Bulk Heterojunction Solar Cells for Large-Area PV Fabrication on Flexible Substrates

  • C. Waldauf
  • G. Dennler
  • P. Schilinsky
  • C. J. Brabec
Part of the Electronic Materials: Science & Technology book series (EMST, volume 11)

Introduction and Motivation


Photovoltaics (PV) is the harvesting of energy from sunlight and conversion into electrical power. This technology is being increasingly recognized as one of the key components in our future global energy scenario. The limited resources of fossil fuel and the steadily increasing costs to supply fossil fuels to the market give a natural limit when renewable energies will begin to kick in as major energy suppliers. In addition, the detrimental long-term effects of CO2 and other emissions from burning fossil fuels into our atmosphere underscore the multiple benefits of developing renewable energy resources and commercializing them.

Certainly, PV technology is only one of many alternative renewable energies like wind, biomass, and water. Though all of these technologies are expected to give significant contributions to the world’s energy supply in the next century, PV has three key properties that make it unique:
  • it directly generates electricity...


Solar Cell Ideality Factor Organic Semiconductor Organic Solar Cell Water Vapor Transmission Rate 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.


  1. 1.
    Shockley W, Queisser HJ (1961) Detailed Balance Limit of Efficiency of p-n Junction Solar Cells J Appl Phys 32:510Google Scholar
  2. 2.
    Gregg BA, Hanna MC (2003) J Appl Phys 93:3605Google Scholar
  3. 3.
    Sariciftci NS (ed) (1997) Primary Photoexcitation in Conjugated Polymers: Molecular Exciton Versus Semiconductor Band Model. World Scientific, SingaporeGoogle Scholar
  4. 4.
    Gregg BA (2003) J Phys Chem B 107:4688Google Scholar
  5. 5.
    O’Regan B, Graetzel M (1991) Nature 353:737Google Scholar
  6. 6.
    Yu G, Gao J, Hummelen JC, Wudl F, Heeger AJ (1995) Science 270:1789Google Scholar
  7. 7.
    Drechsel J, Männig B, Kozlowski F, Pfeiffer M, Leo K, Hoppe H (2005) Appl Phys Lett 86:244101Google Scholar
  8. 8.
    Huynh WU, Dittmer JJ, Alivisatos AP (2002) Science 295:2425Google Scholar
  9. 9.
    Onsager L (1938) Phys Rev 54:554Google Scholar
  10. 10.
    Schweitzer B, Bässler H (2000) Synth Met 109:1Google Scholar
  11. 11.
    Haugeneder A, Neges M, Kallinger C, Spirkl W, Lemmer U, Feldmann J, Scherf U, Harth E, Gügel A, Müllen K (1999) Phys Rev B 59:15346Google Scholar
  12. 12.
    Vacar D, Maniloff ES, McBranch DW, Heeger AJ (1997) Phys Rev B 56:4573Google Scholar
  13. 13.
    Theander M, Yartsev A, Zigmantas D, Sundström V, Mammo W, Andersson MR, Inganäs O (2000) Phys Rev B 61:12957Google Scholar
  14. 14.
    Popovic ZD, Hor A-M, Loutfy RO (1988) Chem Phys 127:451Google Scholar
  15. 15.
    Arkhipov VI, Emelianova EV, Bässler H (1999) Phys Rev Lett 82:1321Google Scholar
  16. 16.
    Wang Y (1992) Nature 356:585Google Scholar
  17. 17.
