Abstract
The diffusion of atoms plays an important part in many processes that can take place in solid metals and alloys. By diffusion we understand here the phenomenon where atoms move through the crystal lattice by jumping from one available site to another. For instance, in iron at room temperature an interstitial nitrogen atom jumps on average once every second from one interstice to another. On the other hand, the jump frequency of atoms that are substitutionally dissolved in a high-melting metal, as for instance the jump frequency of nickel atoms in iron, is negligibly small at room temperature. With rising temperature the rate of diffusion increases rapidly in all metals and alloys.
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F. M. G. Johnson and P. Larose, J. Am. chem. Soc. 46, 1377 (1924) and 49, 312 (1927).
W. Jost, Diffusion in Solids, Liquids, Gases, Academic Press, New York (1952).
H. Dünwald and C. Wagner, Z. Phys. Chem. B24, 53 (1934).
J. D. Fast and M. B. Verrijp, J. Iron Steel Inst. 180, 337 (1955).
J. D. Fast and M. B. Verrijp, J. Iron Steel Inst. 176, 24 (1954).
G. Euringer, Z. Phys. 96, 37 (1935).
M. L. Hill and E. W. Johnson, Acta Metall. 3, 566 (1955).
A. G. Edwards, Br. J. Appl. Phys. 8, 406 (1957).
W. Eichenauer and A. Pebler, Z. Metallk. 48, 373 (1957).
W. Eichenauer, H. Künzig and A. Pebler, Z. Metallk. 49, 220 (1958).
W. Eichenauer and G. Müller, Z. Metallk. 53, 321 (1962).
R. P. Smith, Acta Metall. 1, 578 (1953).
C. Wells, W. Batz and R. F. Mehl, Trans. AIME 188, 553 (1950).
C. Matano, Jap. J. Phys. 8, 109 (1933).
C. Wells, W. Batz and R. F. Mehl, Trans. AIME 188, 553 (1950).
A. D. Smigelskas and E. O. Kirkendall, Trans. AIME 171, 130 (1947).
L. S. Darken, Trans. AIME 175, 184 (1948).
W. Jost, Diffusion und chemische Reaktion in festen Stoffen, Steinkopff-Verlag, Dresden und Leipzig (1937).
L. S. Darken, Trans. AIME180, 430 (1949).
R. P. Smith, J. Am. chem. Soc. 70, 2724 (1948).
P. Frank and R. Von Mises, Die Differential- und Integralgleichungen der Mechanik und Physik, Braunschweig (1935).
J. Crank, Mathematics of Diffusion, Oxford (1956).
H. S. Carslaw and J. C. Jaeger, Conduction of Heat in Solids, Oxford (1959).
W. Eichenauer and A. Pebler, Z. Metallk. 48, 373 (1957).
W. Eichenauer, W. Löser and H. Witte, Z. Metallk. 56, 287 (1965).
W. Eichenauer, H. Künzig and A. Pebler, Z. Metallk. 49, 220 (1958).
W. Eichenauer and D. Liebscher, Z. Naturf. 17a, 355 (1962).
C. Sykes, H. H. Burton and C. C. Gegg, J. Iron Steel Inst. 156, 155 (1947).
W. Geller and T. H. Sun, Arch. Eisenhütt Wes. 21, 423 (1950).
Y. Ebisuzaki, W. J. Kass and M. O’keeffe, J. Chem. Phys. 46, 1378 (1967).
M. L. Hill and E. W. Johnson, Acta metall. 3, 566 (1955).
A. G. Edwards, Br. J. Appl. Phys. 8, 406 (1957).
W. Jost and A. Widmann, Z. phys. Chem. (B) 45, 285 (1940).
O. M. Katz and E. A. Gulbransen, Rev. scient. Instrum. 31, 615 (1960).
