S, Buschbeck R, Lang H (2006) Anal Sci 22: 1327–1332

    Article  CAS  Google Scholar 

  160. Chandra S, Buschbeck R, Lang H (2006) Talanta 70: 1087–1093

    Article  CAS  Google Scholar 

  161. Buschbeck R, Lang H (2005) J Organomet Chem 690: 696–703

    Article  CAS  Google Scholar 

  162. Camerano JA, Casado MA, Ciriano MA, Lahoz FJ, Oro LA (2005) Organometallics 24: 5147–5156

    Article  CAS  Google Scholar 

  163. Casado MA, Hack V, Camerano JA, Ciriano MA, Tejel C, Oro LA (2005) Inorg Chem 44: 9122–9124

    Article  CAS  Google Scholar 

  164. Núñez R, González A, Viñas C, Teixidor F, Sillanpää R, Kivekäs R (2005) Org Lett 7: 231–233

    Article  CAS  Google Scholar 

  165. González-Campo A, Viñas C, Teixidor F, Núñez R, Sillanpää R, Kivekäs R (2007) Macromolecules 40: 5644–5652

    Article  CAS  Google Scholar 

  166. Cuadrado I, Morán M, Moya A, Casado CM, Barranco M, Alonso B (1996) Inorg Chim Acta 251: 5–7

    Article  CAS  Google Scholar 

  167. Roovers J, Comanita B (1999) Adv Polym Sci 142: 179–228

    Article  CAS  Google Scholar 

  168. Malenfant PRL, Fréchet JMJ (2001) In: Fréchet JMJ, Tomalia DA (eds) Dendrimers and Other Dendritic Polymers, Wiley, Chichester, pp. 171–193

    Chapter  Google Scholar 

  169. Frauenrath H (2005) Prog Polym Sci 30: 325–384

    Article  CAS  Google Scholar 

  170. Vlassopoulos D (2004) J Polym Sci Part B: Polym Phys 42: 2931–2941

    Article  CAS  Google Scholar 

  171. Morton M, Helminiak TE, Gadkary SD, Bueche F (1962) J Polym Sci 57: 471–482

    Article  CAS  Google Scholar 

  172. Zelinsky RP, Wofford CF (1965) J Polym Sci Part A 3: 93–103

    Article  Google Scholar 

  173. Roovers J, Bywater S (1972) Macromolecules 5: 384–388

    Article  CAS  Google Scholar 

  174. Iatrou H, Hadjichristidis N (1992) Macromolecules 25: 4649–4651

    Article  CAS  Google Scholar 

  175. Zhou LL, Hadjichristidis N, Toporowski P, Roovers J (1992) Rubber Chem Technol 65: 303–314

    CAS  Google Scholar 

  176. Roovers J, Zhou LL, Toporowski P, van der Zwam M, Iatrou H, Hadjichristidis N (1993) Macromolecules 26: 4324–4331

    Article  CAS  Google Scholar 

  177. Avgeropoulos A, Poulos Y, Hadjichristidis N, Roovers J (1996) Macromolecules 29: 6076–6078

    Article  CAS  Google Scholar 

  178. Polyakov DK, Ignat'eva GM, Rebrov EA, Vasilenko NG, Sheiko SS, Möller M, Muzafarov AM (1998) Polym Sci Ser A 40: 876–883

