• D.V. SCHUR
Part of the NATO Security through Science Series A: Chemistry and Biology book series


The statistical theory of processes of phase transformations realized by hydrogenation of metalfulleride has been developed in present paper. Such reaction was studied experimentally for fullerides of palladium and platinum [1, 2].


Free Energy Hydrogen Atom Hydrogen Concentration Interstitial Site Platinum Atom 
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  1. 1.
    Jin C., Hettich R.L., Compton R.N., Jouce D., Blencoe J., Burch T. Direct solid-phase hydrogenation of fullerenes. // Journ. Phys. Chem. 1994. Vol. 98. P. 4215–4220.CrossRefGoogle Scholar
  2. 2.
    Avent A.G., Birkett P.R., Darwish A.D., Kroto H.W., Taylor R., Walton D.R.M. Fullerene and atomic clusters: Proceed. Int. Workshop IWPAC’95. St. Peterburg. 1995. P. 7.Google Scholar
  3. 3.
    Lobach A. S., Tarasov B.P., Shul’ga Yu.M., Perov A. A. and Stepanov. N. The D2 reaction with palladium fulleride C60Pd4,9 // Izv. RAN, Ser. khim. 1996. No 2. P. 483–494.Google Scholar
  4. 4.
    Tarasov B.P., Fokin V.N., Moravsky A. P., Shul’ga Yu. M. Hydrogenation of fullerites in the presence of intermetallic compounds and metals // Izv. RAN, Ser. khim. 1997. No 4. P. 679–683.Google Scholar
  5. 5.
    Tarasov B.P., Fokin V.N., Moravsky. P., Shul’ga Yu. M. Transformations in fullerene-intermetallic compound-hydrogen systems // Zhurn. neorg. khimii. 1997. Vol. 42. P. 920.Google Scholar
  6. 6.
    Tarasov B.P., Fokin V.N., Moravsky A.P., Shulga Yu.M., Yartys V.A. Hydrogenation of fullerenes C60 and C70 in presence of hydride-forming metals and metallic compounds // J. Alloy and Comp. 1997. Vol. 25. P. 253–254.Google Scholar
  7. 7.
    Tarasov B.P., Fokin V.N., Moravsky A.P., Shulga Yu.M., Yartys V.A., Schur D.V. Promotion of fullerene hydride synthesis by intermetallic compounds // Proceed. 12th World Hydrogen Energy Conf. Buenos Aires. Argentine. 1998. Vol. 2. P. 1221.Google Scholar
  8. 8.
    Tarasov B.P. Mechanism of hydrogenation of fullerite-metallic compositions // Zhurn. obshchei khimii. 1998. Vol. 68, No 8, P. 1245–1248.MathSciNetGoogle Scholar
  9. 9.
    Goldshleger N.F., Tarasov B.P., Shul’ga Yu.M., Perov A. A., Roschupkina A. S. and Moravsky A.P. Interaction of platinum fulleride C60Pt with deuterium // Izv. RAN, Ser. khim. 1999. No 5. P. 999–1002.Google Scholar
  10. 10.
    Tarasov B.P., Fokin V.N., Moravsky A.P., Shulga Yu.M. Synthesis and properties of crystallic hydrides of fullerenes // Izv. RAN, Ser. khim. 1998. No 10. P. 2093–2096.Google Scholar
  11. 11.
    Shul’ga Yu.M., Tarasov B.P., Fokin V.N., Shul’ga N.Yu. and Vasilets V.N. Crystallic deuteride of fullerenes C60D2: investigation by spectral methods // Fizika tv. tela. 1999. Vol. 41. No 8. p. 1520–1526.Google Scholar
  12. 12.
    Hirsch A. Chemistry of fullerenes. Stuttgart: Thieme Verlag. 1994. Ch. 5. P. 117–130.Google Scholar
  13. 13.
    Shul’ga Yu.M., Tarasov B.P. Fullerite C60 with “extended” fcc lattice // Pis’ma v Zhurn. experim. teoret. fiziki. 1998. Vol. 68 No 3. P. 239–242.Google Scholar
  14. 14.
    Shul’ga Yu.M., Tarasov B.P. Crystallic hydrofullerenes: production and properties. In “Fullerenes and fullerenelike structures”. 2000. Minsk: BGU. P. 14–19.Google Scholar