J. W. Simons and T. B. Flanagan, J. phys. Chem., Ithaca 69, 3581 (1965).
D. T. Peterson and D. G. Westlake, J. phys. Chem., Ithaca 64, 649 (1960).
R. J. Wasilewski and G. L. Kehl, Metallurgia 50, 225 (1954).
M. W. Mallett and W. M. Albrecht, J. electrochem. Soc. 104, 142 (1957).
C. R. Cupp and P. Flubacher, J. Nucl. Mater. 6, 213 (1962).
V. L. Gelezunas, P. K. Conn and R. H. Price, J. electrochem. Soc. 110, 799 (1963).
T. M. Stross and F. C. Tompkins, J. Chem. Soc. 230 (1956).
E. W. Johnson and M. L. Hill, Trans. AIME 218, 1104 (1960).
R. Wagner and R. Sizmann, Z. angew. Phys. 18, 193 (1964).
W. M. Albrecht, W. D. Goode and M. W. Mallett, J. electrochem. Soc. 106, 981 (1959).
R. P. Smith, Trans. AIME 230, 476 (1964).
C. Wells, W. Batz and R. F. Mehl, Trans. AIME 188, 553 (1950).
P. Grieveson and E. T. Turkdogan, Trans. AIME 230, 407 (1964).
J. H. Swisher and E. T. Turkdogan, Trans. AIME 239, 426 (1967).
W. Frank, H. J. Engell and A. Seeger, Trans. AIME 242, 749 (1968).
W. Eichenauer and G. Müller, Z. Metallk. 53, 321, 700 (1962).
D. T. Peterson, Trans. AIME 221, 924 (1961).
R. J. Wasilewski and G. L. Kehl, J. Inst. Metals 83, 94 (1954).
M. W. Mallett, W. M. Albrecht and P. R. Wilson, J. electrochem. Soc. 106, 181 (1959).
G. Beranger and P. Lacombe, J. Nucl. Mater. 16, 190 (1965).
J. P. Pemsler, J. electrochem. Soc. Ill, 1185 (1964).
M. W. Mallett, J. Belle and B. B. Cleland, J. electrochem. Soc. 101, 1 (1954).
F. Claisse and H. P. Koenig, Acta Metall. 4, 650 (1956).
A. E. Lord and D. N. Beshers, Acta Metall. 14, 1659 (1966).
M. E. De Morton, J. Appl. Phys. 33, 2768 (1962).
M. J. Klein and A. H. Clauer, Trans. AIME 233, 1771 (1965).
M. J. Klein, J. Appl. Phys. 38, 167 (1967).
P. S. Rudman, Trans. AIME 239, 1949 (1967).
R. W. Powers and M. V. Doyle, Acta Metall. 4, 233 (1956).
T. P. Papazoglou and M. T. Hepworth, Trans. AIME 242, 682 (1968).
R. Frauenfelder, J. Chem. Phys. 48, 3966 (1968).
R. L. Pastorek and R. A. Rapp, Trans. AIME 245, 1711 (1969).
A. F. Gerds and M. W. Mallett, J. electrochem. Soc. 101, 175 (1954).
J. H. Evans and B. L. Eyre, Acta Metall. 17, 1109 (1969).
H. Jehn and E. Fromm, J. less-common Metals 21, 333 (1970).
S. V. Zemskiy and M. N. Spasskiy, Physics Metals Metallogr., Wash. 21, 129 (1966).
C. A. Wert, Physics Chem. Solids 31, 1771 (1970).
J. Piper, J. Appl. Phys. 37, 715 (1966).
S. Glasstone, K. J. Laidler and H. Eyring, The Theory of Rate Processes, McGraw-Hill, New York (1941).
C. A. Wert and C. Zener, Phys. Rev. 76, 1169 (1949).
C. A. Wert, Phys. Rev. 79, 601 (1950).
F. Seitz, Phase Transformations in Solids (edited by R. Smoluchowski), John Wiley, New York (1951), Chapter 4.
C. Zener, Imperfections in Nearly Perfect Crystals (edited by W. Shockley), John Wiley, New York (1952), Chapter 11.
G. H. Vineyard, Physics Chem. Solids 3, 121 (1957).
O. Manley, Physics Chem. Solids 13, 244 (1960).
