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Structural Disorder, Diffusion Pathway of Mobile Oxide Ions, and Crystal Structure in Perovskite-Type Oxides and Related Materials

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Book cover Perovskite Oxide for Solid Oxide Fuel Cells

Part of the book series: Fuel Cells and Hydrogen Energy ((FCHY))

Solid oxides with high ionic conductivity have attracted considerable attention for reasons of their many possible applications, including solid oxide fuel cells (SOFCs), sensors, catalysts, and batteries. Oxide ion (O2−) conductors such as zirconia (ZrO2) solid solutions [1, 2], bismuth oxide (Bi2O3)-based materials [3–6], ceria (CeO2)-based solid solutions [7, 8], and lanthanum gallate-based compounds [9, 10] have been widely investigated. The development of improved electrolyte and electrode materials requires a better understanding of the mechanism of ionic conduction, and crucial to this is comprehension of the crystal structure at high temperatures at which these materials work most efficiently [5, 6, 8, 10–15]. The detailed structural analysis enables the observation of the structural disorders and diffusion paths of mobile ions in ionic and mixed conductors [5, 6, 8, 10–15].

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Acknowledgments

The author acknowledges all the authors and collaborators of the joint papers mentioned in the references. In particular, the author expresses special thanks to Dr. K. Nomura for useful discussion. We also thank Dr. K. Ohoyama and Mr. K. Nemoto for use of the HERMES diffractometer. Figures 6.5, 6.6, 6.7, 6.8, 6.9, 6.10, 6.11, 6.14, and 6.15 were drawn using the VENUS [29] and VESTA [81] programs developed by Dr. R. Dilanian, Dr. K. Momma, and Dr. F. Izumi. This research was supported in part by the Ministry of Education, Culture, Sports, Science and Technology of Japan (Monbu-Kagaku-sho).

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    Masatomo Yashima

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    Yashima, M. (2009). Structural Disorder, Diffusion Pathway of Mobile Oxide Ions, and Crystal Structure in Perovskite-Type Oxides and Related Materials. In: Ishihara, T. (eds) Perovskite Oxide for Solid Oxide Fuel Cells. Fuel Cells and Hydrogen Energy. Springer, Boston, MA. https://doi.org/10.1007/978-0-387-77708-5_6

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    • DOI: https://doi.org/10.1007/978-0-387-77708-5_6

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