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Techniques Giving Mechanistic Information

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Techniques and Mechanisms in Electrochemistry

Abstract

The model of the electrode/electrolyte interface proposed in the first chapter is termed the Stern model. This is now accepted as the definitive picture of the structure of the interface, primarily as a result of electrocapillarity studies.

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References

  • Albery, W.J. (1975) Electrode Kinetics, Clarendon Press, Oxford.

    Google Scholar 

  • Albery, W.J. and Hitchman, M. (1971). Ring-disc Electrodes, Clarendon Press, Oxford.

    Google Scholar 

  • Albrecht, M.G. and Creighton, J.A. (1977) J. Am. Chem. Soc., 99, 5215.

    CAS  Google Scholar 

  • Allendoerfer, R.D., Martincheck, G.A. and Bruckenstein, S. (1973) Anal. Chem., 47, 890.

    Google Scholar 

  • Beden, B., Bewick, A., Kunimatsu, K. and Lamy, C. (1981) J. Electroanal. Chem., 121, 343.

    CAS  Google Scholar 

  • Beden, B., Collas, N., Lamy, C., Leger, J.M. and Solis, V. (1985) Surface Sci., 162, 795.

    Google Scholar 

  • Bedzyk, M.J., Bommarito, G.M., Caffrey, M. and Penner, T.L. (1990) Science, 248, 52.

    CAS  Google Scholar 

  • Binning, G., Quate, C.F. and Gerber, Ch. (1986) Phys. Rev, Lett., 12, 930.

    Google Scholar 

  • Birke, R.L. and Lombardi, J.R. (1988) in Spectroetectrochemistry: Theory and Practice, Gale, R.J. (ed.), Plenum Press, New York, Chapter 6.

    Google Scholar 

  • Blum, L., Abruna, H.D., White, J., Gordon, II, G.J., Borges, G.L., Samant, M.G. and Melroy, O.R. (1986) J. Chem. Phys.. 85, 6732.

    CAS  Google Scholar 

  • Bruckenstein, S. and Shay, M. (1985) J. Electroanal. Chem., 188, 131.

    CAS  Google Scholar 

  • Carroll, J.B. (1983) Ph.D. Thesis, State University of New York at Buffalo.

    Google Scholar 

  • Chen, C.Y., Davoli I., Ritchie, G. and Burstein, E. (1980) Surface Sci., 101, 363.

    CAS  Google Scholar 

  • Christensen, P.A. and Hamnett, A. (1989) J. Electroanal. Chem., 260, 347.

    CAS  Google Scholar 

  • Compton, R.G. and Coles, B.A. (1983) J. Electroanal. Chem., 144, 87.

    Google Scholar 

  • Compton, R.G., Coles, B.A. and Day, M.J. (1986) J. Electroanal. Chem., 200, 205.

    CAS  Google Scholar 

  • Corrigan, D.A. and Weaver, M.J. (1986) J. Phys. Chem., 90, 5300.

    CAS  Google Scholar 

  • Feenstra, R.M., Stroscio, J.A., Tersoff, J. and Fein, A.P. (1987) Phys. Rev. Lett., 58, 1192.

    CAS  Google Scholar 

  • Feldberg, S.W. (1984) J. Am. Chem. Soc., 106, 4671.

    CAS  Google Scholar 

  • Fleischmann, M., Hendra, P.J. and McQuillan, A.J. (1974) Chem. Phys. Lett., 26, 163.

    CAS  Google Scholar 

  • Fleischmann, M., Oliver, A. and Robinson, J. (1986) Electrochim. Acta, 31, 899.

    CAS  Google Scholar 

  • Gokhshtein, A.Y. (1970) Electrochim. Acta, 15, 219.

    CAS  Google Scholar 

  • Golden, W.G., Dunn, D.S. and Overend, J. (1981) J. Catal., 71, 395.

    CAS  Google Scholar 

  • Goodwin, R.D., Gilbert, J.C. and Bard, A.J. (1975) J. Electroanal. Chem., 59, 163.

    Google Scholar 

  • Grahame, D.C. (1947) Chem. Rev., 41, 441.

