Abstract
The ices are model systems for the study of weak interactions — most notably the hydrogen bond — which are applicable to fields as diverse as biology and planetary modelling. High-pressure studies provide a powerful means to access the density dependence of the interactions but prior to 1990 it was not possible to determine accurately the location of the hydrogen atoms at high-pressure because neutron diffraction was generally limited to pressures below 3 GPa. This chapter describes highpressure neutron diffraction studies of a range of ices and the new information that these studies have provided.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
Hemley, R.J. (2000) Effects of high pressure on molecules, Ann. Rev. Phys. Chem. 51, 763.
Bacon, G.E. (1975) Neutron Diffraction, Clarendon Press , Oxford.
Khvostantsev, L.G. , (1984) A title , High Temp. High Press., 16, 165.
Besson, J.M., Nelmes, R.J., Hamel, G., Loveday, J.S., Weill, G. and Hull, S. (1992) Neutron powder diffraction above 10 GPa, Physica B 180, 907–910.
Klug, D.D. and Whalley, E. (1984) The uncoupled 0-H stretch in ice VII. The infrared frequency and integrated intensity up to 189 kbar, J. Chem. Phys. 81, 1220–1228.
Olovsson, I. and Jönsson, P-G. (1976) A Title, in P. Schuster, G. Zundel and C. Sandorfy (eds.), The hydrogen bond. Recent developments in theory and experiments, North-Holland, Amsterdamm, vol II p 395
Nelmes, R.J., Loveday, J.S., Wilson, R.M., Besson, J.M., Pruzan, P., Klotz, S., Hamel, G. and Hull, S. (1993) Neutron-Diffraction Study Of The Structure Of Deuterated Ice-VIII To 10 GPa, Phys. Rev. Lett. 71, 1192–1195.
Loveday, J.S., Nelmes, R.J., Marshall, W.G., Besson, J.M., Klotz, S. and Hamel G (1997) Structural studies of ices at high pressure, Physica B 241, 240–246.
Besson, J.M., Pruzan, P., Klotz, S., Hamel, G., Silvi, B., Nelmes, R.J., Loveday, J.S., Wilson, R.M. and Hull, S. (1994) Variation of interatomic distances in ice-VIII to 10 GPa, Phys. Rev. B 49, 12540–12550 .
Goncharov, A.F., Struzhkin, V.V., Somayazulu, M.S., Hemley, R.J. and Mao, H.K. (1998) Compression of ice to 210 gigapascals: Infrared evidence for a symmetric hydrogen-bonded phase, Science 273, 218–220.
Benoit, M., Marx, D. and Parrinello, M. (1998) Tunnelling and zero-point motion in high-pressure ice, Nature 392, 258–261.
Gauthier, M., Pruzan, P., Chervin, J.C. and Besson, J.M. (1988) Raman-scattering study of ammonia up to 75 GPa evidence for bond symmetrization at 60 GPa, Phys. Rev. B 37, 2102–2115.
Loveday, J.S., Nelmes, R.J., Marshall, W.G., Besson, J.M., Klotz, S. and Hamel, G. (1996) Structure of deuterated ammonia IV, Phys. Rev. Lett. 76, 74–77.
Cavazzoni, C., Chiarotti, G.L., Scandolo, S., Tosatti, E., Bernasconi, M. and Parrinello, M. (1999) Superionic and metallic states of water and ammonia at giant planet conditions, Science 283, 44–46.
Cockcroft, J.K. and Fitch, A.N. (1990) The solid–phases of deuterium sulfide by powder neutron-diffraction, Zeit. Krist. 193, 1–19.
Shimizu, H., Yamaguchi, H., Sasaki, S., Honda, A., Endo, S. and Kobayashi, M. (1995) Pressure-temperature phase-diagram of solid hydrogen-sulfide determined by Raman–spectroscopy, Phys. Rev. B 51, 9391–9394.
Fujihisa, H., Yamawaki, H., Sakashita, M., Aoki, K., Sasaki, S. and Shimizu, H., (1998) Structures of H2S: Phases I ’ and IV under high pressure, Phys. Rev. B 57, 2651–2654.
Rousseau, R., Boero, M., Bernasconi, M., Parrinello, M. and Terakura, K. (1999) Static structure and dynamical correlations in high pressure H2S, Phys. Rev. Lett. 83, 2218–2221.
Jeffery, G.A.. (1997) The Hydrogen bond, Oxford University Press, Oxford.
Hummer, G., Garde, S., Garcia, A.E. ,Paulaitis, M.E. and Pratt, L.R., (1998), The pressure dependence of hydrophobic interactions is consistent with the observed pressure denaturation of proteins, Proc. Natl. Acad. Sci. 95, 1552–1555.
Lunine, J.I. and Stevenson, D.J (1985), Thermodynamics of clathrate hydrate at low and high pressures with application to the outer solar system, Astrophys. I Suppl. S. 58 493–531.
Loveday, J.S. and Nelmes, R.J. (2000) Structural Studies of Ammonia Hydrates, in M. Manghnani, W.B. Nellis and M. Nicol (eds.), Science and Technology ofHigh Pressure, Universities Press, Hyderabad, vol 1, 133–136.
Loveday, J.S. and Nelmes, R.J. (1999) Ammonia monohydrate VI: A hydrogenbonded molecular alloy, Phys. Rev. Lett. 83, 4329–4332.
Loveday, J.S., Nelmes, R.J., Guthrie, M., Belmonte, S.A., Allan, D.R., Klug, D.D., Tse, J.S. and Handa, Y.P. (2001) Stable methane hydrate above 2 GPa and the source of Titan’s atmospheric methane, Nature 410, 661–663.
Loveday, J.S., Nelmes, R.J. and Guthrie, M. (2001) High-pressure transitions in methane hydrate, Chem. Phys. Lett. 350, 459–465.
Loveday, J.S., Nelmes, R.J., Guthrie, M., Klug, D.D. and Tse, J.S. Transition from cage clathrate to filled ice: The structure of methane hydrate III, Phys. Rev. Lett. 87, 215–501.
Loveday, J.S. and Nelmes R.J. (2003) High–pressure neutron diffraction and models of Titan, High Pressure Res. 23, 41–47.
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2004 Springer Science+Business Media New York
About this paper
Cite this paper
Loveday, J.S. (2004). Neutron Diffraction Studies of Ices and Ice Mixtures. In: Katrusiak, A., McMillan, P. (eds) High-Pressure Crystallography. NATO Science Series, vol 140. Springer, Dordrecht. https://doi.org/10.1007/978-1-4020-2102-2_5
Download citation
DOI: https://doi.org/10.1007/978-1-4020-2102-2_5
Publisher Name: Springer, Dordrecht
Print ISBN: 978-1-4020-1954-8
Online ISBN: 978-1-4020-2102-2
eBook Packages: Springer Book Archive