    Google Scholar 

  179. Vasilenko NG, Getmanova EV, Myakushev VD, Rebrov EA, Möller M, Muzafarov AM (1997) Polym Sci Ser A 39: 977–983

    Google Scholar 

  180. Vasilenko NG, Rebrov EA, Muzafarov AM, Esswein B, Striegel B, Möller M (1998) Macromol Chem Phys 199: 889–895

    Article  CAS  Google Scholar 

  181. Vasilenko NG, Ignat'eva GM, Myakushev VD, Rebrov EA, Möller M, Muzafarov AM (2001) Dokl Chem 377: 84–88

    Article  Google Scholar 

  182. Comanita B, Roovers, J (1999) Unpublished results

    Google Scholar 

  183. Hovestad NJ, van Koten G, Bon SAF, Haddleton DM (2000) Macromolecules 33: 4048–4052

    Article  CAS  Google Scholar 

  184. Beerens H, Verpoort F, Verdonck L (2000) J Mol Catal A: Chem 159: 197–201

    Article  CAS  Google Scholar 

  185. Beerens H, Verpoort F, Verdonck L (2000) J Mol Catal A: Chem 151: 279–282

    Article  CAS  Google Scholar 

  186. Beerens H, Wang W, Verdonck L, Verpoort F (2002) J Mol Catal A: Chem 190: 1–7

    Article  CAS  Google Scholar 

  187. Cornelissen JJLM, van Heerbeek R, Kamer PCJ, Reek JNH, Sommerdijk NAJM, Nolte RJM (2002) Adv Mater 14: 489–492

    Article  CAS  Google Scholar 

  188. Kim C, Park E, Jung I (1996) J Korean Chem Soc 40: 347–356

    CAS  Google Scholar 

  189. Kim C, Kang S (2000) J Polym Sci Part A: Polym Chem 38: 724–729

    Article  CAS  Google Scholar 

  190. Ouali N, Méry S, Skoulios A, Noirez L (2000) Macromolecules 33: 6185–6193

    Article  CAS  Google Scholar 

  191. Chang Y, Kim C (2001) J Polym Sci Part A: Polym Chem 39: 918–926

    Article  CAS  Google Scholar 

  192. Moingeon F, Masson P, Méry S (2007) Macromolecules 40: 55–64

    Article  CAS  Google Scholar 

  193. Hawker and Fréchet reported on the convergent synthesis of dendrimers with 3,5-dioxo– C6H3−CH2− repeat units [33]. For a review see also [168]

    Google Scholar 

  194. Welch KT, Arévalo S, Turner JFC, Gómez R (2005) Chem Eur J 11: 1217–1227

    Article  CAS  Google Scholar 

  195. Benito M, Rossell O, Seco M, Muller G, Ordinas JI, Font-Bardia M, Solans X (2002) Eur J Inorg Chem 2477–2487

    Google Scholar 

  196. Krupková A, Čermák J, Walterová Z, Horský J (2007) Anal Chem 79: 1639–1645

    Article  CAS  Google Scholar 

  197. Ropartz L, Morris RE, Foster DF, Cole-Hamilton DJ (2001) Chem Commun 361–362

    Google Scholar 

  198. Wu Z, Biemann K (1997) Int J Mass Spectrom Ion Processes 165/166: 349–361

    Article  CAS  Google Scholar 

  199. Zhou M, Roovers J (2001) Macromolecules 34: 244–252

    Article  CAS  Google Scholar 

  200. Kuklin AI, Ignat'eva GM, Ozerina LA, Islamov AK, Mukhamedzyanov RI, Shumilkina NA, Myakushev VD, Sharipov EY, Gordelii VI, Muzafarov AM, Ozerin AN, (2002) Polym Sci Ser A 44: 1273–1280

    Google Scholar 

  201. Kuklin AI, Ozerin AN, Islamov AK, Muzafarov AM, Gordeliy VI, Rebrov EA, Ignat'eva GM, Tatarinova EA, Mukhamedzyanov RI, Ozerina LA, Shapirov EY (2003) J Appl Cryst 36: 679–683

    Article  CAS  Google Scholar 

  202. Ozerin AN, Muzafarov AM, Kuklin AI, Islamov AK, Gordelyi VI, Ignat'eva GM, Myakushev VD, Ozerina LA, Tatarinova EA (2004) Doklady Chem 395: 59–62

    Article  CAS  Google Scholar 

  203. Lyulin A, Davies G, Adolf D (2000) Macromolecules 33: 6899–6900

    Article  CAS  Google Scholar 

  204. Lach C, Brizzolara D, Frey H (1997) Macromol Theor Simul 6: 371–380

    Article  CAS  Google Scholar 

  205. Mazo MA, Shamaev MY, Balabaev NK, Darinskii AA, Neelov IM (2004) Phys Chem Chem Phys 6: 1285–1289

    Article  CAS  Google Scholar 

  206. Mazo MA, Zhilin PA, Gusarova EB, Sheiko SS, Balabaev NK (1999) J Mol Liq 82: 105–116

    Article  CAS  Google Scholar 

  207. Sagidullin A, Skirda VD, Tatarinova EA, Muzafarov AM, Krykin MA, Ozerin AN, Fritzinger B, Scheler U (2003) Appl Magn Res 25: 129–156

    Article  CAS  Google Scholar 

  208. Sagidullin A, Muzafarov AM, Krykin MA, Ozerin AN, Skirda VD, Ignat'eva GM (2002) Macromolecules 35: 9472–9479

    Article  CAS  Google Scholar 

  209. Krykin MA, Volkov VI, Volkov EV, Surin NM, Ozerina LA, Ignat'eva GM, Muzafarov AM, Ozerin AN (2005) Doklady Chem 403: 115–117

