Skip to main content

Clays are ubiquitous constituents of the Earth’s crust that serve as raw materials for traditional ceramics. Mineralogically, clays are phyllosilicates or layered aluminosilicates. Bonding is strong within layers, but weak between layers, allowing clays to break into micrometer-sized particles. When mixed with water, clays develop plasticity and can be shaped easily and reproducibly. When heated, clays undergo a series of reactions that ultimately produce crystalline mullite and a silica-rich amorphous phase. Beyond the structure and properties of clays, the science that developed to understand traditional ceramics continues to serve as the framework for the study of advanced ceramics.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 129.00
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 169.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 169.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. J.S. Reed, Principles of Ceramic Processing, 2nd edn., John Wiley, New York, 1995.

    Google Scholar 

  2. C.S. Hurlbut, Dana’s Manual of Mineralogy, 15th edn., John Wiley, New York, 1941.

    Google Scholar 

  3. F.H. Norton, Fine Ceramics, McGraw Hill, New York, 1970.

    Google Scholar 

  4. L. Jiazhi, The evolution of chinese pottery and porcelain technology, in Ancient Technology to Modern Science, Ceramics and Civilization, Vol. 1, W.D. Kingery (ed.), The American Ceramic Society, Columbus, OH, 1984, pp. 135–162.

    Google Scholar 

  5. L. Gouzhen and Z. Xiqiu, The development of chinese white porcelain, in Ancient Technology to Modern Science, Ceramics and Civilization, Vol. 2, W.D. Kingery (ed.), The American Ceramic Society, Columbus, OH, 1985, pp. 217–236.

    Google Scholar 

  6. H. Ries, Clays: Their Occurrence, Properties, and Uses, 3rd edn., John Wiley, New York, 1927.

    Google Scholar 

  7. F.H. Norton, Cycles in ceramic history, in Ceramic Processing Before Firing, G.Y. Onoda and L.L. Hench (eds.), John Wiley, New York, 1978, pp. 3–10.

    Google Scholar 

  8. Mineral Commodity Survey 2003, U.S. Geological Survey, 2003.

    Google Scholar 

  9. 2001 Annual Survey of Manufacturers, U.S. Census Bureau, 2002.

    Google Scholar 

  10. T.L. Brown and H.E. LeMay, Jr., Chemistry: The Central Science, 2nd edn., Prentice-Hall, Englewood Cliffs, NJ, 1981, pp. 678–685.

    Google Scholar 

  11. C. Klein and C.S. Hurlbut, Manual of Mineralogy, 21st edn., John Wiley, New York, 1993.

    Google Scholar 

  12. W.D. Neese, Introduction to Optical Mineralogy, Oxford University Press, New York, 1986, pp. 234–251.

    Google Scholar 

  13. G.W. Brindley, Ion exchange in clay minerals, in Ceramic Fabrication Processes, W.D. Kingery (ed.), John Wiley, New York, 1958, pp. 7–23.

    Google Scholar 

  14. R.E. Grim, Applied Clay Mineralogy, McGraw-Hill, New York, 1962.

    Google Scholar 

  15. W.D. Kingery, H.K. Bowen, and D.R. Uhlmann, Introduction to Ceramics, 2nd edn., John Wiley, 1976, pp. 77–80.

    Google Scholar 

  16. M.C. Gastuche, The octahedral layer, in Clays and Clay Minerals, Proceedings of the Twelfth National Conference on Clays and Clay Minerals, W.F. Bradley (ed.), Pergamon Press, Oxford, 1963, pp. 471–493.

    Google Scholar 

  17. B. Velde, Clay Minerals: A Physico-Chemical Explanation of their Occurrence, Elsevier, Amsterdam, 1985, pp. 1–44.

    Google Scholar 

  18. G.W. Brindley, Structural mineralogy of clays, in Clays and Clay Technology, Proceedings of the First National Conference on Clays and Clay Technology, J.A. Pask and M.D. Turner (eds.), California Division of Mines, San Francisco, 1955, pp. 33–44.

    Google Scholar 

  19. P.F. Kerr, Formation and occurrence of clay minerals, in Clays and Clay Technology, Proceedings of the First National Conference on Clays and Clay Technology, J.A. Pask and M.D. Turner (eds.), California Division of Mines, San Francisco, 1955, pp. 19–32.

