Abstract
It has been revealed that carbonic nanomaterials (fullerene, single- and multiwall nanotubes, nanofibers) display high activity at low temperatures (77K) in reactions of chain halogenation (F2, Cl2) with kinetic chain length up to 104–105. The ESR spectra of active free- radical intermediates were recorded. The presence of vibration bands of C–Cl bonds in products has been indicated by IR method.
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MIKHAYLOV, A. et al. (2007). FREE RADICAL HALOGENATION OF CARBON NANOMATERIALS AT LOW TEMPERATURES. In: Veziroglu, T.N., et al. Hydrogen Materials Science and Chemistry of Carbon Nanomaterials. NATO Security through Science Series A: Chemistry and Biology. Springer, Dordrecht. https://doi.org/10.1007/978-1-4020-5514-0_18
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DOI: https://doi.org/10.1007/978-1-4020-5514-0_18
Publisher Name: Springer, Dordrecht
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Online ISBN: 978-1-4020-5514-0
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