J. Bergsma and J. A. Goedkoop, Physicals Grav. 26, 744 (1960).
J. W. Simons and T. B. Flanagan, J. phys. Chem., Ithaca 69, 3581 (1965).
M. L. Hill and E. W. Johnson, Acta Metall. 3, 566 (1955).
C. A. Wert and C. Zener, Phys. Rev. 76, 1169 (1949).
C. Zener in Imperfections in Nearly Perfect Crystals (ed. W. Shockley), John Wiley, New York (1952), p. 289.
E. W. Johnson and M. L. Hill, Trans. AIME 218, 1104 (1960).
J. D. Hobson, J. Iron Steel Inst. 189, 315 (1958).
F. R. Coe and J. Moreton, J. Iron Steel Inst. 204, 366 (1966).
J. D. Fast, Philips tech. Rev. 6, 365 (1941) and 7, 74 (1942).
L. S. Darken and R. P. Smith, Corrosion 5, 1 (1949).
T. G. Owe Berg, Corrosion 14, 562t (1958).
R. M. Hudson, W. G. Norris and G. L. Stragand, Ind. Engng Chem. int. Edn 51, 319 (1959).
R. M. Hudson, K. J. Riedy and G. L. Stragand, Corrosion 16, 115t (1960) and 18, 79t (1962).
R. M. Hudson and G. L. Stragand, Corrosion 16, 253t (1960).
M. Dadian and S. Talbot-Besnard, C. R. hebd. Séanc. Acad. Sci., Paris 260, 1940 (1965).
A. Mcnabb and P. K. Foster, Trans. AIME 227, 618 (1963).
P. K. Foster, A. Mcnabb and C. M. Payne, Trans. AIME 233, 1022 (1965).
M. L. Hill and E. W. Johnson, Trans. AIME 221, 622 (1961).
M. H. Armbruster, J. Am. Chem. Soc. 65, 1043 (1943).
W. Geller and T. H. Sun, Arch. Eisenhütt. Wes. 21, 423 (1950).
I. Class, Stahl Eisen 80, 1117 (1960).
L. C. Weiner, Corrosion 17, 109 (1961).
H. H. Podgurski, Trans. AIME 221, 389 (1961).
J. G. Morlet, H. H. Johnson and A. R. Troiano, J. Iron Steel Inst. 189, 37 (1958) and Trans. AIME 212, 528 (1958).
E. A. Steigerwald, F. W. Schaller and A. R. Troiano, Trans. AIME 215, 1048 (1959) and 218, 832 (1960).
W. Beck, J. O’M. Bockris, J. Mcbreen and L. Nanis, Proc. R. Soc. A290, 220 (1966).
C. A. Wert, Phys. Rev. 79, 601 (1950).
J. K. Stanley, Trans. AIME 185, 752 (1949).
W. R. Thomas and G. M. Leak, Phil. Mag. 45, 986 (1954).
R. R. Hasiguti and G. Kamoshita, J. phys. Soc. Japan 9, 646 (1954).
L. Guillet and B. Hocheid, Revue Métall., Paris 53, 122 (1956).
R. E. Maringer, J. Appl. Phys. 31, 229S (1960) and 35, 2375 (1964).
A. E. Lord and D. N. Beshers, Acta Metall. 14, 1659 (1966).
R. P. Smith, Trans. AIME 224, 105 (1962).
C. G. Homan, Acta Metall 12, 1071 (1964).
H. Wagenblast and A. C. Damask, Physics Chem. Solids 23, 221 (1962) and Acta Metall. 10, 333 (1962).
F. E. Fujita and A. C. Damask, Acta Metall. 12, 331 (1964).
R. A. Arndt and A. C. Damask, Acta Metall. 12, 341 (1964).
H. Wagenblast, F. E. Fujita and A. C. Damask, Acta Metall. 12, 347 (1964).
R. A. Johnson and A. C. Damask, Acta Metall. 12, 443 (1964).
R. A. Johnson, G. J. Dienes and A. C. Damask, Acta Metall. 12, 1215 (1964).
R. B. Mclellan, M. L. Rudee and T. Ishibachi, Trans. AIME 233, 1938 (1965).
D. N. Beshers, J. Appl. Phys. 36, 290 (1965).
L. J. Dijkstra, Philips Res. Rep. 2, 357 (1947).
