Orientation Imaging Microscopy in Research on High Temperature Oxidation


High temperature oxidation of steel has been studied for reducing steel losses and for understanding descaling of oxides (Kuiry et al. 1994; Tomellini and Mazzarano 1988; Sachs and Tuck 1968). Surface defects, such as scale pits and residues, are frequently observed on steel surfaces after hot rolling. The occurrence of surface defects is related to the formation of oxide scale. These defects are undesirable for the surface quality control of slab in the hot rolling process. The quality control of steel products is highly dependent on the removal of scale on slab during the hot rolling process. This is directly related to the scale structure formed in high temperature oxidation.


High Temperature Oxidation Isothermal Oxidation Orientation Imaging Microscopy Continuous Oxidation Magnetite Layer 
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  1. Abuluwefa H, Root JH, Guthrie RIL, Ajersch F (1996) Real-time observations of the oxidation of mild steel at high temperature by neutron diffraction. Metall Mater Trans B 27: 993–997CrossRefGoogle Scholar
  2. Baba-Kishi KZ, Dingley DJ (1989) Backscatter Kikuchi diffraction in the SEM for identification of crystallographic point groups. Scanning 11:305–312Google Scholar
  3. Béranger G (1996) Oxidation. In: Béranger G, Henry G, Sanz G (eds) The book of steel (trans Davidson J.H). Intercept LTD, Andover, U.K.Google Scholar
  4. Birks N, Meier GH (1983) Introduction to high temperature oxidation of metals. Edward Arnold, LondonGoogle Scholar
  5. Birosca S, Dingley D, Higginson RL (2004) Microstructural and microtextural characterization of oxide scale on steel using electron backscatter diffraction. J Microsc 213:235–240CrossRefPubMedMathSciNetGoogle Scholar
  6. Bredesen R, Kofstad P (1990) On the oxidation of iron in CO2 + CO gas mixtures: I. Scale morphology and reaction kinetics. Oxid Met 34:361–379CrossRefGoogle Scholar
  7. Bruckman K, Simkovich G (1972) Concerning the mechanism of scale growth due to cation diffusion in Fe2O3 and CuS. Corros Sci 12:595–601CrossRefGoogle Scholar
  8. Buscail H, Larpin JP (1996) The influence of cerium surface addition on low-pressure oxidation of pure iron at high temperatures. Solid State Ionics 92:243–251CrossRefGoogle Scholar
  9. Caplan D, Cohen M (1966) Effect of cold work on the oxidation of iron from 400 to 650°C. Corros Sci 6:321–335CrossRefGoogle Scholar
  10. Caplan D, Graham MJ, Cohen M (1970a) Effect of oxygen pressure and experimental method on the high temperature oxidation of pure Fe. Corros Sci 10:1–8CrossRefGoogle Scholar
  11. Caplan D, Sproule GI, Hussey RJ (1970b) Comparison of the kinetics of high-temperature oxidation of Fe as influenced by metal purity and cold work. Corros Sci 10:9–17CrossRefGoogle Scholar
  12. Carpenter DL, Ray AC (1973) The effect of metallurgical pretreatment on the kinetics of oxidation of iron at 700°C in pure gaseous oxygen. Corros Sci 13:493–502CrossRefGoogle Scholar
  13. Caudron E, Buscail H, Riffard F (1999) Initial oxidation stage of yttrium implanted pure iron at 700°C by in situ high temperature X-ray diffraction. Eur Phys J-Appl Phys 8:233–240CrossRefADSGoogle Scholar
  14. Chen RY, Yuen WYD (2000) A study of the scale structure of hot rolled steel strip by simulated coiling and cooling. Oxid Met 53(5/6):539–560CrossRefGoogle Scholar
  15. Condon NG, Murray PW, Leibsle FM, Thornton G, Lennie AR, Vaughan DJ (1994) Fe3O4 (111) termination of α- Fe2O3 (0001). Surf Sci 310:L609–L613CrossRefGoogle Scholar
  16. Cornell RM, Schwertmann U (1996) The iron oxides. VCH, Weinheim, Germany, 458Google Scholar
  17. Davies MH, Simnad MT, Birchenall CE (1951) Mechanism and kinetics of the scaling of iron. J Met-T AIME 3:889–896Google Scholar
  18. Davies MJ, Parker SC (1989) Unpublished works (Bath University) cited in: Robertson J, Manning, MI (1990) Mater Sci Techn 6:81–91Google Scholar
  19. Dingley DJ, Randle V (1992) Microtexture determination by electron back-scatter diffraction. J Mater Sci 27:4545–4566CrossRefADSGoogle Scholar
  20. Dubinin GN (2000) On the columnar structure of a diffusion layer. Met Sci Heat Treat 42:89–93CrossRefGoogle Scholar
  21. Eades A (2000) EBSD: Buying a system. In: Schwartz AJ, Kumar M, Adams BL (eds) Electron backscatter diffraction in materials science. Kluwer Academic/Plenum, New YorkGoogle Scholar
  22. Goehner RP, Michael JR (1996) Phase identification in a scanning electron microscope using backscattered electron Kikuchi patterns. J Res Natl Inst Stand Tech 101: 301–308Google Scholar
  23. Graat PCJ, Brongers MPH, Zandbergen HW, Somers MAJ, Mittemeijer EJ (1997) HREM investigation of the constitution and the crystallography of thin thermal oxide layers on iron. In: Newcomb SB, Little JA (eds) Microscopy of oxidation, vol. 3. Institute of Materials, London, pp 503–514Google Scholar
