Abstract
Since an electron-donating substituent will usually also increase the π electron density all over the aromatic ring, such rings react with electrophiles faster than benzene; sometimes so much so that milder conditions have to be used. Thus a hydroxybenzene is as reactive to electrophiles as an alkene, but still giving substitution reactions rather than addition.
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Further Reading
F A Carey and R J Sundberg, Advanced Organic Chemistry, Parts A and B, Plenum, New York, 1977.
C H DePuy and K L Rinehart, Introduction to Organic Chemistry, Wiley, New York, 1967.
J R Gerrish and R C Whitfield, A Modern Course of Organic Chemistry, Longman, London, 1977.
J A Moore and T J Barton, Organic Chemistry: an Overview, W B Saunders, Philadelphia, 1978.
E D Morgan and R Robinson, An Introduction to Organic Chemistry: Aliphatic and Alicyclic Compounds, Hutchinson, London, 1975.
S H Pine, J B Hendrickson, D J Cram, and G S Hammond, Organic Chemistry, McGraw-Hill, New York, 1980.
P Sykes, A Guidebook to Mechanism in Organic Chemistry, Longman, London, 1975.
J M Tedder and A Nechvatal, Basic Organic Chemistry, Wiley, London, 1967.
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© 1982 D. A. Robinson and J. McK. Woollard
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Robinson, D.A., Woollard, J.M. (1982). Benzene and its Derivatives-II. In: Chemistry for Colleges and Schools. Palgrave, London. https://doi.org/10.1007/978-1-349-04540-2_36
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DOI: https://doi.org/10.1007/978-1-349-04540-2_36
Publisher Name: Palgrave, London
Print ISBN: 978-1-349-04542-6
Online ISBN: 978-1-349-04540-2
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