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STRUCTURE AND FORMATION OF FILMS OF ZIRCONIA-BASED SOLID ELECTROLYTE

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Hydrogen Materials Science and Chemistry of Carbon Nanomaterials

Abstract

Films of zirconia-based solid electrolytes were prepared by the ionplasma sputtering method. Scanning and transmission electron microscopy methods were used to analyze their structure and processes of their formation. It was found that films of ZrO2 – Y2O3 and ZrO2 – Sc2O3 systems had a nanocrystalline structure. The zirconia-based films were characterized by a columnar structure. A model describing the formation of pores and submicropores during the growth of films of ZrO2 – Y2O3 and ZrO2 – Sc2O3 systems was proposed and discussed.

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References

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Author information

Authors and Affiliations

  1. Institute of High-Temperature Electrochemistry, Ural Branch RAS 620219 Ekaterinburg, Sverdlovsk, Russia

    V.B. MALKOV & V.N. STREKALOVSKIY

  2. “ROSNA” Scientific and Production Center, Ekaterinburg, 620219, Russia

    A.V. MALKOV

  3. 3Institute of Metal Physics, Ural Branch RAS, Ekaterinburg, 620219, Russia

    V.G. PUCHIN & O.V. MALKOV

  4. Ural State Technical University, Ekaterinburg, 620219, Russia

    B.V. SHULGIN

Authors
  1. V.B. MALKOV
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  2. V.N. STREKALOVSKIY
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  3. A.V. MALKOV
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  4. V.G. PUCHIN
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  5. O.V. MALKOV
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  6. B.V. SHULGIN
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Editor information

Editors and Affiliations

  1. International Association for Hydrogen Energy, University of Miami, Miami, U.S.A

    T. Nejat Veziroglu

  2. Institute of Hydrogen and Solar Energy, Kiev, Ukraine

    Svetlana Yu. Zaginaichenko

  3. Institute for Problems of Materials Science of NAS, Kiev, Ukraine

    Dmitry V. Schur

  4. Institute of Physical Chemistry of PAS, Warsaw, Poland

    Bogdan Baranowski

  5. Institute for Metal Physics of NAS, Kiev, Ukraine

    Anatoliy P. Shpak

  6. Institute for Problems of Materials Science of NAS, Kiev, Ukraine

    Valeriy V. Skorokhod

  7. UNIDO - Centre for Hydrogen Energy Technologies, Istanbul, Turkey

    Ayfer Kale

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© 2007 Springer

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MALKOV, V., STREKALOVSKIY, V., MALKOV, A., PUCHIN, V., MALKOV, O., SHULGIN, B. (2007). STRUCTURE AND FORMATION OF FILMS OF ZIRCONIA-BASED SOLID ELECTROLYTE. In: Veziroglu, T.N., et al. Hydrogen Materials Science and Chemistry of Carbon Nanomaterials. NATO Security through Science Series A: Chemistry and Biology. Springer, Dordrecht. https://doi.org/10.1007/978-1-4020-5514-0_72

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