    Article  CAS  Google Scholar 

  210. Lezov AV, Mel'nikov AB, Polushina GE, Antonov EA, Novitskaya ME, Boiko NI, Ponomarenko SA, Rebrov EA, Shibaev VP, Ryumtsev EI, Muzafarov AM (2001) Doklady Chem 381: 313–316

    Article  Google Scholar 

  211. Tomalia DA, Hedstrand DM, Wilson LR (1990) Encyclopedia of Polymer Science and Engineering, 2nd edn., Index Volume, Wiley, New York, pp. 46–92

    Google Scholar 

  212. Mourey TH, Turner SR, Rubinstein M, Fréchet JMJ, Hawker CJ, Wooley KL (1992) Macromolecules 25: 2401–2406

    Article  CAS  Google Scholar 

  213. Elshahre M, Atallah AS, Santos S, Grigoras S (2000) Compt Theor Polym Sci 10: 21–28

    Article  Google Scholar 

  214. Stark B, Lach C, Farago B, Frey H, Schlenk C, Stühn B (2003) Coll Polym Sci 281: 593–600

    Article  CAS  Google Scholar 

  215. Lezov AV, Mel'nikov AB, Polushina GE, Ponomarenko SA, Boiko NI, Kossmehl E, Ryumtsev EI, Shibaev VP (1998) Doklady Phys Chem 362: 338–342

    Google Scholar 

  216. Ryabkov MV, Kulagina TG, Lebedev BV (2001) Russ J Phys Chem 75: 1988–1996

    Google Scholar 

  217. Lebedev BV, Ryabkov MV, Tatarinova EA, Rebrov EA, Muzafarov AM (2003) Russ Chem Bull Int Ed 52: 545–551

    Article  CAS  Google Scholar 

  218. Smirnova NN, Lebedev BV, Khramova NM, Tsvetkova LY, Tatarinova EA, Myakushev VD, Muzafarov AM (2004) Russ J Phys Chem 78: 1196–1201

    Google Scholar 

  219. Smirnova NN, Stepanova OV, Bykova TA, Markin AV, Muzafarov AM, Tatarinova EA, Myakushev VD (2006) Thermochim Acta 440: 188–194

    Article  CAS  Google Scholar 

  220. Fox TG (1956) Bull Am Phys Soc 1: 123–128

    CAS  Google Scholar 

  221. Perov NS, Martirisov VA, Gritsenko OT, Aulov VA, Nikol'skii OG, Ozerin AN (2000) Doklady Chem 372: 77–80

    Google Scholar 

  222. Trahasch B, Stühn B, Frey H, Lorenz K (1999) Macromolecules 32: 1962–1966

    Article  CAS  Google Scholar 

  223. Chai M, Niu Y, Youngs WJ, Rinaldi PL (2001) J Am Chem Soc 123: 4670–4678

    Article  CAS  Google Scholar 

  224. Rathgeber S, Monkenbusch M, Kreitschmann M, Urban V, Brulet A (2002) J Chem Phys 117: 4047–4062

    Article  CAS  Google Scholar 

  225. Rathgeber S, Monkenbusch M, Hedrick JL, Trollsås M, Gast AP (2006) J Chem Phys 125: 204908

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Formerly of National Research Council of Canada, Canada

    Jacques Roovers

  2. Institute for Chemical Process and Environmental Technology, National Research Council, Ottawa, Ontario, K1A 0R6, Canada

    Jianfu Ding

Authors
  1. Jacques Roovers
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Jianfu Ding
    View author publications

    You can also search for this author in PubMed Google Scholar

Editor information

Editors and Affiliations

  1. Michigan Molecular Institute, 1910 W. St. Andrews Rd., Midland, MI, 48640, USA

    Petar R. Dvornic  & Michael J. Owen  & 

Rights and permissions

Reprints and permissions

Copyright information

© 2009 Springer Science + Business Media B.V.

About this chapter

Cite this chapter

Roovers, J., Ding, J. (2009). Carbosilane Dendrimers. In: Dvornic, P.R., Owen, M.J. (eds) Silicon-Containing Dendritic Polymers. Advances in Silicon Science, vol 2. Springer, Dordrecht. https://doi.org/10.1007/978-1-4020-8174-3_3

Download citation

Publish with us

Policies and ethics

Search

Navigation