    CAS  Google Scholar 

  • Grambow, L. and Bruckenstein, S. (1977) Electrochim. Acta, 22, 377.

    CAS  Google Scholar 

  • Greenler, R.G. (1966) J. Chem. Phys., 44, 310.

    CAS  Google Scholar 

  • Griffiths, P.R. and deHaseth, J.A. (1986) Fourier Transform Infrared Spectrometry, Wiley-Interscience, New York.

    Google Scholar 

  • Hamers, R.J., Tromp, R.M. and Demuth, J.E. (1986) Phys. Rev. Lett., 56, 1972.

    CAS  Google Scholar 

  • Hamnett, A. and Hillmann, A.R. (1988) J. Electrochem. Soc., 135, 2517.

    CAS  Google Scholar 

  • Heinze, J., Storzbach, M. and Mortensen, J. (1987) Ber. Bunsenges. Phys. Chem., 91, 960.

    CAS  Google Scholar 

  • Hupp, J.T., Larkin, D. and Weaver, M.J. (1983) Surface Sci., 125, 429.

    CAS  Google Scholar 

  • Itaya, K., Sugawara, S., Sashikata, K. and Furuya, N. (1990) J. Vac. Sci. Technol., A8, 515.

    Google Scholar 

  • Iwasita-Vielstich, T. (1990) in Advances in Electrochemical Science and Engineering, Gerischer, H. and Tobias, C.W. (eds), VCH Publishers Inc., New York, Vol. 1, Chapter 3.

    Google Scholar 

  • Jeanmarie, D.L. and Van Duyne, R.P. (1977) J. Electroanal. Chem., 84, 1.

    Google Scholar 

  • Jiang, X.C., Seo, M. and Sato, N. (1991) J. Electrochem. Soc., 138, 137.

    CAS  Google Scholar 

  • Kolb, D.M. (1988) in Spectroelectrochemistry: Theory and Practice, Gale R.J. (ed.), Plenum Press. New York, p. 150.

    Google Scholar 

  • Kondrikov, N.B., Orlov, V.V., Ermakov, V.I. and Fioshin, M.Ya.(1972) Elektrokhimiya, 8, 920.

    Google Scholar 

  • Kotz, R. Neff, H. and Muller, K. (1986) J. Electroanal. Chem., 215, 331.

    CAS  Google Scholar 

  • Kunimatsu, K., Seki, H., Golden, W.G., Gordon, II, J.G. and Philpott, M.R. (1986) Langmuir, 2, 464.

    CAS  Google Scholar 

  • Larkin, D., Guyer, K.L., Hupp, J.T. and Weaver, M.J. (1982) J. Electroanal. Chem., 138, 401.

    CAS  Google Scholar 

  • Li, F.B., Hillman, A.R. and Lubetkin D. (1992) Electrochim. Acta, 37, 2715.

    CAS  Google Scholar 

  • Maki, A.H. and Geske, D.H. (1959) J. Chem. Phys., 30, 1356.

    CAS  Google Scholar 

  • Manne, S., Hansma, P.K., Massie, J., Elings V.B. and Gewirth A.A. (1991) Science, 251, 185.

    Google Scholar 

  • Melendres, C.A., You, H., Maroni, V.A. and Nagy, Z. (1991) J. Electroanal. Chem., 297, 549.

    CAS  Google Scholar 

  • Mengoli, G., Musiani, M., Fleischmann, M., Mao, B. and Tian, Z.Q. (1987) Electrochim. Acta, 32, 1239.

    CAS  Google Scholar 

  • Murray, C.A. and Allara, D.L. (1982) J. Chen. Phys., 76, 1290.

    CAS  Google Scholar 

  • Paliteiro, C. (1985) D.Phil Thesis, Oxford.

    Google Scholar 

  • Piette, L.H., Ludwig, R. and Adams, R.N. (1962) Anal. Chem., 34, 916.

    CAS  Google Scholar 

  • Randles, J.E.B. (1948) Trans. Far. Soc., 44, 327.

