ON ELECTROCHEMICAL DEPOSITION OF FULLERENES AND THEIR COMPOUNDS FROM SOLUTIONS

  • N.G. KHOTYNENKO
  • D.V. SCHUR
  • S. YU. ZAGINAICHENKO
  • A.F. SAVENKO
  • V.M. ADEEV
  • A.A. ROGOZINSKAYA
  • O.V. MIL’TO
  • B.P. TARASOV
  • YU.M. SHUL’GA
Part of the NATO Security through Science Series A: Chemistry and Biology book series

Abstract

The work demonstrates a principle possibility to produce the films of fullerenes and fullerene-containing products from their solutions by the electrochemical method. Electrical properties of fullerene solutions have been studied. The proposed method can be used for the special-purpose application of fullerene-containing coatings and for synthesis of fullerene compounds with organic and inorganic substances.

Keywords

Nickel Filtration Carbide Phenol Chromium 

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References

  1. 1.
    Saito I.G., Teramoto T., Otsuka A., Sugita Y., Ban T., Kusunoki M. Preparation and ionicity of C60 charge transfer complexes. Synt Met 1994; 64: 359.CrossRefGoogle Scholar
  2. 2.
    Rosseinsky M.J. Fullerene intercalation chemistry. J Mater Chem 1995;5:1497–513.CrossRefGoogle Scholar
  3. 3.
    Tanigaki K., Prassides K. Conducting and superconducting properties of alkali metal-C60 fullerides. J Mater Chem 1995; 5: 1515–27.CrossRefGoogle Scholar
  4. 4.
    Baenitz M., Heinze M., Luders K., Werner H., Schlogl R., Weiden M., et al. Superconductivity of Ba doped C60 susceptibility results and upper critical field. Solid State Commun 1995; 96: 539–44.CrossRefGoogle Scholar
  5. 5.
    Dubois D., Kadish K.M., Flanagan S., Haufler R.F., Chibante L.P.F., Wilson L.J. Spectroelectrochemical study of the C60 and C70 fullerenes and their mono-, di, tri- and tetraanions. J Amer Chem Soc 1991; 113(11): 4364–6.CrossRefGoogle Scholar
  6. 6.
    Xie Q., Perez-Cordero E., Echegoyen L. Electrochemical detection of C60 6- and C6- 70 : enhanced stability of fullerides in solution. J Amer Chem Soc 1992; 114(10): 3978–80.CrossRefGoogle Scholar
  7. 7.
    Zhou F., Jeboulet C., Bard A.J. Reduction and electrochemistry of fullerene C60 in liquid ammonia. J Amer Chem Soc 1992; 114(27): 11004–6.CrossRefGoogle Scholar
  8. 8.
    Green W.H., Gorun S.M., Fitzgerald G., Fowler P.W., Ceulemans A., Titeca B.C. Electronic structures and geometries of C60 anions via density functional calculations. J Phys Chem 1996; 100(36): 14892–8.CrossRefGoogle Scholar
  9. 9.
    Co D.M., Behal S., Disko M., Gorun S.M., Grang M., Hsu C.S., Kollin E.B., et al. Characterization of C60 and C70 clusters. J Amer Chem Soc 1991; 113(8): 2940–4.CrossRefGoogle Scholar
  10. 10.
    Nuretdinov I.A., Gubskaya V.N., Yanilkin V.V., Morozov V.I., Zverev V.V., Ilyasov A.V., et al. Fullerene-pyrolidine space-embarrased phenol. Synthesis, structure and properties. Izv RAN Ser Khim 2001; 4: 582–7.Google Scholar
  11. 11.
    Kobayashi H., Moriyama H., Kobayashi K., Watanabe T. Synthesis and characterization of some fulleride compounds by electrocrystallization of C60. Synth Met 1995; 70: 1451–2.CrossRefGoogle Scholar
  12. 12.
    Bilow U., Jansen M. Electrocrystallization and crystal structure determination of Ph4PC60 Ph4PCl. J Chem Soc Chem Commun 1994; 4: 403–5.CrossRefGoogle Scholar
  13. 13.
    Schur D.V., Khotynenko N.G., Scherbakova L.G., Adejev V.M., Golovko E.I., Zaginaichenko SYu. Electrochemical method for synthesis of fullerenecontaining compounds and coatings. In: Carbon-2004 Int. Confer. on Carbon, Brown University, USA, 2004: 198.Google Scholar
  14. 14.
    Kolotyrkin Ya.M., editor. Electrochemistry of metals in nonaqueous solutions. Moscow, Russia: Mir; 1974.Google Scholar
  15. 15.
    ASTM, X-ray diffraction date cards, 1995.Google Scholar
  16. 16.
    Gallagher S.H., Armstrong R.S., Lay P.A., Reed C.A. Solvent effects on the electronic spectrum of C60. J Phys Chem 1995; 99(16): 5817–25.CrossRefGoogle Scholar
  17. 17.
    Magdesieva T.V., Bashilov V.V., Kravchuk D.N. Electrochem. in Molecul. and Microscop. Deminsions. In: 53 Meeting of the Int. Soc Electrochem. Book of Abstracts: Franfurt an Main, Germany: Dechema 2002: 337.Google Scholar
  18. 18.
    Rogers W., Kipnes S.M. Polarography of carbonyl compounds in methanol. Anal Chem 1955; 27(12): 1916–8.CrossRefGoogle Scholar
  19. 19.
    Push E.S., Yang N.C. Polarographic oxidation potentials of aromatic compounds. J Amer Chem Soc 1963; 85(14): 2124–30.CrossRefGoogle Scholar

Copyright information

© Springer 2007

Authors and Affiliations

  • N.G. KHOTYNENKO
    • 1
  • D.V. SCHUR
    • 1
  • S. YU. ZAGINAICHENKO
    • 1
  • A.F. SAVENKO
    • 1
  • V.M. ADEEV
    • 1
  • A.A. ROGOZINSKAYA
    • 1
  • O.V. MIL’TO
    • 1
  • B.P. TARASOV
    • 2
  • YU.M. SHUL’GA
    • 2
  1. 1.Institute for Problems of Materials Science of Ukrainian Academy of SciencesKievUkraine
  2. 2.Institute of Problems of Chemical Physics of RASRussia

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