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Ionic Conduction in Perovskite-Type Compounds

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Perovskite Oxide for Solid Oxide Fuel Cells

Part of the book series: Fuel Cells and Hydrogen Energy ((FCHY))

A perovskite-type oxide typically expressed by ABO3 is structurally stable because of its well-balanced geometrical array of constituent atoms and their valences, as described in Chapter 1, which means that the deviation from its strict stoichiometric composition is allowed to a considerable extent, keeping the original perovskite-type structure. Thus, a nonstoichiometric perovskite such as oxygen-deficient ABO3–δ, A-deficient A1−δBO3, or B-deficient AB1−δO3 often appears, where δ expresses the number of deficient atoms per unit formula. In the first case, an oxygen vacancy would be formed, and in the second and third cases deviation from stoichiometric composition (A:B = 1:1) would result in the formation of some lattice imperfections. Also, it is possible to partially substitute a foreign atom M for A or B in ABO3 forming A1−xMxBO3−δ or AB1−xMxO3−δ. If the valence of M is different from A or B, lattice defects would be formed to maintain the electrical neutrality of the crystal.

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  1. Nagoya University, Furo-cho, Chigusaku, Nagoya, 464-8601, Japan

    Hiroyasu Iwahara

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    Iwahara, H. (2009). Ionic Conduction in Perovskite-Type Compounds. In: Ishihara, T. (eds) Perovskite Oxide for Solid Oxide Fuel Cells. Fuel Cells and Hydrogen Energy. Springer, Boston, MA. https://doi.org/10.1007/978-0-387-77708-5_3

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    • DOI: https://doi.org/10.1007/978-0-387-77708-5_3

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