In this chapter we shall discuss applications of block copolymers (bcps) to nanotechnologies and nanosciences. Our objectives here are to explore the methods and principles concerning fabrications of ordered structures of bcps having various symmetries with nano-sized periodicity to create new materials with interesting structures and properties. We define this kind of fabrication as nano-fabrication. In other words we aim to control or manipulate self- organized microdomain structures of bcps, in both nonequilibrium and equi- librium states, and utilize them as templates for further nano-fabrication to- ward advanced devices and materials, such as tunable photonic crystals [1-4], quantum dots and nanowires [5-9], nanohybrids with inorganic materials and nanometal particles [10-12], photovoltaics and photoluminescence [13-16], etc. We shall present the bcp templates in both bulk (Sect. 2) and thin films (Sect. 3).
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References
Fink Y., Urbas A. M., Bawendi M. G., Joannopoulos J. D., Thomas E. L. (1999) Journal of Lightwave Technology 17:1963
Urbas A. M., Sharp R., Fink Y., Thomas E. L., Xenidou M., Fetters, L. J. (2000) Advanced Materials (Weinheim, Germany) 12: 812
Urbas, A. M., Maldovan M., DeRege P., Thomas E. L. (2002) Advanced Materials (Weinheim, Germany) 14: 1850
Yoon J., Lee W., Thomas E. L., (2005) MRS Bulletin 30: 721
Leclere P. H., Parente V., Bredas J. L., Francois B., Lazzaroni R. (1998) Chem. Mater.10: 4010
Thurn-Albrecht T., Schotter J., Kastle G. A., Emley N., Shibauchi T., KrusinElbaum L., Guarini K., Black C. T., Tuominen M. T., Russell T. P. (2000) Science 290: 2126
Niu H., Zhang L., Gao M., Chen Y. (2005) Langmuir 21: 4205
Minelli C., Hinderling C., Heinzelmann H., Pugin R., Liley M. (2005) Langmuir 21: 7080
Lu J.,Q, Yi S. (2006) Lungmuir 22: 3951
Tjandra W., Yao J., Ravi P., Tam K. C., Alamsjah A. (2005) Chem. Mater. 17: 4865
Fu B. X., Lee A., Haddad T. S. (2004) Macromolecules 37:5211
Jain A., Hall L. M., Garcia C. B., Gruner S. M., Wiesner U. (2005) Macromolecules 38: 10095
Brouwer H. J., Hilberer A., Krasnikov V. V., Werts M., Wildeman J., Hadziioannou G. (1997) Synthetic Metals 84:881
Cacialli F., Feast W. J., Friend R. H., de Jong M., Lovenich P. W., Salaneck W. R. (2002) Polymer 43: 3555
Sun Q. J., Wang H. Q., Yang C. H., Wang X. G., Liu D. S., Li Y. F. (2002) Thin Solid Films 417:14
Heiser T., Adamopoulos G., Brinkmann M., Giovanella U., Ould-Saad S., Bro- chon C, van de Wetering K., Hadziioannou G. (2006) Thin Solid Films 511-512: 219
Hashimoto T., Yamauchi K., Yamaguchi D., Hasegawa H. (2003) Macromol. Symp. 201:65
Hamley I. (1998) Physics of Block Copolymers, vol. 94, Oxford University Press, Oxford
Kellogg G. J., Walton D. G., Mayes A. M., Lambody P., Russell T. P., Gallagher P. D., Satija S. K. (1996) Phys. Rev. Lett. 76: 2503
Thomas E. L., Alward D. B., Kinning D. J., Martin D. C., Handlin D. L., Fetters L. J. (1986) Macromolecules 19: 2197
Hasegawa H., Tanaka H., Yamasaki K., Hashimoto T. (1987) Macromolecules 20: 1651
Nishikawa Y., Kawada H., Hasegawa H., Hashimoto T. (1993) Acta Polym. 44:192
Gido S. P., Gunter J., Thomas E. L., Hoffman D. (1993) Macromolecules 26: 4506
Gido S. P., Thomas E. L. (1994) Macromolecules 27: 849, 6137
Hashimoto T., Tsutsumi K., Funaki Y. (1997) Langmuir 13: 6869
. Hashimoto T., Nishikawa Y., Tsutsumi K. (2006) Macromolecules, in press
Okumura A., Nishikawa Y., Hashimoto T. (2006) Polymer, 47:7805
Adachi M., Okumura A., Sivaniah E., Hashimoto T. (2006) Macromolecules, 39:7352
. Hasegawa H., Hashimoto T. (1996) In Comprehensive Polymer Science, Second Supplement, Aggarwal S., Russo S., Eds., Pergamon, Chap. 14, pp.497-539
Hashimoto T., Hasegawa H. (2004) Trans. Mater. Res. Soc. Jpn (2004) 1: 77
Hashimoto T., Okumura A., Tanabe D. (2003) Macromolecules 36: 7324
Tsutsumi K., Funaki Y., Hirokawa Y., Hashimoto T. (1999) Langmuir 15: 5200
Hashimoto T., Yamaguchi D., Court F. (2003) Macromol. Symp. 195:191
Shi A-C, Noolandi J. (1994) Macromolecules 27: 2936
Lyatskaya J. V., Zhulina E. B., Birshtein T. M. (1992) 33: 343
Court F., Hashimoto T., (2001) Macromolecules 34:2536
Court F., Hashimoto T., (2002) Macromolecules 35: 2566
Ribbe A. E., Okumura A., Matsushige K., Hashimoto T. (2001) Macromolecules 34:8239
Okumura A., Tsutsumi K., Hashimoto T. (2000) Polym. J. 32: 520
Hashimoto T., Harada M., Sakamoto N., (1999) Macromolecules 32: 6867
Hashimoto T., Bodycomb J., Funaki Y., Kimishima K., (1999)Macromolecules 32:952
Bodycomb J., Funaki Y., Kimishima K., Hashimoto T. (1999), Macromolecules 32:2075
. Ciebien J. F., Clay R. T., Sohn B. H., Cohen, R. E. (1998) New Journal of Chemistry 685.