    CAS  Google Scholar 

  • Ranjith, S.K.A., Gamage, S.U. and McQuillan, A.J. (1990) J. Electroanal. Chem., 284, 229.

    Google Scholar 

  • Russell, J.W., Overend, J., Scanlon, K., Severson M. and Bewick, A. (1982) J. Phys. Chem., 86, 3066.

    CAS  Google Scholar 

  • Seo, M., Makino, T. and Sato, N. (1986) J. Electrochem. Soc., 133, 1138.

    CAS  Google Scholar 

  • Seo, M., Jiang, X.C. and Sato, N. (1987) J. Electrochem. Soc., 134, 3094.

    CAS  Google Scholar 

  • Sevcik, A. (1948) Czech. Chem. Commun., 13, 349.

    CAS  Google Scholar 

  • Shirakawa, H., Louis, E.J., MacDiarmid, A.G., Chiang, C.K. and Heeger, A.J. (1977) J. Chem. Soc. Chem. Comm., 578.

    Google Scholar 

  • Uosaki, K. and Koinuma, M. (1992) Far. Diss. 94.

    Google Scholar 

  • Waller, A.M. and Compton, R.G. (1989) in Comprehensive Chemical Kinetics, Compton, R.G. and Hamnett. A. (eds), Elsevier, Amsterdam, Chapter 7, Vol. 29.

    Google Scholar 

  • Wilhelm, S., Vielstich, W., Buschmann, H.W. and Iwasita, T. (1987) J. Electroanal. Chem., 229, 377.

    CAS  Google Scholar 

  • Wolter, O. and Heitbaum, J. (1984) Ber. Bunsenges. Phys. Chem., 88, 2.

    CAS  Google Scholar 

Further reading

  • Albery, W.J. (1975) Electrode Kinetics, Clarendon Press, Oxford.

    Google Scholar 

  • Albery, W.J. and Hitchman, M. (1971) Ring Disc Electrodes, Clarendon Press, Oxford.

    Google Scholar 

  • Arvia, A.J. (1990) in Spectroscopic and Diffraction Techniques in Interfacial Electrochemistry, Gutierrez, C. and Melendres, C. (eds), Nato ASI Series, Series C: Mathematical and Physical Sciences, Vol. 320, Kluwer Academic Publishers, Dordrecht, Chapter 16.

    Google Scholar 

  • Ashley, K. and Pons, S. (1988) in Chem. Rev., 88, 673.

    CAS  Google Scholar 

  • Banwell, C.N. (1983) Fundamentals of Molecular Spectroscopy, McGraw-Hill, Maidenhead.

    Google Scholar 

  • Bard, A.J. and Faulkener, L.R. (1980) Electrochemical Methods, John Wiley and Sons, New York.

    Google Scholar 

  • Beden, B. and Lamy, C. (1988) in Spectroelectrochemistry: Theory and Practice, Gale, R.J. (ed.), Plenum Press, New York, Chapter 5.

    Google Scholar 

  • Behm, R.J., Garcia, R. and Rohrer, H. (1990) Scanning Tunnelling Microscopy and Related Methods, NATO ASI Series, Series E: Applied Sciences, Vol. 184, Kluwer Academic Publishers, Dordrecht.

    Google Scholar 

  • Bewick, A. and Pons, S. (1985) in Advances in Infrared and Raman Spectroscopy, Clark, R.J.H. and Hester, R.E. (eds), Vol. 12, Wiley-Heyden, p. 1.

    Google Scholar 

  • Birke, R.J. and Lombardi, J.R. (1988) in Spectroelectrochemistry: Theory and Practice, Gale, R.J. (ed.), Plenum Press, New York, Chapter 6.

    Google Scholar 

  • Bockris, J.O’M. and Reddy, A.K.N. (1970) Modern Electrochemistry, Plenum, New York.

    Google Scholar 

  • Bruckenstein, S. and Shay, M. (1985) Electrochim. Acta, 30, 1295.

    CAS  Google Scholar 

  • Cataldi, T.R.I., Blackham, I.G., Briggs, G.A.D., Pethica, J. and Hill, H.A.O. (1990) J. Electroanal. Chem., 290, 1.

