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The effect of hydrogen on fatigue properties of metals used for fuel cell system

  • Conference paper
Advances in Fracture Research

Abstract

The effect of hydrogen on the fatigue properties of alloys which are used in fuel cell (FC) systems has been investigated. In a typical FC system, various alloys are used in hydrogen environments and are subjected to cyclic loading due to pressurization, mechanical vibrations, etc. The materials investigated were three austenitic stainless steels (SUS304, SUS316 and SUS316L), one ferritic stainless steel (SUS405), one martensitic stainless steel (0.7C-13Cr), a Cr-Mo martensitic steel (SCM435) and two annealed medium-carbon steels (0.47 and 0.45%C). In order to simulate the pickup of hydrogen in service, the specimens were charged with hydrogen. The fatigue crack growth behaviour of charged specimens of SUS304, SUS316, SUS316L and SUS405 was compared with that of specimens which had not been hydrogen-charged. The comparison showed that there was a degradation in fatigue crack growth resistance due to hydrogen in the case of SUS304 and SUS316 austenitic stainless steels. However, SUS316L and SUS405 showed little degradation due to hydrogen. A marked increase in the amount of martensitic transformation occurred in the hydrogen-charged SUS304 specimens compared to specimens without hydrogen charge. In case of SUS316L, little martensitic transformation occurred in either specimens with and without hydrogen charge. The results of S-N testing showed that in the case of the 0.7C-13Cr stainless steel and the Cr-Mo steel a marked decrease in fatigue resistance due to hydrogen occurred. In the case of the medium carbon steels hydrogen did not cause a reduction in fatigue behaviour. Examination of the slip band characteristics of a number of the alloys showed that slip was more localized in the case of hydrogen-charged specimens. Thus, it is presumed that a synergetic effect of hydrogen and martensitic structure enhances degradation of fatigue crack resistance.

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References

  • Au, J.J. and Birnbaum, H.K. (1973). Magnetic relaxation studies of hydrogen in iron: relaxation spectra. Scripta Metallurgica 7, 595–604.

    Article  Google Scholar 

  • Benson, Jr. R.B., Dann, R.K. and Robert, Jr. L.W. (1968). Hydrogen embrittlement of stainless steel. Transformation of the Metallurgical Society of AIME 242, 2199–2205.

    Google Scholar 

  • Birnbaum, H.K., Robertson, I.M. and Sofronis, P. (2000). Hydrogen effects on plasticity. In: Multiscale Phenomena in Plasticity, (edited by Lepinoux, J.), Kluwer Academic Publishers, Dordrecht.

    Google Scholar 

  • Birnbaum, H.K. and Sofronis, P. (1994). Hydrogen-enhanced localized plasticity-a mechanism for hydrogen-related fracture. Material Science and Engineering A176, 191–202.

    Article  Google Scholar 

  • Brass, A.M. and Chene, J. (1998). Influence of deformation on the hydrogen behavior in iron and nickel base alloys: a review of experimental data. Material Science and Engineering, A242, 210–221.

    Article  Google Scholar 

  • Clum, J.A. (1975). The role of hydrogen in dislocation generation in iron alloys. Scripta Metallurgica 9, 51–58.

    Article  Google Scholar 

  • Dufresne, J.F. and Seeger, A. (1976). Hydrogen relaxation in α-iron. Groh P. and Moser P., Physics Statistics Solutions (a) 36, 579–589.

    Article  Google Scholar 

  • Farrell, K. and Quarrell, A.G. (1964). Hydrogen embrittlement of an ultra-high-tensile steel. Journal of the Iron and Steel Institute December, 1002–1011.

    Google Scholar 

  • Fiedler, H.C., Averbach, B.L. and Cohen M. (1954). The effect of deformation on the martensitic transformation in austenitic stainless steels. Transaction of the ASME 47, 267–290.

    Google Scholar 

  • Heller, W.R. (1961). Quantum effects in diffusion: internal friction due to hydrogen and deuterium dissolved in α iron. Acta Metallurgica 9, 600–613.

    Article  Google Scholar 

  • Herms, E., Olive, J.M., Puiggali, M. (1999). Hydrogen embrittlement of 316L type stainless steel. Materials Science and Engineering A272, 279–283.

    Google Scholar 

  • Hirth, J.P. (1980). Effect of hydrogen on the properties of iron and steel. Metallurgical Transactions A 11A, 861–890.

    Google Scholar 

  • Kanezaki, T., Mine, Y., Fukushima, Y. and Murakami, Y. (2004). Effects of hydrogen on fatigue crack growth behaviour and ductility loss of austenitic stainless steels. Proc. of ECF15, CD-ROM.

    Google Scholar 

  • Kimura, H. and Matsui, H. (1979). Reply to “further discussion on the lattice hardening due to dissolved hydrogen in iron and steel” by Asano and Otsuka. Scripta Metallurgica 13, 221–223.

    Article  Google Scholar 

  • Magnin, T., Bosch, C., Wolski, K. and Delafosse, D. (2001). Cyclic plastic deformation behaviour of Ni single crystals oriented for single slip as a function of hydrogen content. Material Science and Engineering A314, 7–11.

    Article  Google Scholar 

  • Matsui, H. and Kimura, H. (1979). The effect of hydrogen on the mechanical properties of high purity iron III. The dependence of softening on specimen size and charging current density. Material Science and Engineering 40, 227–234.

    Article  Google Scholar 

  • Mignot, F., Doquet, V. and Sarrazin-Baudoux, C. (2004). Contribution of internal hydrogen and roomtemperature creep to the abnormal fatigue cracking of Ti6246 at high K max. Material Science Engineering A380, 308–319.