    Sariciftci NS, Smilowitz L, Heeger AJ, Wudl F (1992) Science 258:1474Google Scholar
  18. 18.
    Morita S, Zakhidov AA, Yoshino K (1992) Solid State Commun 82:249Google Scholar
  19. 19.
    Brabec CJ, Zerza G, Cerullo G, De Silvestri S, Luzzati S, Hummelen JC, Sariciftci NS (2001) Chem Phys Lett 340:232Google Scholar
  20. 20.
    Würfel P, Bauer G (2003) Quantum solar energy conversion in organic solar cells. In: Brabec CJ, Dyakonov V, Parisi J, Sariciftci S (eds) Organic Photovoltaics, Springer, Berlin, pp 118–158Google Scholar
  21. 21.
    Waldauf C, Schilinsky P, Hauch J, Brabec CJ (2004) Thin Solid Films 451–452:503Google Scholar
  22. 22.
    Koster LJA, Smits ECP, Mihailetchi VD, Blom PWM (2005) Phys Rev B 72:085205Google Scholar
  23. 23.
    Mihailetchi VD, Koster LJA, Hummelen JC, Blom PWM (2005) Phys Rev Lett 93:216601Google Scholar
  24. 24.
    Marcus RA (1993) Rev Mod Phys 65:599Google Scholar
  25. 25.
    Miller A, Abrahams E (1960) Phys Rev 120:745Google Scholar
  26. 26.
    Pai DM (1970) J Chem Phys 52:2285Google Scholar
  27. 27.
    Mozer AJ, Dennler G, Sarificti NS, Westerling M, Pivrikas A, Österbacka R, Juska G (2005) Phys Rev B 72:035217Google Scholar
  28. 28.
    Rakhmanova SV, Conwell EM (2001) Synth Met 116:389Google Scholar
  29. 29.
    Mozer AJ, Sariciftci NS, Pivrikas A, Österkacka R, Juska G, Brassat L, Bässler H (2005) Phys Rev B 72:035214Google Scholar
  30. 30.
    Riedel I, Parisi J, Dyakonov V, Lutsen L, Vanderzande D, Hummelen JC (2004) Adv Funct Mater 14:38Google Scholar
  31. 31.
    Gommans HHP, Kemerink M, Kramer JM, Janssen RAJ (2005) Appl Phys Lett 87:122104Google Scholar
  32. 32.
    Montanari I, Nohueira AF, Nelson J, Durrant J, Winder C, Loi MA, Sariciftci NS, Brabec CJ (2002) Appl Phys Lett 81:3001Google Scholar
  33. 33.
    O'Regan BC, Scully S, Mayer AC, Palomares E, Durrant J (2005) J Phys Chem B 109:4616Google Scholar
  34. 34.
    Meskers SCJ, van Hal PA, Spiering AJH, Hummelen JC, Janssen RAJ (2000) Phys Rev B 61:9917Google Scholar
  35. 35.
    Kroeze JE, Savenije TJ, Vermeulen MJW, Warman JM (2003) J Phys Chem B 107:7696Google Scholar
  36. 36.
    Savenije TJ, Kreoze JE, Wienk MM, Kroon JM, Warman JM (2004) Phys Rev B 69:155205Google Scholar
  37. 37.
    Juška G, Arlauskas K, Viliūnas M, Kočka J (2000) Phys Rev Lett 84:4946Google Scholar
  38. 38.
    Juska G, Arlauskas K, Viliunas M, Genevicius K, Österbacka R, Stubb H (2000) Phys Rev B 62:16235Google Scholar
  39. 39.
    Langevin P (1903) Ann Chem Phys 28:289Google Scholar
  40. 40.
    Pivrikas A, Juska G, Mozer AJ, Scharber M, Arlauskas K, Sariciftci NS, Stubb H, Osterbacka R (2005) Phys Rev Lett 94:176806Google Scholar
  41. 41.
    Mihailetchi VD, Koster LJA, Blom PWM, Melzer C, de Boer B, van Duren JKJ, Janssen RAJ (2005) Adv Funct Mater 15:795Google Scholar
  42. 42.
    Parker ID (1994) J Appl Phys 75:1656Google Scholar
  43. 43.
    Brabec CJ, Cravino A, Meissner D, Sariciftci NS, Fromherz T, Rispens MT, Sanchez L, Hummelen JC (2001) Adv Funct Mater 11:374Google Scholar
