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Multipole — Induced Dipole Contributions to the Far-Infrared Spectra of Diatomic Molecules in Non-Polar Solvents

  • A. Medina
  • J. M. M. Roco
  • A. Calvo Hernández
  • S. Velasco
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  • 202 Downloads
Part of the NATO Science Series book series (NAII, volume 133)

Abstract

In this paper we overview our work on far-infrared spectroscopy of both hetero- and homonuclear diatomic molecules in nonpolar fluids. Special attention is paid to electric multipolar induced contributions. From comparison between theoretical and experimental spectra estimation of the leading multipoles of CO and N2 molecules has been obtained. Also a temperature and density dependence analysis of many-body cancellation effects in the different pure induced components of the far-infrared integrated absorption coefficient of CO in liquid Ar is reported.

Keywords

Dipole Moment Diatomic Molecule Rotational Component Multipole Moment Permanent Dipole Moment 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Springer Science+Business Media Dordrecht 2004

Authors and Affiliations

  • A. Medina
    • 1
  • J. M. M. Roco
    • 2
  • A. Calvo Hernández
    • 2
  • S. Velasco
    • 2
  1. 1.ETSII de BéjarUniversidad de SalamancaBéjar, SalamancaSpain
  2. 2.Departamento de Física Aplicada, Facultad de CienciasUniversidad de SalamancaSalamancaSpain

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