    Google Scholar 

  20. W. Ryan, Properties of Ceramic Raw Materials, 2nd edn., Pergamon Press, Oxford, 1978, pp. 42–72.

    Google Scholar 

  21. Kaolin Clays and Their Uses, 2nd edn., The Huber Chemical Corporation, New York, 1955.

    Google Scholar 

  22. F.H. Norton, Elements of Ceramics, Addison-Wesley, Reading, MA, 1952, pp. 1–35.

    Google Scholar 

  23. EPK Kaolin Product Information Sheet, Zemex Industrial Minerals, Atlanta, GA, 2002.

    Google Scholar 

  24. S-4 and 44-B Clay Product Information Sheets, Old Hickory Clay Company, Gleason, TN, 2001.

    Google Scholar 

  25. W.D. Kingery, Introduction to Ceramics, 1st edn., John Wiley, New York, 1960.

    Google Scholar 

  26. R.A. Haber and P.A. Smith, Overview of traditional ceramics, in Ceramics and Glasses: Engineered Materials Handbook, Vol. 4, S.J. Schneider, Jr. (ed.), ASM International, Materials Park, OH, 1991, pp. 3–15.

    Google Scholar 

  27. F.H. Norton, Clay–Water Pastes, in Ceramic Fabrication Processes, W.D. Kingery (ed.), John Wiley, New York, 1958, pp. 81–89.

    Google Scholar 

  28. S.J. Glass and K.G. Ewsuk, Ceramic powder compaction, MRS Bulletin, 1997, pp. 24–28.

    Google Scholar 

  29. B.J. McEntire, Dry pressing, in Ceramics and Glasses: Engineered Materials Handbook, Vol. 4, S.J. Schneider, Jr. (ed.), ASM International, Materials Park, OH, 1991, pp. 141–146.

    Google Scholar 

  30. I. Ruppel, Extrusion, in Ceramics and Glasses: Engineered Materials Handbook, Vol. 4, S.J. Schneider, Jr. (ed.), ASM International, Materials Park, OH, 1991, pp. 165–172.

    Google Scholar 

  31. R.E. Gould and J. Lux, Some experiences with the control of plastic bodies for automatic jiggering, in Ceramic Fabrication Processes, W.D. Kingery (ed.), John Wiley, New York, 1958, pp. 98–107.

    Google Scholar 

  32. M.H. LeChatelier, De L’Action De La Chaleur Sur Les Agriles, Societe Française Minéralogie Bulletin, 10(6), 204–211 (1887).

    Google Scholar 

  33. G.W. Brindley and M. Nakahira, The kaolinite-mullite reaction series: I, a Survey of outstanding problems; II, metakaolin; and III, the high temperature phases, J. Am. Ceram. Soc. 42(7), 311–324 (1959).

    Article  CAS  Google Scholar 

  34. K.J.D. MacKenzie, I.W.M. Brown, R.H. Meinhold, and M.E. Bowden, Outstanding problems in the kaolinite–mullite reaction sequence investigated by silicon-29 and aluminum-27 solid-state nuclear magnetic resonance: I, metakaolinite, J. Am. Ceram. Soc. 68(6), 293–297 (1985).

    Article  CAS  Google Scholar 

  35. J.A. Pask, X.W. Zhang, A.P. Tomsia, and B.E. Yoldas, Effect of sol–gel mixing on mullite microstructure and phase equilibria in the α–-Al2O3–SiO2 system, J. Am. Ceram. Soc. 70(10), 704–707 (1987).

    Article  CAS  Google Scholar 

  36. I.W.M. Brown, K.J.D. MacKenzie, M.E. Bowden, and R.H. Meinhold, Outstanding problems in the kaolinite–mullite reaction sequence investigated by 29Si and 27Al solid-state nuclear magnetic resonance: II, high temperature transformations of meta-kaolin, J. Am. Ceram. Soc. 68(6), 298–301 (1985).

    Article  CAS  Google Scholar 

  37. A.K. Chakraborty and D.K. Ghosh, Reexamination of the kaolinite-to-mullite reaction series”, J. Am. Ceram. Soc. 61(3–4), 169–173 (1978).

    Google Scholar 

  38. K.J.D. MacKenzie, J.S. Hartman, and K. Okada, MAS NMR evidence for the presence of silicon in the alumina spinel from thermally transformed kaolinite, J. Am. Ceram. Soc. 79(11), 2980–2982 (1996).

    Article  CAS  Google Scholar 

  39. K. Okada and N. Otsuka, Formation process of mullite, in Mullite and Mullite Matrix Composites: Ceramic Transactions, Vol. 6, S. Somiya, R.F. Davis, and J.A. Pask (eds.), The American Ceramic Society, Westerville, OH, 1990, pp. 375–388.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2008 Springer

About this chapter

Cite this chapter

Fahrenholtz, W.G. (2008). Clays. In: Shackelford, J.F., Doremus, R.H. (eds) Ceramic and Glass Materials. Springer, Boston, MA. https://doi.org/10.1007/978-0-387-73362-3_7

Download citation

Publish with us

Policies and ethics