Skip to main content

Coatings for Increasing and Preserving the Bending Strength of Glass

  • Chapter
Sol-Gel Technologies for Glass Producers and Users

Abstract

The practical strength of glass with a value of about 100 MPa is approximately 100 times smaller than its theoretical ones [1]. This is due to micro flaws on the glass surface, which amount up to 50.000 on one cm2[2]. During the handling of glass externals stresses are amplified by these flaws, like clefts, pores or inclusions [3]. The degree of amplification depends on the geometry of the crack tip, which can be strongly influenced by chemical interactions with the surroundings. Depending on the intensity of these external influences, a rather slow crack propagation is observed under subcritical load (static fatigue). However, when the applied tensile stress exceeds a critical value (Kic-factor) the crack grows spontaneously with almost the speed of sound [4,5], leading essentially to the breaking of the glass.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 169.00
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 219.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 219.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. II. Müller-Simon, J. Wagner, A. Lenhardt, Practical strength of glass containers Part. 1: Influence of the type of defects, Glastechn. Ber. Glass Sci. Technol,67(5), 134 (1994)

    Google Scholar 

  2. F. M. Ernsberger, Advances in glass technology, New York, Plenum Press 511 (1962)

    Google Scholar 

  3. A. Griffith, Phil. Trans., A221, 163 (1920)

    Google Scholar 

  4. O. L Anderson, T. L. Preiser, Role of environment in stress corrosion cracking in silicate glasses, .1. Am. Ceram. Soc,61, 534 (1978)

    Article  CAS  Google Scholar 

  5. S. M. Wiederhorn, Influence of water vapor on crack propagation in solda-lime glass, J. Am. Soc,50, 407 (1967)

    CAS  Google Scholar 

  6. II. Richter, Festigkeit anorganischer, nichtmetallischer Werkstoffe, HVG Fortbildungskurs, Festigkeit von Glas, 1 (1987)

    Google Scholar 

  7. II. Scholze, Glas-Natur, Struktur und Eigenschaften, 3. Auflage, Springer Verlag Berlin (1988)

    Google Scholar 

  8. B. D. Fabes, D. R. Uhlmann, Strengthening of glass by sol-gel coatings, J. Am. Ceram. Soc,73,978(1990)

    Article  CAS  Google Scholar 

  9. H. Schmidt, Presentation at Soc. of Glass Tech. Symp. on Glass Strength, Harrowgate (1988)

    Google Scholar 

  10. P. Strehlow, II. Schmidt, Verfahren zur Herstellung von Gläsern mit erhöhter Bruchfestigkeit, EP 0294830 Bl

    Google Scholar 

  11. A. Gier, M. Amlung, K. Endres, M. Mennig, H. Schmidt, Untersuchungen zur Festigkeit von Glas: Verhalten und Heilen von Mikrorissen unter gezielten chemischen, atmosphärischen und mechanischen Bedingungen, AiF Abschlussbericht, Nr. 10651, Institut für Neue Materialien, Saarbrücken (1998)

    Google Scholar 

  12. DIN 52 292, T 1 (April 1984): Bestimmung der Biegebruchfestigkeit: Doppelringbiegeversuch an platten form igen Proben mit kleiner Probenfläche. Berlin DIN 1984

    Google Scholar 

  13. W. A. Weibull, A statistical distribution of wide applicability, J. Appl. Mech.,18, 293 (1951)

    Google Scholar 

  14. M. Mennig, G. Jonschker, H. Schmidt, Sol-gel derived thick coatings and their thermochemical and optical properties, in: Spie Proc“Sol-Gel Optics H”, vol. 1758, 125 (1992)

    Google Scholar 

  15. M. Mennig, G. Jonschker, H. Schmidt, Verfahren zur Herstellung von Glas mit verbesserter Langzeitstandfestigkeit bei erhöhten Temperaturen, DE 4217432 Al

    Google Scholar 

  16. DIN 52 348 (Februar 1985) Prüfung von Glas und Kunststoff. Verschleißprüfung, Sandrieselver-fahren. Berlin DIN 1985

    Google Scholar 

  17. R. Hauk, G.H. Frischat, K. Ruppert, Sol-gel preparation of scratch resistant AI2O3coatings on float glass, in: Glastechnische Berichte. Glass Science and Technology,72, 386 (1999)

    Google Scholar 

  18. A. Gier, D. Anschütz, M. Mennig, H. Schmidt, Untersuchungen zur Festigkeit von Glas: Festigkeitserhaltende und festigkeitserhöhende Schichten auf Glas, AiF Abschlußbericht, Nr. 11685N, Institut für Neue Materialien, Saarbrücken, 2000

    Google Scholar 

  19. M. Mennig, A. Gier, D. Anschütz, H. Schmidt, Development of organic-inorganic coatings for strength-preserving of glass bottles, Glastechnische Berichte, Glass Science and Technology, 74, 217(2001)

    CAS  Google Scholar 

Download references

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2004 Springer Science+Business Media New York

About this chapter

Cite this chapter

Gier, A., Endres, K., Anschütz, D., Mennig, M., Schmidt, H. (2004). Coatings for Increasing and Preserving the Bending Strength of Glass. In: Aegerter, M.A., Mennig, M. (eds) Sol-Gel Technologies for Glass Producers and Users. Springer, Boston, MA. https://doi.org/10.1007/978-0-387-88953-5_31

Download citation

  • DOI: https://doi.org/10.1007/978-0-387-88953-5_31

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4419-5455-8

  • Online ISBN: 978-0-387-88953-5

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics