STRUCTURE AND FORMATION OF FILMS OF ZIRCONIA-BASED SOLID ELECTROLYTE

  • V.B. MALKOV
  • V.N. STREKALOVSKIY
  • A.V. MALKOV
  • V.G. PUCHIN
  • O.V. MALKOV
  • B.V. SHULGIN
Part of the NATO Security through Science Series A: Chemistry and Biology book series

Abstract

Films of zirconia-based solid electrolytes were prepared by the ionplasma sputtering method. Scanning and transmission electron microscopy methods were used to analyze their structure and processes of their formation. It was found that films of ZrO2 – Y2O3 and ZrO2 – Sc2O3 systems had a nanocrystalline structure. The zirconia-based films were characterized by a columnar structure. A model describing the formation of pores and submicropores during the growth of films of ZrO2 – Y2O3 and ZrO2 – Sc2O3 systems was proposed and discussed.

Keywords

Dioxide Zirconia 

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Copyright information

© Springer 2007

Authors and Affiliations

  • V.B. MALKOV
    • 1
  • V.N. STREKALOVSKIY
    • 1
  • A.V. MALKOV
    • 2
  • V.G. PUCHIN
    • 3
  • O.V. MALKOV
    • 3
  • B.V. SHULGIN
    • 4
  1. 1.Institute of High-Temperature ElectrochemistrySverdlovskRussia
  2. 2.“ROSNA” Scientific and Production CenterEkaterinburgRussia
  3. 3.3Institute of Metal PhysicsEkaterinburgRussia
  4. 4.Ural State Technical UniversityEkaterinburgRussia

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