  24. Gulbransen EA, Ruka R (1952) Role of crystal orientation in the oxidation of iron. J Electrochem Soc 99:360–368CrossRefGoogle Scholar
  25. Hauffe (1965) Oxidation of metals. Plenum, New YorkGoogle Scholar
  26. Higginson RL, Roebuckb B, Palmiere EJ (2002) Texture development in oxide scales on steel substrates. Scripta Mater 47:337–342CrossRefGoogle Scholar
  27. Iordanova I, Surtchev M, Forcey KS, Krastev V (2000) High-temperature surface oxidation of low-carbon rimming steel. Surf Interface Anal 30:158–160CrossRefGoogle Scholar
  28. Katrakova D, Maas C, Hohnerlein D, Mucklich F (1998) Experiences on contrasting microstructure using orientation imaging microscopy. Prakt Metall 35:4–20Google Scholar
  29. Kim BK, Szpunar JA (2001a) Orientation imaging microscopy for the study of high temperature oxidation. Scripta Mater 44:2605–2610CrossRefGoogle Scholar
  30. Kim BK, Szpunar JA (2001b) Grain growth of iron oxides during high temperature oxidation. In: Gottstein G, Molodov DA (eds) Proceedings of the first joint international conference on recrystallization and grain growth, Aug. 27–31. Aachen, GermanyGoogle Scholar
  31. Kofstad P (1988) High temperature oxidation. Elsevier Applied Science, LondonGoogle Scholar
  32. Kuiry SC, Roy SK, Bose SK (1994) A superficial coating to improve high-temperature-oxidation resistance of a plain-carbon steel under nonisothermal conditions. Oxid Met 41:65–79CrossRefGoogle Scholar
  33. Lagoeiro LE (1998) Transformation of magnetite to hematite and its influence on the dissolution of iron oxide minerals. J Metamorph Geol 16:415–423CrossRefGoogle Scholar
  34. Li H (2001) TexTools, ver. 3.1Google Scholar
  35. Matthies S, Vinel GW (1993) On some methodical developments concerning calculations performed directly in the orientation space. Mater Sci Forum 157–162:1641–1646Google Scholar
  36. Mehl RF, Candless EL, Rhines FN (1934) Orientation of oxide films on metals. Nature 134:1009CrossRefADSGoogle Scholar
  37. Michael JR, Eades JA (2000) Use of reciprocal lattice layer spacing in electron backscatter diffraction pattern analysis. Ultramicroscopy 81:67–81CrossRefPubMedGoogle Scholar
  38. Michael JR, Goehner RP (1993) Crystallographic phase identification in the scanning electron microscope: Backscattered electron Kikuchi patterns imaged with a CCD-based detector. MSA Bulletin 23:168–175Google Scholar
  39. Newcomb SB, Stobbs WM (1985) Proceedings of Electron Microscopy and Analysis Group (EMAG) Conference. The Institute of Physics, Newcastle upon Tyne, 2–5 Sept., UK., 451Google Scholar
  40. Pawlik K, Pospiech J, Lücke K (1991) The ODF approximation from pole figures with the aid of the ADC method. Texture Microstructure 14–18, 25–30CrossRefGoogle Scholar
  41. Pinder LW (1995) The oxidation resistance of low-alloy steels. In: Shreir LL, Jarman RA, Burstein GT (eds) Corrosion, vol. 1. Butterworth Heinemann, LondonGoogle Scholar
  42. Randle V, Engler O (2000) Introduction to texture analysis: macrotexture, microtexture and orientation mapping. Gordon & Breach Science, Amsterdam, The NetherlandsGoogle Scholar
  43. Sachs K, Tuck CW (1968) Surface oxidation of steel in industrial furnaces. Proceedings of the conference reheating for hot working. Iron and Steel Institute, Publication No. 111, London, pp 1–17Google Scholar
  44. Scully JC (1990) The Fundamentals of corrosion. Pergamon Press, OxfordGoogle Scholar
  45. Swell PB, Cohen M (1964) The oxidation of iron single crystals around 200°C. J Electrochem Soc 111(5):501–508CrossRefGoogle Scholar
  46. Tomellini M, Mazzarano A (1988) High-temperature oxidation under time-dependent gas pressure: An application to steel oxidation. Oxid Met 29(3/4):179–191CrossRefGoogle Scholar
  47. Tominaga J, Wakimoto K, Mori T, Murakami M, Yoshimura T (1982) Manufacture of wire rods with good descaling property. Trans ISIJ 22:646–656Google Scholar
  48. TSL (2000) OIM analysis user manual (ver. 3.07)Google Scholar
  49. Wagner JB, Lawless KR Jr, Gwathmey AT (1961) T Metall Soc AIME 221:257–261Google Scholar
  50. Watanabe Y, Ishii K (1995) Geometrical consideration of the crystallography of the transformation from α-Fe2O3 to Fe3O4. Phys Status Solidi A 150:673–686CrossRefADSGoogle Scholar
  51. Wright SI, Nowell MM (2002) Chemistry assisted phase differentiation in automated electron backscatter diffraction. Microsc Microanal 8(Suppl 2):682–683Google Scholar

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© Springer Science+Business Media, LLC 2009

Authors and Affiliations

  1. 1.Department of Mining and Materials EngineeringMcGill UniversityMontrealCanada
  2. 2.Corporate R&D Institute, Samsung Electro-MechanicsSuwonKorea 443–743
  3. 3.Department of Mining, Metals and Materials EngineeringMcGill UniversityMontrealCanada

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