Abstract
The synthesis, isolation and multistage chromatographic separation of the Y2@C84, Ce2@C78 M@C82 (M = Y, La, Ce, Gd) was carried out. All these newly synthesized metallofullerenes are characterized by S8-MALDI mass spectrometry and UV-vis-NIR absorption spectroscopy.
This is a preview of subscription content, log in via an institution.
Buying options
Tax calculation will be finalised at checkout
Purchases are for personal use only
Learn about institutional subscriptionsPreview
Unable to display preview. Download preview PDF.
References
Shinohara H. (2000) Endohedral metallofullerenes. Rep. Prog. Phys. 63: 843 –892.
Bolskar R.D., Benedetto A.F., Husebo L.O., Price R.E., Jackson E.F., Wallase S., et al. (2003) First soluble M@C60 derivatives provide enhanced access to metallofullerenes and permit in vivo evaluation of Gd @C60[C(COOH)2]10 as a MRI contrast agent. J. Am. Chem. Soc. 125: 5471 –5478.
Bubnov V.P., Kareev I.E., Laukhina E.E., Buravov L.I., Koltover V.K., Yagubskii E.B. (2002) Electric Conduction Properties of M@C2n Endohedral Metallofullerenes (M = La, Y). Physics of the Solid State 44 (3): 527 –528.
Masahito M., Haruhito K., Masafumu O., Michiko N., Yoko, Naoto M., et al. (2001) Paramagnetic Water-Soluble Metallofullerenes Having the Highest Relaxivity for MRI Contrast Agents Boiconjugate Chem. 12: 510 –514.
Ding J.Q., Yang S.H. (1996) Isolation and characterization of the dimetallofullerene Ce2 @C80. Angew. Chem. Int. Ed. Engl 35: 2234 –2235.
Nishibori E., Takata M., Sakata M., Taninaka A., and Shinohara H. (2001) Pentagonal-Dodecahedral La2 Charge Density in [80-Ih]Fullerene: La2 @C80. Angew. Chem. Int. Ed. Engl. 40: 2998 –2999.
Akasaka T., Nagase S., Kobayashi K., Waelchli M., Yamamoto K., Funasaka H., et al. (1997) 13C and 139La NMR studies of La2 @C80: First evidence for circular motion of metal atoms in endohedral dimetallofullerenes. Angew. Chem., Int. Ed. Engl. 36: 1643 –1645.
Bubnov V.P., Laukhina E.E., Kareev I.E., Koltover V.K., Prokhorova T.G., Yagubskii E.B., et al. (2002) Endohedral Metallofullerenes: A Convenient Gram-Scale Preparation. Chem. Mater. 14: 1004 –1008.
Laukhina E.E., Bubnov V.P., Estrin Ya.I., Golub Y.I., Khodorkovskii M.A., Koltover V.K. et al. (1998) Novel proficient method for isolation of endometallofullerenes from fullerene-containing soots by two-step o-xylene - N, N-dimetilformamide extraction. J. Mater. Chem. 8: 893 –895.
Cao B., Wakahara T., Tsuchiya T., Kondo M., Maeda Y., Rahman G.M.A. et al. (2004) Isolation, Characterization, and Theoretical Study of La2 @C78. J. Am. Chem. Soc. 126: 9164 –9165.
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2007 Springer
About this paper
Cite this paper
KAREEV, I., BUBNOV, V., YAGUBSKII, E., LEBEDKIN, S. (2007). SYNTHESIS, ISOLATION AND SPECTROSCOPIC STUDY OF A SERIES OF ENDOHEDRAL METALLOFULLERENES Y2@C84, Ce2@C78 AND M@C82 (M = Y, La, Ce, Gd). In: Veziroglu, T.N., et al. Hydrogen Materials Science and Chemistry of Carbon Nanomaterials. NATO Security through Science Series A: Chemistry and Biology. Springer, Dordrecht. https://doi.org/10.1007/978-1-4020-5514-0_30
Download citation
DOI: https://doi.org/10.1007/978-1-4020-5514-0_30
Publisher Name: Springer, Dordrecht
Print ISBN: 978-1-4020-5512-6
Online ISBN: 978-1-4020-5514-0
eBook Packages: Chemistry and Materials ScienceChemistry and Material Science (R0)