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Experimental Methods to Evaluate the Critical Properties of Electrodes and Electrolytes

Because of the desire to discover and optimize materials and configurations to be used in the components of advanced batteries, it is important to have a set of tools to evaluate their properties. A number of methods have been developed for this purpose, and the most useful and important ones are described and discussed in the following pages.

It is critical when using any such tool to design experiments that isolate the particular property that is to be evaluated. This is sometimes difficult to do, for battery materials and systems often consist of a number of components, with a significant degree of interaction among them.

Keywords

Critical Property Transference Number Chemical Diffusion Electroactive Species Mixed Conductor 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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References

  1. 1.
    W. Hittorf, Ann. Phys. 106, 543 (1859)Google Scholar
  2. 2.
    C. Tubandt, Z. Electrochem. 26, 338 (1920)Google Scholar
  3. 3.
    M. Hebb, J. Chem. Phys. 20, 185 (1952)CrossRefGoogle Scholar
  4. 4.
    C. Wagner, Z. Elektrochem. 60, 4 (1956)Google Scholar
  5. 5.
    C. Wagner, Proc. Int. Comm. Electrochem. Thermo. Kinet. (CITCE) 7, 361 (1957)Google Scholar
  6. 6.
    R.A. Huggins, Solid State Ionics 143, 3 (2001)CrossRefGoogle Scholar
  7. 7.
    J.W. Patterson, E.A. Bogren and R.A. Rapp, J. Electrochem. Soc. 114, 752 (1967)CrossRefGoogle Scholar
  8. 8.
    S. Crouch-Baker, Solid State Ionics 45, 101 (1991)CrossRefGoogle Scholar
  9. 9.
    V.B. Tare and H. Schmalzried, Z. Physik. Chem. NF 43, 30 (1964)Google Scholar
  10. 10.
    C. Wagner, Adv. Electrochem. Electrochem. Eng. 4, 1 (1966)Google Scholar
  11. 11.
    R.A. Huggins, Ionics 5, 269 (1999)CrossRefGoogle Scholar
  12. 12.
    W. Weppner and R.A. Huggins, J. Electrochem. Soc. 124, 1569 (1977)CrossRefGoogle Scholar
  13. 13.
    W. Weppner and R.A. Huggins, Electrochemical Methods for Determining Kinetic Properties of Solids in Annual Review of Materials Science, R.A. Huggins, Ed., Annual Reviews, Inc., Palo Alto, CA (1978), p. 269Google Scholar
  14. 14.
    C. Ho, I.D. Raistrick and R.A. Huggins, J. Electrochem. Soc. 127, 343 (1980)CrossRefGoogle Scholar
  15. 15.
    C.J. Wen, C. Ho, B.A. Boukamp, I.D. Raistrick, W. Weppner and R.A. Huggins, Int. Metals Rev. 5, 253 (1981)Google Scholar
  16. 16.
    C. Wagner, J. Chem. Phys. 21, 1819 (1953)CrossRefGoogle Scholar
  17. 17.
    A.L. L'vov, et al. Elektrokhimiya 11, 1322 (1975)Google Scholar
  18. 18.
    B.E. Conway, J. Electrochem. Soc. 138, 1539 (1991)CrossRefGoogle Scholar
  19. 19.
    I.D. Raistrick, C. Ho, Y.W. Hu and R.A. Huggins, J. Electroanal. Chem. 77, 319 (1977)CrossRefGoogle Scholar
  20. 20.
    I.D. Raistrick, C. Ho and R.A. Huggins, J. Electrochem. Soc. 123, 1469 (1976)CrossRefGoogle Scholar
  21. 21.
    V. Thangadurai, R.A. Huggins and W. Weppner, Determination of the Electronic and Ionic Partial Conductivities in Several Mixed Conductors Using a Simple AC Method, in Elec-trochem Society Proceedings, Vol. 2001–28, A. Nazri, Ed., Electrochem Society, Pennington, NJ (2001), p. 109Google Scholar

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