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Silicon-Organic Dendrimers

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Silicon-Containing Dendritic Polymers

Part of the book series: Advances in Silicon Science ((ADSS,volume 2))

Silicon can play a variety of different roles when incorporated in or combined with otherwise “purely” organic dendritic branch cells which in this chapter are meant to include those that contain carbon and some combination of hydrogen, nitrogen, oxygen and sulfur. As a result, a diversity of compositional and architectural hybrid dendrimers can be formed, containing one or more of the following types of building blocks (see Fig. 11.1):

  1. (a)

    Silicon atoms (di-, tri- or tetra-functional) (see Chapters 2–5) or silicon-containing groups (e.g., cyclic siloxanes, see Chapter 6, or polyhedral oligosilsesquioxanes [POSS], see Chapter 7) as dendrimer cores.

  2. (b)

    Silicon atoms in dendrimer interiors as (see Chapter 1)

    1. (b1)

      Branch extenders (i.e., constitutive elements of branches with 1→1 multiplicity between branch junctures).

    2. (b2)

      Branch junctures with di- (1→2) or tri- (1→3) branching multiplicity.

  3. (c)

    Reactive or non-reactive (inert) silicon-containing end-groups providing organic dendrimers with properties characteristic for organo-silicon compounds.

  4. (d)

    Copolymeric dendrimers having silicon-containing and “purely” organic branch cells organized either in a radially layered or segmented (i.e., individual dendrons of different compositions) architectural arrangement (see below and also Chapter 2).

Because of these structural differences, the properties of the resulting dendrimers may range from being quite similar to those of their purely organic counterparts to being dramatically different from them. Hence, the introduction of silicon into organic dendritic structures opens up vast new areas of molecular design and engineering aimed at unique new materials for specific targeted applications.

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References

  1. de Leuze-Jallouli AM, Swanson DR, Perz SV, Owen MJ, Dvornic PR (1997) Polym Mater Sci Eng 77: 67.

    Google Scholar 

  2. Dvornic PR, de Leuze-Jallouli AM, Swanson DR, Owen MJ, Perz SV (1998) US Patent 5,739,218.

    Google Scholar 

  3. Dvornic PR, de Leuze-Jallouli AM, Owen MJ, Perz SV (2000) Macromolecules 33: 5366.

    Article  CAS  Google Scholar 

  4. www.Dendritech.com

  5. Dvornic PR, de Leuze-Jallouli AM, Owen MJ, Perz SV (2000) Radially layered poly(amidoamine-organosilicon) copolymeric dendrimers and their networks containing controlled hydrophilic and hydrophobic nanoscopic domains, in Silicones and Silicone-Modified Materials, Clarson SJ, Fitzgerald JJ, Owen MJ, Smith SD, Eds., ACS Symposium Series 729, American Chemical Society, Washington, DC, pp. 241–269.

    Google Scholar 

  6. Dvornic PR, de Leuze-Jallouli AM, Owen MJ, Perz SV (2000) US Patent 6,077,500.

    Google Scholar 

  7. Dvornic PR, Hu J, de Leuze-Jallouli AM, Owen MJ, Parham PL, Perz SV, Reeves SD (2002) US Patent 6,350,384 B1.

    Google Scholar 

  8. Dvornic PR, Hu J, Reeves SD, Owen MJ (2002) Silicon Chem 1: 177.

    Article  CAS  Google Scholar 

  9. Hawker CJ, Fréchet JMJ (1992) J Am Chem Soc 114: 8405.

    Article  CAS  Google Scholar 

  10. Hawker CJ, Fréchet JMJ (1995) Three-dimensional dendritic macromolecules: Design, synthesis, and properties, in New Methods of Polymer Synthesis, Ebdon JR, Eastmond GC, Eds., Blackie Academic & Professional, London, Volume 2, pp. 290–330.