  44. 44.
    Brabec CJ, Cravino A, Meissner D, Sariciftci NS, Rispens MT, Sanchez L, Hummelen JC, Fromherz T (2002) Thin Solid Films 403–404:368Google Scholar
  45. 45.
    Kim H, Jin S-H, Suh H, Lee K (2004) Proc. SPIE 5215:111Google Scholar
  46. 46.
    Gadisa A, Svensson M, Andersson MR, Inganäs O (2004) Appl Phys Lett 84:1609Google Scholar
  47. 47.
    Frohne H, Shaheen SE, Brabec CJ, Mueller D, Sariciftci NS, Meerholz K. (2002) Chem Phys Chem 9:795Google Scholar
  48. 48.
    Würfel P. (2004) Physics of Solar Cells. Wiley VCH, WeinheimGoogle Scholar
  49. 49.
    Crispin A, Crispin X, Fahlman M, Berggren M, Salaneck, W (2006) Appl Phys Lett 89:213503Google Scholar
  50. 50.
    Waldauf C, Schilinsky P, Hauch J, Brabec CJ (2004) Thin Solid Films 451–452:503Google Scholar
  51. 51.
    Hall RN (1952) Phys Rev 87:387Google Scholar
  52. 52.
    Shockley W, Read WT (1952) Phys Rev 87:835–842Google Scholar
  53. 53.
    Merten J, Asensi JM, Voz C, Shah AV, Platz R, Andreu J (1998) IEEE Transactions on Electron Devices 45:423Google Scholar
  54. 54.
    Brabec CJ, Cravino A, Meissner D, Sariciftci NS, Fromherz T, Rispens MT, Sanchez L, Hummelen JC (2001) Adv Funct Mater 11(5):374–380Google Scholar
  55. 55.
    Montanari I, Nogueira AF, Nelson J, Durrant JR, Winder C, Loi MA, Sariciftci NS, Brabec C (2002) Appl Phys Lett 81:3001Google Scholar
  56. 56.
    Koster LJA, Mihailetchi VD, Ramaker R, Blom PWM (2005) Appl Phys Lett 86:123509Google Scholar
  57. 57.
    Mihailetchi VD, Koster LJA, Blom PWM (2004) Appl Phys Lett 85(6):971Google Scholar
  58. 58.
    Haugeneder A, Neges M, Kallinger C, Spirkl W, Lemmer U, Feldmann J, Scherf U, Harth E, Gugel A, Mullen K (1999) Phys Rev B Condens Matter 59(23):15346Google Scholar
  59. 59.
    Kankan B, Castelino K, Majumdar A (2003) Nano Lett 3(12):1729Google Scholar
  60. 60.
    Brabec CJ, Zerza G, Cerillo G, DeSilvestris S, Luzatti S, Hummelen JC, Sariciftci NS (2001) Chem Phys Lett 340:232Google Scholar
  61. 61.
    Morteani AC, Sreearunothai P, Herz LM, Friend RH, Silva C (2004) Phys Rev Lett 92(24):247402–247413Google Scholar
  62. 62.
    Halls JJM, Cornil J, dosSantos DA, Silbey R, Hwang DH, Holmes AB, Bredas JL, Friend RH (1999) Phys Rev B Condens Matter 60(8):5721Google Scholar
  63. 63.
    Fujii A, Mizukami H, Umeda T, Shirakawa T, Hashimoto Y, Yoshino K (2004) Jpn J Appl Phys 43(12):8312–8315Google Scholar
  64. 64.
    Schilinsky P, Waldauf C, Brabec CJ (2002) Appl Phys Lett 81:3885Google Scholar
  65. 65.
    Waldauf C, Schilinsky P, Hauch J, Brabec CJ (2004) Thin Solid Films 451–452:503Google Scholar
  66. 66.
    NREL certificate for Konarka solar cell E8-6 from July, 18th, 2005Google Scholar
  67. 67.
    Shaheen S, Radspinner R, Peyghambarian N, Jabbour GE (2001) Appl Phys Lett 79:2996Google Scholar
  68. 68.
    Sirringhaus H, Kawase T, Friend RH (2001) MRS Bulletin 26(7):539Google Scholar
  69. 69.
    Duren KJ, Yang X, Loos J, Bulle-Lieuwana CWT, Sieval AB, Hummelen JC, Janssen RAJ (2004) Adv Func Mat 14:425Google Scholar
