Skip to main content
SpringerLink
Log in

Thermodynamics of Polymer Blends

  • Chapter
Physical Properties of Polymers Handbook

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Log in via an institution
Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 509.00
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Hardcover Book
USD 649.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. D. R. Paul, S. Newman, eds., ‘‘Polymer Blends’’, vols. 1 and 2, Academic Press, San Diego (1978).

    Google Scholar 

  2. O. Olabisi, L. M. Robeson, M. T. Shaw, ‘‘Polymer-Polymer Miscibil- ity’’, Academic Press, New York (1979).

    Google Scholar 

  3. D. R. Paul, J. W. Barlow, H. Keskkula, Encyclopedia of Polymer Science and Engineering, 2nd ed., H. F. Mark, C. G. Overberger, G. Menges, eds., Wiley Interscience, New York, 12, 399 (1988).

    Google Scholar 

  4. S. Krause, J. Macromol. Sci. Rev. Macromol. Chem. C7, 251 (1972).

    Google Scholar 

  5. M. L Huggins, J. Chem. Phys. 9, 440 (1941).

    Article  CAS  Google Scholar 

  6. P. J. Flory, J. Chem. Phys. 9, 660 (1941).

    Article  CAS  Google Scholar 

  7. The Flory-Huggins theory, originally developed for polymer/solvent systems, was extended to polymer blends and other multicomponent mixtures by R. L. Scott, J. Polym. Sci. 9, 423 (1952).

    Google Scholar 

  8. P. G. de Gennes, ‘‘Scaling Concepts in Polymer Physics’’, Cornell University Press, Ithaca, NY (1979).

    Google Scholar 

  9. L. Leibler, Macromolecules 13, 1602 (1980).

    Article  CAS  Google Scholar 

  10. L. Leibler, Macromolecules 15,1283 (1982).

    Article  CAS  Google Scholar 

  11. H. Benoit, M. Benmouna, W. L Wu, Macromolecules 23, 1511 (1990).

    Article  CAS  Google Scholar 

  12. A. Z. Akcasu, M. Tombakoglu, Macromolecules 23, 607 (1990).

    Article  CAS  Google Scholar 

  13. A. K. Dolan, S. F. Edwards, Proc. R. Soc. Lond. A 337, 509 (1974).

    Article  CAS  Google Scholar 

  14. E. Helfand, J. Chem. Phys. 62, 999 (1975).

    Article  CAS  Google Scholar 

  15. M. W. Matsen, J. Phys.: Condens. Matter 14, R21 (2002).

    Article  CAS  Google Scholar 

  16. C. C. Hsu, J. M. Prausnitz, Macromolecules 7, 320 (1974).

    Article  CAS  Google Scholar 

  17. B. J. Reynolds, M. L. Ruegg, N. P. Balsara, C. J. Radke, T. D. Shaffer, M. Y. Lin, K. R. Shull, D. J. Lohse, Macromolecules 37, 7401 (2004).

    Article  CAS  Google Scholar 

  18. B. J. Reynolds, M. L. Ruegg, T. E. Mates, C. J. Radke, N. P. Balsara, Macromolecules 38, 3872 (2005).

    Article  CAS  Google Scholar 

  19. J. H. Lee, N. P. Balsara, A. K. Chakraborty, R. Krishnamoorti, B. Hammouda, Macromolecules 35, 7748 (2002).

    Article  CAS  Google Scholar 

  20. C. Herkt-Maetzky and J. Schelten, Phys. Rev. Lett. 51, 896 (1983).

    Article  CAS  Google Scholar 

  21. C. T. Murray, J. W. Gilmore, and R. S. Stein, Macromolecules 18, 996 (1985).

    Article  CAS  Google Scholar 

  22. G. Hadziioannou and R. S. Stein, Macromolecules 17, 567 (1984).

    Article  CAS  Google Scholar 

  23. C. C. Han, B. J. Bauer, J. C. Clark, Y. Muroga, Y. Matsushita, M. Okada, Q. Tran-cong, T. Chang, I. C. Sanchez, Polymer 29, 2002 (1988).