    Google Scholar 

  11. Brewis M, Clarkson GJ, Goddard V, Helliwell M, Holder AM, McKeown NB (1998) Angew Chem Int Ed 37: 1092.

    Article  CAS  Google Scholar 

  12. McKeown NB (1999) Adv Mater 11: 67.

    Article  CAS  Google Scholar 

  13. Ruiz J, Lafuente G, Marcen S, Ornelas C, Lazare S, Cloutet E, Blais J-C, Astruc D (2003) J Am Chem Soc 125: 7250.

    Article  CAS  Google Scholar 

  14. Kemmitt T, Henderson W (1997) J Chem Soc Perkin Trans 1: 729.

    Article  Google Scholar 

  15. Newkome GR, Baker GR, Moorefield CN, He E, Epperson J, Weis CD (1997) Polym Mater Sci Eng 77: 65.

    CAS  Google Scholar 

  16. Newkome GR, Weis CD, Moorefield CN, Baker GR, Childs BJ, Epperson J (1998) Angew Chem Int Ed 37: 307.

    Article  CAS  Google Scholar 

  17. Uppuluri S, Keinath SE, Tomalia DA, Dvornic PR (1998) Macromolecules 31: 4498.

    Article  CAS  Google Scholar 

  18. Aldrich handbook of fine chemicals (2007–2008) p. 823.

    Google Scholar 

  19. Dvornic PR, Owen MJ (2002) Poly(amidoamine-organosilicon) (PAMAMOS) dendrimers and their derivatives of higher degree of structural complexity, in Synthesis and Properties of Silicones and Silicone-Modified Materials, Clarson SJ, Fitzgerald JJ, Owen MJ, Smith SD, Van Dyke ME, Eds., ACS Symposium Series 838, American Chemical Society, Washington, DC, pp. 236–259.

    Google Scholar 

  20. Sachdeva R, Dvornic PR (2008).

    Google Scholar 

  21. de Leuze-Jallouli AM, Swanson D, Dvornic PR, Perz SV, Owen MJ (1997) Polym Mater Sci Eng 77: 93.

    Google Scholar 

  22. Dvornic PR, de Leuze-Jallouli AM, Perz S V, Owen MJ (2000) Mol Cryst Liq Cryst 353: 223.

    Article  CAS  Google Scholar 

  23. Sayed-Sweet Y, Hedstrand DM, Spindler R, Tomalia DA (1997) J Mater Chem 7: 1199.

    Article  CAS  Google Scholar 

  24. Iyer J, Hammond PT (1999) Langmuir 15: 1299.

    Article  CAS  Google Scholar 

  25. Zhang T, Dvornic PR, Kaganove SN (2007) Langmuir 23: 10589.

    Article  CAS  Google Scholar 

  26. Dvornic PR, de Leuze-Jallouli AM, Owen MJ, Perz SV (1998) The first dendrimer-based networks containing hydrophobic organosilicon and hydrophilic amidoamine nanoscopic domains, in Silicones in Coatings II, Paint Research Association, London, Paper 5.

    Google Scholar 

  27. Dvornic PR, de Leuze-Jallouli AM, Owen MJ, Perz SV (1998) Polym Preprints 39(1): 473.

    Google Scholar 

  28. de Leuze-Jallouli AM, Dvornic PR, Perz S V, Owen MJ (1998) Polym Preprints 39(1): 475.

    Google Scholar 

  29. Dvornic PR, de Leuze-Jallouli AM, Owen MJ, Perz SV (1999) US Patent 5,902,863

    Google Scholar 

  30. Dvornic PR, Li J, de Leuze-Jallouli AM, Reeves SD, Owen MJ (2002) Macromolecules 35: 9323.

    Article  CAS  Google Scholar 

  31. Dvornic PR, de Leuze-Jallouli AM, Owen MJ, Perz SV (1999) Polym Preprints 40(1): 408.

    CAS  Google Scholar 

  32. Dvornic PR, de Leuze-Jallouli AM, Owen MJ, Dalman DA, Parham P, Pickelman D, Perz SV (1999) Polym Mater Sci Eng 81: 187.