    CAS  Google Scholar 

  • Chang, R.K. (1990) in Spectroscopic and Diffraction Techniques in Interfacial Electrochemistry, Gutierrez, C. and Melendres, C. (eds), Nato ASI Series, Series C: Mathematical and Physical Sciences, Vol. 320, Kluwer Academic Publishers, Dordrecht, Chapter 5.

    Google Scholar 

  • Christensen, P.A. (1992) Chem. Soc. Rev., 21, 207.

    Google Scholar 

  • Christensen, P.A. and Hamnett, A. (1989) in Comprehensive Chemical Kinetics, Vol. 29, Compton R.G. and Hamnett, A. (eds), Elsevier, Amsterdam, Chapter 1.

    Google Scholar 

  • Compton, R.G. and Hamnett, A. (1989) Comprehensive Chemical Kinetics, Vol. 29, Elsevier, Amsterdam.

    Google Scholar 

  • Compton, R.G. and Waller, A.M. (1988) in Spectroelectrochemistry: Theory and Practice, Gale, R.J. (ed.), Plenum Press, New York, Chapter 5.

    Google Scholar 

  • Fleischmann, M. and Hill, I.R. (1984) in Comprehensive Treatise of Electrochemistry, Vol. 8, White, R.E., Bockris, J.O’M., Conway, B.E. and Yeager, E. (eds), Plenum Press, New York, Chapter 6.

    Google Scholar 

  • Foley, J.K. and Pons, S. (1985) Anal. Chem., 57, 945A.

    CAS  Google Scholar 

  • Greef, R. (1984) in Comprehensive Treatise of Electrochemistry, White, R.E., Bockris, J.O’M., Conway, B.E. and Yeager, E. (eds), Vol. 8, Plenum Press, New York, Chapter 5.

    Google Scholar 

  • Greef, R. (1989) in Comprehensive Chemical Kinetics, Compton, R.G. and Hamnett, A. (eds), Vol. 29, Elsevier, Amsterdam, Chapter 10.

    Google Scholar 

  • Griffiths, PR. and deHaseth, J.A. (1986) Fourier Transform Infrared Spectrometry, Wiley-Interscience, New York.

    Google Scholar 

  • Gutierrez, C. and Melendres, C. (1990) Spectroscopic and Diffraction Techniques in Interfacial Electrochemistry, Nato ASI Series, Series C: Mathematical and Physical Sciences, Vol. 320, Kluwer Academic Publishers, Dordrecht.

    Google Scholar 

  • Hamers, R.J. (1989) Ann. Rev. Phys. Chem., 40, 531.

    CAS  Google Scholar 

  • Hammond, J.S. and Winograd, N. (1984) in Comprehensive Treatise of Electrochemistry, Vol. 8, White, R.E., Bockris, J.O’M., Conway, B.E. and Yeager, E. (eds), Plenum Press, New York, Chapter 8.

    Google Scholar 

  • Hansen, W.N. (1973) in Advances in Electrochemistry and Electrochemical Engineering, Vol. 9, Delahay, P. and Tobias, C.W. (eds), John Wiley and Sons, New York, Chapter 1.

    Google Scholar 

  • Heineman, W.R., Hawkridge, F.M. and Blount, H.N. (1984) in Electroanalytical Chemistry, A Series of Advances, Vol. 13, Bard, A.J. (ed.), Marcel Dekker Inc., New York, Chapter 1.

    Google Scholar 

  • Hester, R.W. (1989) in Comprehensive Chemical Kinetics, Compton, R.G. and Hamnett, A. (eds) Vol. 29, Elsevier, Amsterdam, Chapter 2.

    Google Scholar 

  • Hollas, J.M. (1988) Modern Spectroscopy, John Wiley and Sons, Chichester.

    Google Scholar 

  • Howarth, O. (1973) Theory of Spectroscopy, Thomas Nelson and Sons Ltd, London.

    Google Scholar 

  • Iwasita, T. and Vielstich, W. (1990) in Advances in Electrochemical Science and Engineering, Vol. 1

    Google Scholar 

  • Gerischer, H. and Tobias, C.W. (eds), VCH Publishers Inc., New York, Chapter 3.