C. Wells, W. Batz and R. F. Mehl, Trans. AIME 188, 553 (1950).
R. P. Smith, Acta Metall. 1, 578 (1953).
A. E. Lord and D. N. Beshers, Acta Metall. 14, 1659 (1966).
W. T. Read, Dislocations in Crystals, McGraw-Hill, New York (1953).
N. F. Mott, Proc. phys. Soc. 60, 391 (1948).
R. E. Hoffman and D. Turnbull, J. Appl. Phys. 22,634 and 984 (1951).
D. Turnbull Atom Movements, Am. Soc. Metals, Cleveland (1951), p. 129.
C. Leymonie and P. Lacombe, Revue Métall., Paris 54, 653 (1957). See also their contribution to the book La Diffusion dans les Métaux (editors J. D. Fast, H. G. van Bueren and J. Philibert), Philips Technical Library, Eindhoven (1957).
B. Okkerse, T. J. Tiedema and W. G. Burgers, Acta Metall. 3, 300 (1955).
R. E. Hoffman, Acta Metall. 4, 97 (1956).
J. C. Fisher, J. Appl. Phys. 22, 74 (1951).
R. T. P. Whipple, Phil. Mag. 45, 1225 (1954).
H. S. Levine and C. J. Maccallum, J. Appl. Phys. 31, 595 (1960).
T. Suzuoka, Trans. Japan Inst. Metals 2, 25 (1961).
L. C. Luther, J. Chem. Phys. 45, 1080 (1966).
J. P. Stark, J. Appl. Phys. 36, 3938 (1965).
R. S. Barnes, G. B. Redding and A. H. Cottrell, Phil. Mag. 3, 97 (1958).
R. S. Barnes, Colloque sur la Diffusion à l’Etat solide (editor: G. Chaudron), North Holland Publ. Co., Amsterdam (1959), p. 57.
R. S. Barnes, Phil. Mag. 5, 635 (1960).
R. S. Barnes and D. J. Mazey, Proc. R. Soc. A275, 47 (1963).
G. T. Murray, J. Appl. Phys. 32, 1045 (1961).
R. S. Barnes and D. J. Mazey, Proc. R. Soc. A275, 47 (1963) and Mém. Scient. Revue Métall 63, 81 (1966).
R. S. Barnes, J. Nucl. Mater. 11, 135 (1964) and R. S. Nelson, J. Nucl. Mater. 19, 149 (1966).
F. A. Nichols, J. Nucl. Mater. 30, 143 (1969).
H. Mykura, Phil. Mag. 4, 907 (1959).
W. W. Mullins, J. Appl. Phys. 28, 333 (1957) and 30, 77 (1959). See also his article in the book Metal Surfaces (editors: W. D. Robertson and N. A. Gjostein), Am. Soc. Metals, Cleveland (1963).
J. C. Chaston, J. Inst. Metals 71, 23 (1945).
M. J. Klein and R. A. Huggins, Trans. AIME 224, 903 (1962).
M. Davis, K. R. Montgomery and J. Standring, J. Inst. Metals 89, 172 (1960–61).
J. Debuigne and P. Lehr, Mém. Scient. Revue Métall. 60, 911 (1963).
G. Beranger and P. Lacombe, J. Nucl. Mater. 16, 190 (1965).
G. Sainfort, R. Jacquesson and P. Laurent, Colloque sur la Diffusion a L’Etat solide (editor: G. Chaudron), North Holland Publ. Co., Amsterdam (1959), p. 79.
E. Smith, Direct Observation of Imperfections in Crystals (editors: J. B. Newkirk and J. H. Wernick), John Wiley, New York (1961), p. 203.
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© 1971 N. V. Philips’ Gloeilampenfabrieken, Eindhoven
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Fast, J.D. (1971). Diffusion in Interstitial Alloys. In: Interaction of Metals and Gases. Philips Technical Library. Palgrave, London. https://doi.org/10.1007/978-1-349-00500-0_2
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