• Christopher Hall


Materials science seeks to explain the properties of materials in terms of structure. Chapter 1 dealt with the molecular structure of polymers, that is, with the internal organisation of the individual chain molecules. We next consider how the chain molecules are assembled to form the bulk material. In broad terms, in polymers as in other materials, we can envisage regular, ordered crystalline arrangements or irregular, random, amorphous arrangements of the constituent molecules. Furthermore, several levels of structural organisation may exist, and materials may reveal complex microstructures in the optical or electron microscope. It is to these observed forms and their inner structure that we refer when we speak of the morphology of polymeric materials. The properties of materials are governed by the subtle interplay of processes operating at all of these structural levels.


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Suggestions for Reading

  1. Billmeyer, F. W. Jr., Textbook of Polymer Science, 2nd edn (Wiley, New York, 1971).Google Scholar
  2. Clark, E. S., ‘Structure of crystalline polymers’, in Polymeric Materials, ch. 1 (American Society of Metals, Metals Park, Ohio, 1975).Google Scholar
  3. Ingram, P., and Peterlin, A., ‘Morphology’, in Encyclopaedia of Polymer Science and Technology, vol. 9, pp. 204–74 (Wiley, New York, 1968).Google Scholar
  4. Keller, A., ‘The many faces of order in solid polymers’, Plastics and Polymers, 43(163) (1975) 15–29.Google Scholar
  5. Magill, J. H., ‘Morphogenesis of solid polymer microstructures’, in J. M. Schultz (Ed.), Treatise on Materials Science and Technology, vol. 10A (Academic Press, New York, 1977).Google Scholar
  6. Schultz, J. M., Polymer Materials Science (Prentice-Hall, Englewood Cliffs, N. J., 1974).Google Scholar
  7. Sharples, A., Introduction to Polymer Crystallization (Edward Arnold, London, 1966).Google Scholar
  8. Sharples, A., ‘Crystallinity’, in A. D. Jenkins (Ed.), Polymer Science, ch. 4 (North-Holland, Amsterdam, 1972).Google Scholar
  9. Wyatt, O. H., and Dew-Hughes, D., Metals, Ceramics and Polymers (Cambridge University Press, 1974).Google Scholar

Copyright information

© Christopher Hall 1981

Authors and Affiliations

  • Christopher Hall
    • 1
  1. 1.Institute of Science and TechnologyUniversity of ManchesterUK

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