MgH2–CARBON COMPOSITES FOR HYDROGEN STORAGE

LUKASHEV, R.V.; TARASOV, B.P.; KLYAMKIN, S.N.

doi:10.1007/978-1-4020-5514-0_24

MgH₂–CARBON COMPOSITES FOR HYDROGEN STORAGE

R.V. LUKASHEV⁸,
B.P. TARASOV⁸ &
S.N. KLYAMKIN⁹

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Part of the book series: NATO Security through Science Series A: Chemistry and Biology ((NASTA))

Abstract

Peculiarities of hydrogenation reactions of magnesium at temperatures of 410°C to 450°C and pressures of 15 to 55 MPa have been investigated. Interactions in MgH₂–graphite system under quasihydrostatic conditions (3 GPa, 800°C, 1 h) have been explored. It has been shown that such a treatment did not lead to formation of new chemical compounds. The phase transformation of MgH₂ to a metastable high-pressure modification has been found. As a result of mechanochemical activation, the MgH₂–graphite and MgH₂–CNF composites have been obtained. It has been pointed that the mechanical activation of mixtures of magnesium hydride with carbon affect strongly the kinetic parameters of hydrogen desorption but also led to decreasing the thermal stability of the hydride phase.

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References

Zaluska, A., Zaluska, L., and Strom-Olsen, J.O. (1999) J. Alloys Comp., 288, 217–225.
Article CAS Google Scholar
Imamura, H., Tabata, Sh., Sakata, Y., et al. (2002) J. Alloys Comp., 330, 579–583.
Article Google Scholar
Klyamkin, S.N., Tarasov, B.P., Straz, E.L., Lukashev, R.V., Gabis, I.E., Evard, E.A., and Voyt, A.P. (2005) Int. J. Alternative Energy and Ecology, No. 1, 5–7.
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Authors and Affiliations

Institute of Problems of Chemical Physics of RAS Chernogolovka, Moscow region, 142432, Russian Federation
R.V. LUKASHEV & B.P. TARASOV
Chemistry Department, Moscow State University, Moscow, 119992, Russian Federation
S.N. KLYAMKIN

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R.V. LUKASHEV
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B.P. TARASOV
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S.N. KLYAMKIN
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Editors and Affiliations

International Association for Hydrogen Energy, University of Miami, Miami, U.S.A
T. Nejat Veziroglu
Institute of Hydrogen and Solar Energy, Kiev, Ukraine
Svetlana Yu. Zaginaichenko
Institute for Problems of Materials Science of NAS, Kiev, Ukraine
Dmitry V. Schur
Institute of Physical Chemistry of PAS, Warsaw, Poland
Bogdan Baranowski
Institute for Metal Physics of NAS, Kiev, Ukraine
Anatoliy P. Shpak
Institute for Problems of Materials Science of NAS, Kiev, Ukraine
Valeriy V. Skorokhod
UNIDO - Centre for Hydrogen Energy Technologies, Istanbul, Turkey
Ayfer Kale

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LUKASHEV, R., TARASOV, B., KLYAMKIN, S. (2007). MgH₂–CARBON COMPOSITES FOR HYDROGEN STORAGE. In: Veziroglu, T.N., et al. Hydrogen Materials Science and Chemistry of Carbon Nanomaterials. NATO Security through Science Series A: Chemistry and Biology. Springer, Dordrecht. https://doi.org/10.1007/978-1-4020-5514-0_24

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DOI: https://doi.org/10.1007/978-1-4020-5514-0_24
Publisher Name: Springer, Dordrecht
Print ISBN: 978-1-4020-5512-6
Online ISBN: 978-1-4020-5514-0
eBook Packages: Chemistry and Materials ScienceChemistry and Material Science (R0)

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