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Abstract

The use of electron dot diagrams provides a simple pictorial representation of the valence bonds in a particular molecule. The technique involves using dots to represent electrons from the valence shells of the atoms in the molecule: the atoms are then combined in such a way as to pair the electrons (dots) in (single) valence bonds. For example:

Electrons from only the valence shells are shown because it is these which are used in bond formation. Electron dot diagrams give immediate visual confirmation of there being any remaining unpaired electrons or residual bonding capacity in a proposed molecule.

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Further Reading

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  • H B Gray, Chemical Bonds, Benjamin-Cummings, California, 1973.

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  • W Heitler, Elementary Wave Mechanics, Oxford University Press, Oxford, 1969.

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  • R McWeeney, Coulson’s Valence, Oxford University Press, Oxford, 1979.

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  • J N Murrell, S F A Kettle, and J M Tedder, The Chemical Bond, Wiley, Chichester, 1978.

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  • L Pauling, The Chemical Bond, Oxford University Press, Oxford, 1967.

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  • H S Pickering, The Covalent Bond, Wykeham Publications, London, 1977.

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  • D H Williams and I Fleming, Spectroscopic Methods in Organic Chemistry, McGraw-Hill, London, 1973.

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© 1982 D. A. Robinson and J. McK. Woollard

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Robinson, D.A., Woollard, J.M. (1982). Molecular Geometry. In: Chemistry for Colleges and Schools. Palgrave, London. https://doi.org/10.1007/978-1-349-04540-2_15

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