Applications to Polymer Science

Chapter

Abstract

ESR spectroscopic applications to polymer science are presented. ESR parameters used for the molecular and material characterization of polymer materials are reviewed. It is emphasized that ESR studies of the polymer science are particularly effective in three areas. (1) Intermediate species such as free radicals produced in chemical reactions of polymer materials can be directly detected. (2) The temperature dependent ESR spectra of free radicals trapped in the polymer matrices are very effective for the evaluation of molecular mobility (molecular motion) of polymer chains. (3) The mobility of electron, the structure of solitons, and the doping behavior in conduction polymers can be observed in detail in order to clarify the mechanism of conduction.

Keywords

Migration Anisotropy Polyethylene Milling Soliton 

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Copyright information

© Springer Science+Business Media B.V. 2011

Authors and Affiliations

  • Anders Lund
    • 1
  • Masaru Shiotani
    • 2
  • Shigetaka Shimada
    • 3
  1. 1.Department of Physics, Chemistry and Biology, IFMLinkoping UniversityLinkopingSweden
  2. 2.Graduate School of EngineeringHiroshima UniversityHigashi-HiroshimaJapan
  3. 3.Graduate School of EngineeringNagoya Institute of TechnologyOwari-AsahiJapan

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