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CONDUCTIVITY OF C60 FULLERENE CRYSTALS UNDER MULTI-STEP DYNAMIC COMPRESSION UP TO 300 KBAR

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Hydrogen Materials Science and Chemistry of Carbon Nanomaterials

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Abstract

In the present work the conductivity of fullerene C60 crystals has been measured under smooth shock wave quasi-isentropic loading conditions up to 30 GPa at initial temperature T=293 K. Not monotone behavior of conductivity has been revealed under compression of crystal with pressure increasing: -at first conductivity grows by many orders then it falls very fast. Conductivity increasing is explained by decreasing of bandgap of C60 under compression whereas conductivity decreasing can be explained on the assumption that the energy barrier of polymerization ofC60 reduces with pressure increasing approximately in the same measure, as band-gap energy.

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References

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Author information

Authors and Affiliations

  1. Institute of Problems of Chemical Physics of Russian Academy of Science, 142432 Chernogolovka, Moscow Region, Russia

    V.V. AVDONIN, V.I. POSTNOV, K.L. KAGAN, D.V. SHAKHRAY, V.E. FORTOV & A.F. SHESTAKOV

  2. Institute of Solid State Physics of Russian Academy of Science, 142432 Chernogolovka, Moscow Region, Russia

    R.K. NIKOLAEV, N.S. SIDOROV, V.V. KVEDER & YU. A. OSIP’YAN

Authors
  1. V.V. AVDONIN
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  2. V.I. POSTNOV
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  3. K.L. KAGAN
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  4. D.V. SHAKHRAY
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  5. V.E. FORTOV
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  6. A.F. SHESTAKOV
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  7. R.K. NIKOLAEV
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  8. N.S. SIDOROV
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  9. V.V. KVEDER
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  10. YU. A. OSIP’YAN
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Editor information

Editors and Affiliations

  1. International Association for Hydrogen Energy, University of Miami, Miami, U.S.A

    T. Nejat Veziroglu

  2. Institute of Hydrogen and Solar Energy, Kiev, Ukraine

    Svetlana Yu. Zaginaichenko

  3. Institute for Problems of Materials Science of NAS, Kiev, Ukraine

    Dmitry V. Schur

  4. Institute of Physical Chemistry of PAS, Warsaw, Poland

    Bogdan Baranowski

  5. Institute for Metal Physics of NAS, Kiev, Ukraine

    Anatoliy P. Shpak

  6. Institute for Problems of Materials Science of NAS, Kiev, Ukraine

    Valeriy V. Skorokhod

  7. UNIDO - Centre for Hydrogen Energy Technologies, Istanbul, Turkey

    Ayfer Kale

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AVDONIN, V. et al. (2007). CONDUCTIVITY OF C60 FULLERENE CRYSTALS UNDER MULTI-STEP DYNAMIC COMPRESSION UP TO 300 KBAR. In: Veziroglu, T.N., et al. Hydrogen Materials Science and Chemistry of Carbon Nanomaterials. NATO Security through Science Series A: Chemistry and Biology. Springer, Dordrecht. https://doi.org/10.1007/978-1-4020-5514-0_3

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