    Article  CAS  Google Scholar 

  24. R. Krishnamoorti, W. W. Graessley, N. P. Balsara, D. J. Lohse, J. Chem. Phys. 100, 3894 (1994).

    Article  CAS  Google Scholar 

  25. N. P. Balsara, D. J. Lohse, L. J. Fetters, N. Hadjichristidis, C. C. Han, W. W. Graessley, R. Krishnamoorti, Macromolecules 25, 6317 (1992).

    Google Scholar 

  26. R. J. Roe, M. Fishkis, J. C. Chang, Macromolecules 14,1091 (1981).

    Article  CAS  Google Scholar 

  27. T. Hashimoto, M. Shibayama, H. Kawai, Macromolecules 16, 1093 (1983).

    Article  CAS  Google Scholar 

  28. G. H. Fredrickson, E. Helfand, J. Chem. Phys. 87, 697 (1987).

    Article  CAS  Google Scholar 

  29. Compare l obtained for polystyrene in N. P. Balsara, C. C. Lin, H. J. Dai, R. Krishnamoorti, Macromolecules 27, 1216 (1994) with that given in ref. 30.

    Google Scholar 

  30. J. E. Mark, ed., ‘‘Physical Properties of Polymers Handbook’’, Chapter

    Google Scholar 

  31. Chain Dimensions and Entanglement Spacings, AIP Press, Wood-bury, NY (1996).

    Google Scholar 

  32. H. S. Jeon, J. H. Lee, N. P. Balsara, M. C. Newstein, Macromolecules 31,3340 (1998).

    Article  CAS  Google Scholar 

  33. D. Y. Ryu, U. Jeong, D. H. Lee, J. Kim, H. S. Youn, J. K. Kim, Macromolecules 36, 2894 (2003).

    Article  CAS  Google Scholar 

  34. F. Scheffold, E. Eiser, A. Budkowski, U. Steiner, J. Klein, L. J. Fetters, J. Chem. Phys. 106, 8786 (1996).

    Article  Google Scholar 

  35. A. A. Lefebvre, N. P. Balsara, J. H. Lee, C. Vaidyanathan, Macromol- ecules, 35, 7758 (2002).

    Article  CAS  Google Scholar 

  36. J. H. Hildebrand, R. L. Scott, ‘‘The Solubility of Non-Electrolytes’’, Dover, New York (1964).

    Google Scholar 

  37. R. Krishnamoorti, W. W. Graessley, N. P. Balsara, D. J. Lohse, Macromolecules 27, 3073 (1994).

    Article  CAS  Google Scholar 

  38. P. A. Small, J. Appl. Chem. 3, 71 (1953).

    Article  CAS  Google Scholar 

  39. K. L. Hoy, J. Paint Technol. 42, 76 (1970).

    CAS  Google Scholar 

  40. D. W. van Krevelen ‘‘Properties of Polymers’’, Elsevier, Amsterdam (1972).

    Google Scholar 

  41. Small’s values were derived from heats of vaporization [37]. Hoy’s values were derived from vapor pressures [38]. van Krevelen’s values were based on dilute solution properties of polymers [39].

    Google Scholar 

  42. J. Rhee, B. Crist, J. Chem. Phys. 98, 4174 (1993).

    Article  CAS  Google Scholar 

  43. W.W.Graessley,R.Krishnamoorti,N.P.Balsara,L.J.Fetters,D.J.Lohse, D. N. Schulz, J. A. Sissano, Macromolecules 26, 1137 (1993).

    Google Scholar 

  44. A. D. Buckingham, H. G. E. Hentschel, J. Polym. Sci., Polym. Phys. Ed. 18, 853 (1980).

    Google Scholar 

  45. F. S. