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Hydrogen Materials Science and Chemistry of Carbon Nanomaterials pp 235–242Cite as

TRIFLUOROMETHYLATION OF ENDOHEDRAL METALLOFULLERENES M@C82(M = Y, Ce): SYNTHESIS, ISOLATION AND STRUCTURE

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Abstract

Endohedral metallofullerenes were for the first time trifluoromethylated to afford the isolation and characterization of two isomers of Y@C82(CF3)5 and of three isomers of Ce@C82(CF3)5. All of the purified new compounds were characterized by S8-MALDI mass spectrometry, UV-vis and by 1D and 2D-COSY 19F NMR spectroscopy. The most probable structures proposed from the NMR data and quantum chemical calculations, contain 1,4 chains of CF3 groups.

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Authors and Affiliations

  1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow Region, 142432, Russia

    I.E. KAREEV

  2. Forschungszentrum Karlsruhe, Institute for Nanotechnology, Karlsruhe, 76021, Germany

    I.E. KAREEV

  3. Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow Region, 142432, Russia

    V.P. BUBNOV, D.N. FEDUTIN & E.B. YAGUBSKII

  4. Forschungszentrum Karlsruhe, Institute for Nanotechnology, Karlsruhe, 76021, Germany

    S.F. LEBEDKIN

  5. Institut de Ciencia de Materials de Barcelona CSIC, Campus UAB, Bellaterra, E-08193, Spain

    E.E. LAUKHINA

  6. Department of Chemistry, Colorado State University, Fort Collins, CO, 80523, USA

    I.V. KUVYCHKO, S.H. STRAUSS & O.B. BOLTALINA

Authors
  1. I.E. KAREEV
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  2. V.P. BUBNOV
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  3. D.N. FEDUTIN
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  4. E.B. YAGUBSKII
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  5. S.F. LEBEDKIN
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  6. E.E. LAUKHINA
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  7. I.V. KUVYCHKO
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  8. S.H. STRAUSS
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  9. O.B. BOLTALINA
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Editor information

Editors and Affiliations

  1. International Association for Hydrogen Energy, University of Miami, Miami, U.S.A

    T. Nejat Veziroglu

  2. Institute of Hydrogen and Solar Energy, Kiev, Ukraine

    Svetlana Yu. Zaginaichenko

  3. Institute for Problems of Materials Science of NAS, Kiev, Ukraine

    Dmitry V. Schur

  4. Institute of Physical Chemistry of PAS, Warsaw, Poland

    Bogdan Baranowski

  5. Institute for Metal Physics of NAS, Kiev, Ukraine

    Anatoliy P. Shpak

  6. Institute for Problems of Materials Science of NAS, Kiev, Ukraine

    Valeriy V. Skorokhod

  7. UNIDO - Centre for Hydrogen Energy Technologies, Istanbul, Turkey

    Ayfer Kale

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© 2007 Springer

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KAREEV, I. et al. (2007). TRIFLUOROMETHYLATION OF ENDOHEDRAL METALLOFULLERENES M@C82(M = Y, Ce): SYNTHESIS, ISOLATION AND STRUCTURE. In: Veziroglu, T.N., et al. Hydrogen Materials Science and Chemistry of Carbon Nanomaterials. NATO Security through Science Series A: Chemistry and Biology. Springer, Dordrecht. https://doi.org/10.1007/978-1-4020-5514-0_29

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