    Article  Google Scholar 

  • Murakami, Y. (2002). Metal Fatigue: Effect of Small Defects and Nonmetallic Inclusions, Elsevier, Oxford.

    Google Scholar 

  • Murakami, Y. (2004). Keynote lecture, The Kick-off Conference for the Fukuoka Hydrogen Energy Project Alliance, August, 3.

    Google Scholar 

  • Murakami, Y. and Endo, M. (1986a). Effects of hardness and crack geometry on ΔK th of small cracks. Journal of the Society of Material Science Japan 35, 911–917.

    Google Scholar 

  • Murakami, Y. and Endo, M. (1986b). Effects of hardness and crack geometries on ΔK th of small cracks emanating from small defects. In: The Behaviour of Short Fatigue Cracks, EGF Pub.1, (edited by Miller, K.J. and delos Rios ), Mechanical Engineering Publications, London, 275–293.

    Google Scholar 

  • Murakami, Y. (Yukitaka), Konishi, H., Takai, K., Murakami Y. (Yasuo) (2000). Acceleration of superlong fatigue failure by hydrogen trapped by inclusions and elimination of conventional fatigue limit. Tetsu-to-Hagane 86, 777–783.

    Google Scholar 

  • Murakami, Y., Makabe, C. and Nisitani, H. (1989). Effects of small surface cracks on ductility loss in low cycle fatigue of 70 / 30 brass. Journal of Testing and Evaluation. JTEVA 17, 20–27.

    Google Scholar 

  • Murakami, Y. and Miller, K.J. (2005). What is fatigue damage? A viewpoint from the observation of low cycle fatigue process, International Journal of Fatigue 27, 991–1005.

    Article  Google Scholar 

  • Murakami, Y. and Nagata J. (2005). Effect of hydrogen on high cycle fatigue failure of high strength steel, SCM435. Journal of the Society of Material Science Japan 54, 420–427.

    Article  Google Scholar 

  • Murakami, Y., Nomoto, T., Ueda, T. (1999). Factors influencing the mechanism of superlong fatigue failure in steels. Fatigue Fracture Engineering Material Structures 22, 581–590.

    Article  Google Scholar 

  • Murakami, Y. (Yukitaka), Ueda, T., Nomoto, T., Murakami, Y. (Yasuo) (1998). Analysis of the mechanism of superlong fatigue failure by optical microscope and SEM/AFM observations. Proceedings of the 24th Symposium on Fatigue, 47–50.

    Google Scholar 

  • Murakami, Y. (Yukitaka), Ueda, T., Nomoto, T., Murakami, Y. (Yasuo) (2000). Mechanism of superlong fatigue failure in the regime of N>107 cycles and fractography of the fracture surface. Transactions of the Japan Society of Mechanical Engineers A66, 311–319.

    Google Scholar 

  • Murakami, Y., Yokoyama, N.N. and Takai, K. (2001). Effect of hydrogen trapped by inclusions on ultra-long life fatigue failure of bearing steel. Journal of the Society of Material Science Japan 50, 1068–1073.

    Google Scholar 

  • Nagata, J. and Murakami, Y. (2003). Factors influencing the formation of ODA in ultralong fatigue regime. Journal of the Society of Material Science Japan 52, 966–973.

    Google Scholar 

  • Sakamoto, Y. and Katayama, H. (1982). The electrochemical determination of diffusivity and solubility of hydrogen in an austenitic type 304 steel. Journal of the Japan Institute Metals 46, 805–814.

    Google Scholar 

  • Senkov, O.N. and Jonas, J.J. (1996). Dynamic strain aging and hydrogen-induced softening in alpha titanium. Metallurgica and Materials Transactions A 27A, 1877–1887.

    Google Scholar 

  • Shih, D.S., Robertson, I.M. and Birnbaum, H.K. (1988). Hydrogen embrittlement of α titanium: in situ TEM studies. Acta Metallurgica 36, 111–124.

    Article  Google Scholar 

  • Shiina, T., Nakamura, T. and Noguchi, T. (2004). Effect of stress ratio on surface-and interior-originating fatigue properties of high strength steel. Transactions of the Japan Society of Mechanical Engineers A70, 1042–1049.

    Google Scholar 

  • Takai, K., Homma, Y., Izutsu, K. and Nagumo, M. (1996). Identification of trapping sites in highstrength steels by secondary ion mass spectrometry for thermally desorbed hydrogen. Journal of the Japan Institute Metals 60, 1155–1162.

    Google Scholar 

  • Uyama, H., Mine, Y. and Murakami, Y. (2004). Effects of hydrogen charge on cyclic stress-strain properties and fatigue behaviour. Proceedings of ECF15 (2004) CD-ROM. 197–209

    Google Scholar 

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Authors and Affiliations

  1. Department of Mechanical Engineering Science, Kyushu University, 6-10-1 Hakozaki, Higashi-ku, Fukuoka, 812-8581, Japan

    Y. Murakami

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  1. Y. Murakami
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Editors and Affiliations

  1. Politecnico di Torino, Torino, Italy

    Alberto Carpinteri

  2. University of Sydney, Sydney, Australia

    Yiu-Wing Mai

  3. University of California, Berkeley, USA

    Robert O. Ritchie

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© 2006 Springer

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Murakami, Y. (2006). The effect of hydrogen on fatigue properties of metals used for fuel cell system. In: Carpinteri, A., Mai, YW., Ritchie, R.O. (eds) Advances in Fracture Research. Springer, Dordrecht. https://doi.org/10.1007/978-1-4020-5423-5_10

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  • DOI: https://doi.org/10.1007/978-1-4020-5423-5_10

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  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-1-4020-4626-1

  • Online ISBN: 978-1-4020-5423-5

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