Ulbricht M. (2006) Polymer 47:2217
Mayer ABR, Mark J. E. (1997) J. Polym. Sci.: Part A: Polym. Chem. 35: 3151
Berkovich, Y., Garti N. (1997) Colloids and Surfaces A. 128: 91
Wagner C. (1961) Z. Electrochem 65: 581
Lifshitz I., M, Slyozov V. V. (1961) J. Phys. Chem. Sol. 19: 35
Gunton J. D., San Miguel M., Sahni P. S. (1983) In Phase Transitions and Critical Phenomena, Domb C., Lebowitz J. L., Eds. Academic Press: New York, Vol. 8, Chap. 3
Binder K., Stauffer D. (1974) Phys. Rev. Lett. 33:1006
Kawasaki K., Ohta T. (1978) Progr. Theor. Phys. 59:362
Oki K., Sagana H., Eguchi T. (1977) J. Phys. (Paris) C 7: 414
Horiuchi S., Fujita T., Hayakawa T., Nakao Y. Langmuir (2003) 19: 2963
Hashimoto T. (2005) Bull. Chem. Soc. Jpn, 78:1
Park M., Harrison C., Chaikin P. M., Register R. A., Adamson D. H. (1997) Science 276:1401
Hasegawa H., Hashimoto T. (1985) Macromolecules 18:589
Hasegawa H., Hashimoto T. (1992) Polymer 33:475
Russell T. P., Coulon G., Deline V. R., Miller D. C. (1989) Macromolecules 22:4600
Coulon G., Ausserre D., Russell T. P. (1990) Journal de Physique (Paris) 51:777
Fukunaga K., Ribbe A. R., Hashimoto T. (2006) Macromolecules, 39:6171
Elbs H., Fukunaga K., Stadler R., Sauer G., Magerle R., Krausch G. (1999) Macromolecules 32:1204
Fukunaga K., Elbs H., Magerle R., Krausch G. (2000) Macromolecules 33:947
Magonov S. (2001) Handbook of Surfaces and Interfaces of Materials, vol. 2, eds. Nalwa H. S., Academic Press, San Diego, CA, in pp. 393-430
Zheng W., Wang Z. G. (1995) Macromolecules 28:7215
Fukunaga K., Hashimoto T., Elbs H., Krausch G. (2002) Macromolecules 35:4406
Fukunaga K., Hashimoto T., Elbs H., Krausch G. (2003) Macromolecules 36:2852
Hashimoto T., Jinnai H., Nishikawa Y., Koga T. (2002) Polym. Symp. 190:9
Kim G. and Libera M. (1998) Macromolecules 31:2569
Kim G. and Libera M. (1998) Macromolecules 31:2670
Albalak R. J., Capel M. S., Thomas E. L. (1998) Polymer 39:1647
Russell T. P., Mayes A. M., Kunz M. S. (1994) Ordering in Macromolecular Systems; eds. Teramoto A., Kobayashi M., Norisuye T., Springer-Verlag, Berlin, 217
Huang E., Mansky P., Russell T. P., Harrison C., Chaikin P. M., Register R. A., Hawker C. J., Mays J. (2000) Macromolecules 33:80
Rockford L., Mansky P., Russell T. P., Mochrie S. G. (1999) Phys. Rev. Lett. 82:2602
Kim S. O., Solak H. H., Stoykovich M. P., Ferrier N. J., de Pablo J. J., Nealey P. F. (2003) Nature 424:411
Amundson K., Helfland E., Davis D. D., Quan X., Patel S. S., Smith S. D. (1991) Macromolecules 24:6546
Morkved T. L., Lu M., Urbas A. M., Ehrichs E. E., Jaeger H. M., Mansky P., Russell T. P. (1996) Science 273:931
Xu T., Hawker C. J., Russell T. P. (2003) Macromolecules 36:6178
Kim S. H., Misner M. J., Xu T., Kimura M., Russell T. P. (2004) Advanced Materials 16, 226
Sivaniah E., Hayashi Y., Iino M., Hashimoto T., Fukunaga K. (2003) Macromolecules 36:5894
Sivaniah E., Hayashi Y., Matsubara S., Kiyono S., Hashimoto T., Fukunaga K., Kramer E. J., Mates T. (2005) Macromolecules 38:1837
Turner M. S., Joanny J. F. (1992) Macromolecules 25, 6681
Pickett G. T., Witten T. A., Nagel S. R. (1993) Macromolecules 26:3194
Tsori Y., Andelman D. (2003) Macromolecules 36:8560
Fasolka M. J., Harris D. J., Mayes A. M., Yoon M., Mochrie S. G. (1997) Phys. Rev. Lett. 79:3018.
Li Z., Qu S., Rafailovich M. H., Sokolov J., Tolan M., Turner M. S., Wang J., Schwarz S. A., Lorenz H., Kotthaus J. P. (1997) Macromolecules 30:8410.
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Hashimoto, T., Fukunaga, K. (2007). Nanofabrication of Block Copolymer Bulk and Thin Films: Microdomain Structures as Templates. In: Zvelindovsky, A.V. (eds) Nanostructured Soft Matter. NanoScience and Technology. Springer, Dordrecht. https://doi.org/10.1007/978-1-4020-6330-5_2
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