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Inorganic and Organometallic Macromolecules pp 1–20Cite as

Synthetic Versatility and Structural Modularity in Organometallic Polymers

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The structural and synthetic evolution surrounding organometallic polymers has given rise to great diversity in macromolecular materials. Modular approaches allow for the frontiers in this area to be pushed further, and at a faster pace. This chapter describes common designs and tunable structural features of various types of organometallic polymers with key emphasis on the manner in which the polymers are constructed. The concept of highly tunable systems without the need for redesign has inspired a new approach to organometallic polymers based on difunctional heterocyclic carbenes. This approach has several original design features, an ability to rapidly optimize or modulate structural characteristics, and provides rapid access to a diverse array of polymeric materials.

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Author information

Authors and Affiliations

  1. Department of Chemistry and Biochemistry, University of Texas at Austin, Austin, TX 78712, USA

    Andrew J. Boydston & Christopher W. Bielawski

Authors
  1. Andrew J. Boydston
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  2. Christopher W. Bielawski
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Editor information

Editors and Affiliations

  1. The University of British Columbia, Okanagan, 3333 University Way, V1V 1V7, Kelowna, British Columbia, Canada

    Alaa S. Abd-El-Aziz

  2. Department of Chemistry & Biochemistry, Florida Atlantic University, 777 Glades Rd., 33431, Boca Raton, Florida, USA

    Charles E. Carraher Jr.

  3. Department of Chemistry, Mississippi State University, 39762, Mississippi State, Mississippi, USA

    Charles U. Pittman Jr.

  4. Department of Chemistry, University of Richmond, 28 Westhampton Way, 23173, Richmond, Virginia, USA

    Martel Zeldin

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© 2008 Springer

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Boydston, A.J., Bielawski, C.W. (2008). Synthetic Versatility and Structural Modularity in Organometallic Polymers. In: Abd-El-Aziz, A.S., Carraher, C.E., Pittman, C.U., Zeldin, M. (eds) Inorganic and Organometallic Macromolecules. Springer, New York, NY. https://doi.org/10.1007/978-0-387-72947-3_1

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