    CAS  Google Scholar 

  33. Bubeck RA, Bauer BJ, Dvornic PR, Owen MJ, Reeves SD, Parham PL, Hoffman LW (2001) Polym Mater Sci Eng 84: 866.

    CAS  Google Scholar 

  34. Balogh L, de Leuze-Jallouli AM, Dvornic PR, Owen MJ, Perz SV, Spindler R (1999) US Patent 5,938,934.

    Google Scholar 

  35. Dvornic PR (2006) J Polym Sci Part A: Polym Chem 44: 2755.

    Article  CAS  Google Scholar 

  36. Vohs JK, Fahlman BD (2007) New J Chem 31: 1041.

    Article  CAS  Google Scholar 

  37. Vidal F, Hémonic I, TeyssiéD, Boileau S, Reeves SD, Dvornic PR (2001) Polym Preprints 42(1): 128.

    CAS  Google Scholar 

  38. Dvornic PR, Owen MJ, Keinath SE, Hu J, Hoffman LW, Parham PL (2001) Polym Preprints 42(1): 126.

    CAS  Google Scholar 

  39. Ruckenstein E, Yin W (2000) J Polym Sci Part A: Polym Chem 36: 1443.

    Article  Google Scholar 

  40. Owen MJ, Dvornic PR, Bubeck RA (2002) Nanostructured coatings from radially layered poly(amidoamine-organosilicon) (PAMAMOS) dendrimers, in Silicones in Coatings IV, Paint Research Association, London, Paper 3.

    Google Scholar 

  41. Bubeck RA, Dvornic PR, Hu J, Hexemer A, Li X, Keinath SE, Fischer DA (2005) Macromol Chem Phys 206: 1146.

    Article  CAS  Google Scholar 

  42. Dvornic PR, Bubeck RA, Reeves SD, Li J, Hoffman LW (2003) Silicon Chem 2: 207.

    Article  Google Scholar 

  43. Dvornic PR, Hartmann-Thompson C, Kaganove SN, Rousseau J, Sarkar A, Zhang T (2006) Polym Preprints 47(2): 1166.

    CAS  Google Scholar 

  44. Dvornic PR, Sarkar A, Rousseau J, Hartmann-Thompson C, Merrington A, Carver P, Zhang T, Keinath S (2008) Dendritic polymer networks: A new class of nano-structured antifouling coatings, 235 ACS National meeting, New Orleans, LA.

    Google Scholar 

  45. Arkas M, Tsiourvas D, Paleos CM (2005) Chem Mater 17: 3439.

    Article  CAS  Google Scholar 

  46. Kaganove SN, Zhang T, Dvornic PR (2005) Presentations at IDS-4, Mount Pleasant, MI; ACS-Midland Section Fall Scientific Meeting, Midland, MI; Pacifichem 2005, Honolulu, HI.

    Google Scholar 

  47. Dalman DA, Dvornic PR, Hoover MF, Lentz T (2002) PAMAMOS copper nanocomposite coatings for the fabrication of printed wiring boards, in Microelectronics Gold Rush, Proceedings 35th International Symposium on Microelectronics, IMPAS, pp. 33–38.

    Google Scholar 

  48. Dalman DA, Dvornic PR (2005) US Patent 6,866,764 B2.

    Google Scholar 

  49. Kohli N, Dvornic PR, Kaganove SN, Worden RM, Lee I (2004) Macromol Rapid Commun 25: 935.

    Article  CAS  Google Scholar 

  50. Kohli N, Worden RM, Lee I (2005) Chem Commun 3: 316.

    Google Scholar 

  51. Dvornic PR, Owen MJ (2009) Radially layered poly(amidoamine-organosilicon) dendrimers, submitted to Advances in Silicones and Silicone-Modified Materials, Clarson SJ, Owen MJ, Smith SD, Van Dyke ME, Eds., ACS Symposium Series, American Chemical Society, Washington, DC.

    Google Scholar 

  52. Uchiyama T, Ishii K, Nonomura T, Kobayashi N, Isoda S (2003) Chem Eur J 9: 5757.

    Article  CAS  Google Scholar 

  53. Dvornic PR, Hartmann-Thompson C, Keinath SE, Hill EJ (2004) Macromolecules 37: 7818.

    Article  CAS  Google Scholar 

  54. Sarkar A, Dvornic PR, (2007) Unpublished results, Michigan Molecular Institute.

    Google Scholar 

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Authors and Affiliations

  1. Michigan Molecular Institute, 1910 W. St. Andrews Rd., Midland, MI, 48640, USA

    P.R. Dvornic, M.J. Owen & R. Sachdeva

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  1. P.R. Dvornic
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  2. M.J. Owen
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  3. R. Sachdeva
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    Petar R. Dvornic  & Michael J. Owen  & 

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Dvornic, P., Owen, M., Sachdeva, R. (2009). Silicon-Organic Dendrimers. In: Dvornic, P.R., Owen, M.J. (eds) Silicon-Containing Dendritic Polymers. Advances in Silicon Science, vol 2. Springer, Dordrecht. https://doi.org/10.1007/978-1-4020-8174-3_11

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