Hafnium-Containing Nanocomposites

  • A. D. Pomogailo
  • A. S. Rozenberg
  • G. I. Dzhardimalieva
  • A. M. Bochkin
  • S. I. Pomogailo
  • N. D. Golubeva

New types of hafnium-containing nanocomposites were prepared by combining polymer synthesis and controlled thermolysis. This approach involved the preparation and subsequent thermolysis of hafnium-containing polymers or concurrent solid-state polymerization of hafnium-containing monomers and thermal decomposition of the forming metal-containing polymer at different temperatures. The composition and structure of the synthesized hafnium-containing precursors and thermolysis products are determined by elemental analysis, IR spectroscopy, mass spectrometry, optical microscopy, and x-ray diffraction. Thermodynamic analysis was used to assess the equilibrium composition of the Hf-C-H-O system and establish the conditions under which HfC and HfO2 were formed.


Thermolysis Product Hafnium Oxide Tantalum Carbide Hafnium Carbide Dilithium Salt 
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Copyright information

© Springer 2008

Authors and Affiliations

  • A. D. Pomogailo
    • 1
  • A. S. Rozenberg
    • 1
  • G. I. Dzhardimalieva
    • 1
  • A. M. Bochkin
    • 1
  • S. I. Pomogailo
    • 1
  • N. D. Golubeva
    • 1
  1. 1.Institute of Problems of Chemical PhysicsRussian Academy of SciencesChernogolovkaRussia

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