Effect of Pigment Dispersion on Durability of a TiO2 Pigmented Epoxy Coating During Outdoor Exposure

  • Cyril Clerici
  • Xiaohong Gu
  • Li-Piin Sung
  • Aaron M. Forster
  • Derek L. Ho
  • Paul Stutzman
  • Tinh Nguyen
  • Jonathan W. Martin


Dynamic Mechanical Thermal Analysis Dynamic Mechanical Thermal Analysis Outdoor Exposure Epoxy Coating Pigment Coating 
These keywords were added by machine and not by the authors.


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  1. (1).
    Braun, J.H., “Gloss of Paint Films and the Mechanism of Pigment Involvement,” J. Coat. Technol., 63, No. 799, 43-51 (1991).Google Scholar
  2. (2).
    Rutter, E.G., J. Oil Colour Chem. Assoc., 28, 187 (1945).Google Scholar
  3. (3).
    Colling, J.H. and Dunderdale, J., “The Durability of Paint Films Containing Titanium Dioxide— Contraction, Erosion, and Clear Layer Theories,” Prog. Org. Coat., 9, 47-84 (1981).CrossRefGoogle Scholar
  4. (4).
    Perera, D.Y., “Effect of Pigmentation on Organic Coating Characteristics,” Prog. Org. Coat., 50, 247-262(2004).CrossRefGoogle Scholar
  5. (5).
    Hosseinpour, D., Guthrie, J.T., and Berg, J.C., “The Effect of Additives on the Quality of Dispersion and Physical Properties of an Automotive Coating Pigmented with TiO2,” J. Adhes. Sci. Technol., 21, 141-151(2007).CrossRefGoogle Scholar
  6. (6).
    Farrokhpay, S., Morris, G.E., Fornasiero, D., and Self, P., “Titania Pigment Particles Dispersion in Water-Based Paint Films,” J. Coat. Technol. Res., 3, No. 4, 275-283(2006).Google Scholar
  7. (7).
    Rabeck, J.F., Polymer Photodegradation—Mechanisms and Experimental Method, Chapman & Hall, New York, 1995.Google Scholar
  8. (8).
    Luoma, G.A. and Rowland, R.D., “Environmental Degradation of Epoxy Resin Matrix,” J. Appl. Polym. Sci., 32, 5777-5790(1986).Google Scholar
  9. (9).
    VanLandingham, M.R., Nguyen, T., Byrd, W.E., and Martin, J.W., “On the Use of the Atomic Force Microscopy to Monitor Physical Degradation of Polymeric Coating Surfaces,” J. Coat. Technol., 73, No. 923, 43(2001).Google Scholar
  10. (10).
    Gu, X., Sung, L., Kidah, B., Oudina, M., Martin, D., Rezig, A., Nguyen, T., and Martin, J.W., “Relating Topographical Change to Gloss Loss of Polymer Coatings during UV Radiation,” ACS Symposium Series, Nanotechnology Applications in Coatings, 2007.Google Scholar
  11. (11).
    Gu, X., Nguyen, T., Oudina, M., Martin, D., Kidah, B., Jasmin, J., Rezig, A., Sung, L., Byrd, E., Martin, J.W., Ho, D.L., and Jean, Y.C., “Microstructure and Morphology of Amine-Cured Epoxy Coatings Before and After Outdoor Exposures—An AFM Study,” J. Coat. Technol., 2, No. 7, 547- 556(2005).Google Scholar
  12. (12).
    Sung, L., Jasmin, J., Gu, X., Nguyen, T., and Martin, J.W., “Use of Laser Scanning Confocal Microscopy for Characterization Changes in Film Thickness and Local Surface Morphology of UV Exposed Polymer Coatings,” J. Coat. Technol. Res., 1, No. 4, 267-276(2004).Google Scholar
  13. (13).
    Faucheu, J., Wood, K.A., Sung, L., and Martin, J.W., “Relating Gloss Loss to Topographical Features of a PVDF Coating,” J. Coat. Technol. Res., 3, No. 1, 29-39(2006).Google Scholar
  14. (14).
    Barker, J.G., Glinka, C.J., Moyer, J.J., Kim, M.H., Drews, A.R., and Agamalian, M., “Design and Performance of a Thermal-neutron Double-crystal Diffractometer for USANS at NIST,” J. Appl. Crystallography, 38, 1004-1011(2005).CrossRefGoogle Scholar
  15. (15).
    Higgins, J.S. and Benoit, H.C., Polymers and Neutron Scattering, Oxford, New York, 1994.Google Scholar
  16. (16).
    ImageJ is a free public domain image analysis program available from the U.S. National Institute of Health website (http://rsb.info.nih.gov/ij/).
  17. (17).
    Dickens, B. in Service Life Prediction: Methodology and Metrologies, Martin, J.W. and Bauer , D.R. (Eds.), American Chemical Society, 2001.Google Scholar
  18. (18).
    Oliver, W.C. and Pharr, G.M., J. Mater. Res., 7, 156(1992).CrossRefGoogle Scholar
  19. (19).
    Asif, S.A.S., Wahl, K.J., and Colton, R.J., Review of Scientific Instruments, 70, 2408(1999).CrossRefGoogle Scholar
  20. (20).
    Guinier, A. and Fournet, G., Small Angle Scattering of X-Rays,Wiley, New York, 1955.Google Scholar
  21. (21).
    Sung, L., Clerici, C., Hu, H., and Gu, X., “Relating Optical Properties to Pigment Dispersion of Weathered Pigmented Polymeric Coatings,” Proc. 4th International Symposium on Service Life Prediction of Coatings, Key Largo, FL, 2006.Google Scholar
  22. (22).
    Biggs, S., Lukey, C.A., Spinks, G.M., and Yau, S., “An Atomic Force Microscopy Study of Weathering of Polyester/melamine Paint Surfaces,” Prog. Org. Coat., 42, 49-58(2001).CrossRefGoogle Scholar
  23. (23).
    Rezig, A., Nguyen, T., Martin, D., Sung, L., Gu, X., and Martin, J.W., “Relationship Between Chemical Degradation and Thickness Loss of an Amine-Cured Epoxy Coating Exposed to Different UV Environments,” J. Coat. Technol. Res. 3, No. 3, 173-184(2006).CrossRefGoogle Scholar
  24. (24).
    Forster, A.M., Waston, S.S., Forster, A.L., and Drzal, P.L., “Quantifying Surface Mechanical Properties of Filled Coatings Exposed to Accelerated Weathering Conditions,” submitted to J. Coat. Technol. Res. Google Scholar

Copyright information

© Springer Science+Business Media, LLC 2009

Authors and Affiliations

  • Cyril Clerici
    • 1
  • Xiaohong Gu
    • 1
  • Li-Piin Sung
    • 1
  • Aaron M. Forster
    • 1
  • Derek L. Ho
    • 2
  • Paul Stutzman
    • 3
  • Tinh Nguyen
    • 1
  • Jonathan W. Martin
    • 1
  1. 1.Polymeric Materials GroupBuilding and Fire Research Laboratory, National Institute of Standards and TechnologyGaithersburg
  2. 2.Electronic Materials GroupMaterials Science and Engineering LaboratoryNIST
  3. 3.Inorganic Materials GroupBuilding and Fire Research LaboratoryNIST

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