  70. 70.
    Sze SM (1985) Physics of Semiconductor Devices, 2nd edn. John Wiley & Sons, New YorkGoogle Scholar
  71. 71.
    Lewerenz HJ, Jungblut H (1995) Photovoltaik. Springer, BerlinGoogle Scholar
  72. 72.
    Waldauf C, Scharber MC, Schilinsky P, Hauch JA, Brabec CJ (2006) J Appl Phys 99:104503Google Scholar
  73. 73.
    Waldauf C, Schilinsky P, Hauch J, Brabec CJ (2004) Thin Solid Films 451–452:503Google Scholar
  74. 74.
    Chang J-F, Sun B, Breiby DW, Nielsen MM, Solling T, Giles M, McCulloch I, Sirringhaus H (2004) Chem Mater 16:4772Google Scholar
  75. 75.
    Osterbacka R, An CP, Jiang XM, Vardeny ZV (2000) Science 287:839Google Scholar
  76. 76.
    Brabec CJ, Hummelen JC, Janssen RAJ, Sariciftci NS (1999) Synth Met 102:861Google Scholar
  77. 77.
    Sirringhaus H, Kawase T, Friend RH, Shimoda T, Inbasekaran M, Wu W, Woo EP (2000) Science 290:2123Google Scholar
  78. 78.
    Brabec CJ, Sariciftci NS, Hummelen JC (2001) Adv Funct Mater 11:15Google Scholar
  79. 79.
    Mäkelä T, Pienimaa S, Jussila S (1999) Synth Met 101:705Google Scholar
  80. 80.
    Granlund T, Nyberg T, Roman LS, Svensson M, Inganäs O (2000) Adv Mater 12:269Google Scholar
  81. 81.
    Tak Y-H, Kim C-N, Kim M-S, Kim K-B, Lee M-H, Kim S-T (2003) Synth Met 138:497Google Scholar
  82. 82.
    Dennler G, Lungenschmied C, Neugebauer H, Sariciftci NS, Labouret A (2005) J Mater Res 20:3224Google Scholar
  83. 83.
    Akimasa U, Susumu K (2001) Method of Fabricating Integrated Thin Film Solar Cells. Patent US6168968Google Scholar
  84. 84.
    Morgado J, Friend RH, Cacialli F (2000) Synth Met 114:189Google Scholar
  85. 85.
    Sutherland DGJ, Carlisle JA, Elliker P, Fox G, Hagler TW, Jimenez I, Lee HW, Pakbaz K, Terminello LJ, Williams SC, Himpsel FJ, Shuh DK, Tong WM, Lia JJ, Callcott TA, Ederer DL (1996) Appl Phys Lett 68:2046Google Scholar
  86. 86.
    Low HY (2002) Thin Solid Films 413:160Google Scholar
  87. 87.
    Scurlock RD, Wang B, Ogilby PR, Sheats JR, Clough RL (1995) J Am Chem Soc 117:10194Google Scholar
  88. 88.
    Cumpston BH, Parker ID, Jensen KF (1997) J Appl Phys 81:3716Google Scholar
  89. 89.
    Kumar S, Biswas AK, Shukla VK, Awasthi A, Anand RS, Narain J (2003) Synth Met 139:751Google Scholar
  90. 90.
    Do LM, Han EM, Nidome Y, Fujihira M, Kanno T, Yoshida S, Maeda A, Ikushima AJ (1994) J Appl Phys 76:5118Google Scholar
  91. 91.
    Schaer M, Nüesch F, Berner D, Leo W, Zuppiroli L (2001) Adv Func Mater 11:116Google Scholar
  92. 92.
    Hale GD, Oldenburg SJ, Halas NJ (1997) Phys Rev B 55:16069Google Scholar
  93. 93.
    Neugebauer H, Brabec CJ, Hummelen JC, Sariciftci NS (2000) Sol Ener Mater Sol Cells 61:35Google Scholar
  94. 94.
    Schuller S, Schilinsky P, Hauch J, Brabec CJ (2004) Appl Phys A 79:37Google Scholar
  95. 95.
    Jeranko T, Tributsch H, Sariciftci NS, Hummelen JC (2004) Sol Ener Mater Sol Cells 83:247Google Scholar
  96. 96.
