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Models for Isomeric Bispidine Complexes – Accurate Prediction Versus Thorough Understanding

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Models, Mysteries and Magic of Molecules

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Abstract

Bispidine transition-metal complexes possess several unique properties. We suggest these to be derived primarily from the rigid ligand backbone, which enforces specific geometries on the metal center and also produces a large elasticity in the coordination geometries. The unexpected trend of complex stabilities along the series of the first transition-metal row, isomerism of various types and the reactivities of the iron systems towards oxygen activation are reviewed on the basis of the structures enforced by the bispidine ligands; various computational approaches are discussed, which might assist a thorough understanding of the various molecular properties

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Authors
  1. Peter Comba
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  2. Marion Kerscher
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Editor information

Editors and Affiliations

  1. University of Pretoria, South Africa

    Jan C.A. Boeyens

  2. Universidad de Costa Rica, Costa Rica

    J.F. Ogilvie

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Comba, P., Kerscher, M. (2008). Models for Isomeric Bispidine Complexes – Accurate Prediction Versus Thorough Understanding. In: Boeyens, J.C., Ogilvie, J. (eds) Models, Mysteries and Magic of Molecules. Springer, Dordrecht. https://doi.org/10.1007/978-1-4020-5941-4_18

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