  15. 15.
    Tarasov B.P. Hydrogen accumulation in carbon nanostructures, In “Fullerenes and fullerenelike structures”. 2000. Minsk: BGU. P. 113–120.Google Scholar
  16. 16.
    Smirnov A. A. Theory of phase transformations and atoms distribution in interstitial alloys. K.: Nauk. dumka. 1992. 280 p.(in Russian).Google Scholar
  17. 17.
    Shul’tse G. Mettallophysics. M.: Mir. 1971. 504 p. (in Russian).Google Scholar
  18. 18.
    Sokolov V.I., Stankevich I.V. Fullerenes and new allotropic forms of carbon: structures, electronic structures, chemical properties // Usp. khimii. 1993. Vol. 62. No 5. P. 455–473.Google Scholar
  19. 19.
    Boba M.S., T.S.L., Balssubtamaian R. et al. Studies on the thermodynamics of the C60-C70 binary system // Journ. Phys. Chem. 1994. Vol. 98. P. 1333–1340.CrossRefGoogle Scholar
  20. 20.
    Kniaz K., Fisher J.E., Girifalco L.A. et al. Fullerene alloys // Sol. State Comm. 1995. Vol. 96. P. 739–743.CrossRefGoogle Scholar
  21. 21.
    Havlik D., Schranz W., Haluska M., Kuzmany N., Rogl P. Thermal expansion measurements of C60-C70 mized crystals // Sol. State Comm. 1997. Vol. 104. P. 775–779.CrossRefGoogle Scholar
  22. 22.
    Bezmelnitsin V.N., Eletskiy V., Okun M.V. Fullerenes in solutions // Usp. fiz. nauk. 1998. Vol. 168. P. 1195–1221.CrossRefGoogle Scholar
  23. 23.
    Vovk O. M., Isakina A.P., Garbuz A.S. and Kravchenko Yu.G. Solid solutions of fullerenes C60-C70 produced from hexane-toluene solution. In “Fullerenes and fullerenelike structures”. 2000. Minsk: BGU. P. 70–76.Google Scholar
  24. 24.
    Girifalco L.A. Molecular properties of C60 in the gas and solid phases. // Journ. Phys. Chem. 1992. Vol. 96. P. 858–861.CrossRefGoogle Scholar
  25. 25.
    Eletskiy. F., Smirnov B. M. Fullerenes and carbon structures // Usp. fiz. nauk. 1995. Vol. 165. No 9. P. 977–1009.CrossRefGoogle Scholar
  26. 26.
    David W.I., Ibberson R.M., Dennis T.J.S., Harr J.P., Prassides K. // Europhys. Lett. 1992. Vol. 18. P. 219.ADSCrossRefGoogle Scholar
  27. 27.
    Blinc R., Selinger J., Dolinsek J., Arcon D. // Phys. Rev. B. 1994. Vol. 49. P. 4993.CrossRefADSGoogle Scholar
  28. 28.
    Brazhkin V.V., Lyapin A. G. Transformation of fullerite C60 at high pressure and temperature // Usp. fiz. nauk. 1996. Vol. 166. P. 893–897.Google Scholar
  29. 29.
    Tareeva E. E., Schelkacheva T. I. Orientantional ordering in solid C60: branching method // Teor. matem. fiz. 1999. Vol. 121. No 3. P. 479–491.Google Scholar
  30. 30.
    Makarova T. L. Electrical and optical properties of monomerical and polymerical fullerenes (review) // Fiz. i tekhnika polyprovodnikov. 2001. Vol. 35. No 3. P. 257–293.Google Scholar

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© Springer 2007

Authors and Affiliations

    • 1
    • 2
  • D.V. SCHUR
    • 2
    • 3
    • 4
  1. 1.Dnepropetrovsk National UniversityDnepropetrovskUkraine
  2. 2.Institute for Problems of Materials Science of NAS of UkraineKyivUkraine
  3. 3.G.V. Kurdyumov Institute for Metal PhysicsKyyiv-142Ukraine
  4. 4.International Association for Hydrogen Energy University of MiamiMiamiUSA

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