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Homogeneous and Heterogeneous Catalysis Using Base Metals From Groups 10 And 11

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New Methodologies and Techniques for a Sustainable Organic Chemistry

Part of the book series: NATO Science Series II: Mathematics, Physics and Chemistry ((NAII,volume 246))

Recent developments on the use of nickel-in-charcoal (Ni/C) as a catalyst for several cross-couplings assisted by microwave irradiation are presented. The new reagent for synthesis, nickel-on-graphite (Ni/Cg) is presented as a means of catalyzing the reductions of aryl tosylates and mesylates. Another reagent under development, copper-in-charcoal (Cu/C) is described and its potential to effect heterogeneous asymmetric hydrosilylations in the presence of an inexpensive silane is disclosed.

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Author information

Authors and Affiliations

  1. Department of Chemistry & Biochemistry, University of California, 93106, Santa Barbara, CA, USA

    Bruce H. Lipshutz

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  1. Bruce H. Lipshutz
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Editors and Affiliations

  1. Istituto di Chimica dei Composti Organometallici-CNR, 50019, Firenze, Italy

    Alessandro Mordini

  2. Research Group for Organic Chemical Technology, Budapest University of Technology and Economics, H-1521, Budapest, Hungary

    Ferenc Faigl

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Lipshutz, B.H. (2008). Homogeneous and Heterogeneous Catalysis Using Base Metals From Groups 10 And 11. In: Mordini, A., Faigl, F. (eds) New Methodologies and Techniques for a Sustainable Organic Chemistry. NATO Science Series II: Mathematics, Physics and Chemistry, vol 246. Springer, Dordrecht. https://doi.org/10.1007/978-1-4020-6793-8_8

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