    Krebs FC, Carlé JE, Cruys-Bagger N, Andersen M, Lilliedal MR, Hammond MA, Hvidt S (2005) Sol Ener Mater Sol Cells 86:499Google Scholar
  97. 97.
    Kroon JM, Wienk MM, Verhees WJH, Hummelen JC (2002) Thin Solid Films 403–404:223Google Scholar
  98. 98.
    Sahin Y, Alem S, De Bettignies R, Nunzi J-M (2005) Thin Solid Films 476:340Google Scholar
  99. 99.
    Brabec CJ, Padinger F, Sarificti NS, Hummelen JC (1999) J Appl Phys 85:6866Google Scholar
  100. 100.
    Lewis JS, Weaver MS (2004) IEEE. J Select Topics Quantum Elect 10:45Google Scholar
  101. 101.
    da Silva Sobrinho AS, Latreche M, Czeremuszkin G, Klemberg-Sapieha JE, Wertheimer MR (1998) J Vac Sci Technol A 16:3190Google Scholar
  102. 102.
    Leterrier Y (2003) Prog Mater Sci 48:1Google Scholar
  103. 103.
    da Silva Sobrinho AS, Czeremuszkin G, Latreche M, Dennler G, Wertheimer MR (1999) Surf Coat Technol 116–119:1204Google Scholar
  104. 104.
    Dennler G, Houdayer A, Ségui Y, Wertheimer MR (2001) J Vac Sci Technol A 19:2320Google Scholar
  105. 105.
    Russi G, Nulman M (1993) J Appl Phys 74:5471Google Scholar
  106. 106.
    da Silva Sobrinho AS, Czeremuszkin G, Latreche M, Wertheimer MR (2000) J Vac Sci Technol A 18:149Google Scholar
  107. 107.
    Affinito JD, Gross ME, Coronado CA, Graff GL, Greenwell EN, Martin PM (1996) Thin Solid Films 290–291:263Google Scholar
  108. 108.
    Affinito JD, Gross ME, Mournier PA, Shi MK, Graff GL (1999) J Vac Sci Technol A 17:1974Google Scholar
  109. 109.
    Weaver MS, Michalski LA, Rajan K, Rothman MA, Silvernail JA, Burrows PE, Graff GL, Gross ME, Martin PM, Hall M, Mast E, Bonham C, Bennett W, Zumhoff M (2002) Appl Phys Lett 81:2929Google Scholar
  110. 110.
    Chwang AB, Rothman MA, Mao SY, Hewitt RH, Weaver MS, Sivernail JA, Rajan K, Hack M, Brown JJ, Chu X, Moro L, Krajewski T, Rutherford N (2003) Appl Phys Lett 83:413Google Scholar
  111. 111.
    Dennler G, Lungenschmied C, Neugebauer H, Sariciftci NS, Latrèche M, Czeremuszkin G, Wertheimer MR (2005) Thin Sol Films 349Google Scholar
  112. 112.
    Kroon JM, Veenstra SC, Slooff LH, Verhees WJH, Koetse MM, Sweelssen J, Schoo HFM, Beek WJE, Wienk MM, Janssen RAJ, Yang X, Loos J, Michailetchi VD, Blom PWM, Knol J, Hummelen JC (2005) Proceedings of the 20th European Photovoltaic Solar Energy Conference and Exhibition, Barcelona, Spain, June 6–10, 2005Google Scholar
  113. 113.
    Schuller S, Schilinsky P, Hauch J, Brabec CJ (2004) Appl Phys A 79:37Google Scholar
  114. 114.
    Brabec CJ, Schilinsky P, Waldauf C, Hauch J (2005) MRS Bulletin January 30, 2005Google Scholar
  115. 115.
    Chamberlain GA (1983) Solar Cells 8:47Google Scholar
  116. 116.
    Simon J, Andre J-J (1985) Molecular Semiconductors. Springer-Verlag, BerlinGoogle Scholar

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© Springer Science+Business Media, LLC 2009

Authors and Affiliations

  • C. Waldauf
  • G. Dennler
  • P. Schilinsky
  • C. J. Brabec

There are no affiliations available

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