    Google Scholar 

  • Kastening, B. (1984) in Comprehensive Treatise of Electrochemistry, Vol. 8, White, R.E., Bockris, J.O’M., Conway, B.E. and Yeager, E. (eds), Plenum Press, New York, Chapter 7.

    Google Scholar 

  • Kruger, J. (1973) in Advances in Electrochemistry and Electrochemical Engineering, Delahay, P. and Tobias, C.W. (eds.), Vol 9, John Wiley and Sons, New York, Chapter 4.

    Google Scholar 

  • Macdonald, JR. (1987) John Wiley and Sons, New York.

    Google Scholar 

  • McLauchlan, K.A. (1972) Magnetic Resonance, Clarendon Press, Oxford.

    Google Scholar 

  • Melendres, C.A. (1990) in Spectroscopic and Diffraction Techniques in Interfacial Electrochemistry, Gutierrez, C. and Melendres, C. (eds), Nato ASI Series, Series C: Mathematical and Physical Sciences, Vol. 320, Kluwer Academic Publishers, Dordrecht, Chapter 6.

    Google Scholar 

  • Miles, R. (1983) Surf. and Inter. Anal., 5, 43.

    CAS  Google Scholar 

  • Muller, R.H. (1973) in Advances in Electrochemistry and Electrochemical Engineering, Delahay, P. and Tobias, C.W. (eds), Vol. 9, John Wiley and Sons, New York, Chapter 3.

    Google Scholar 

  • Nichols, R.J. (1992) in Adsorption of Molecules at Metal Electrodes, Lipkowski, J. and Ross, P.N. (eds), VCH Publishers Inc., New York, Chapter 7.

    Google Scholar 

  • Parker, V.D. (1986) in Electroanalytical Chemistry. A Series of Advances, Vol. 14, Bard, A.J. (ed.), Marcel Dekker Inc., New York, Chapter 1.

    Google Scholar 

  • Pettinger, B. (1992) in Adsorption of Molecules at Metal Electrodes, Lipkowski, J. and Ross, P.N. (eds), VCH Publishers Inc., New York, Chapter 6.

    Google Scholar 

  • Plieth, W., Kozlowski, W. and Twomey, T. (1992) in Adsorption of Molecules at Metal Electrodes, Lipkowski, J. and Ross P.N. (eds), VCH Publishers Inc., New York, Chapter 5.

    Google Scholar 

  • Robinson, J. (1988) in Spectroelectrochemistry: Theory and Practice, Gale, R.J. (ed.), Plenum Press, New York, Chapter 2.

    Google Scholar 

  • Sauerbrey, G. (1955) Z. Phys., 155, 206.

    Google Scholar 

  • Sawyer, D.T. and Roberts, J.L. (1974) Experimental Electrochemistry for Chemists, John Wiley and Sons, New York.

    Google Scholar 

  • Sonnenfeld, R., Schneir, J. and Hansma P.K. (1990) in Modern Aspects of Electrochemistry, White R.E., Bockris, J.O’M. and Conway, B.E. (eds), Plenum Press, New York, p. 1.

    Google Scholar 

  • Southampton Electrochemistry Group (1990) Instrumental Methods in Electrochemistry, Ellis Horwood, Chichester.

    Google Scholar 

  • Waller, A.M. and Compton, R.G. (1989) in Comprehensive Chemical Kinetics, Compton, R.G. and Hamnett, A. (eds), Vol. 29, Elsevier, Amsterdam, Chapter 7.

    Google Scholar 

  • West, A.R. (1985) Solid State Chemistry and its Applications, John Wiley and Sons, Chichester.

    Google Scholar 

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(1994). Techniques Giving Mechanistic Information. In: Techniques and Mechanisms in Electrochemistry. Springer, Dordrecht. https://doi.org/10.1007/978-0-585-27623-6_2

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  • DOI: https://doi.org/10.1007/978-0-585-27623-6_2

  • Publisher Name: Springer, Dordrecht

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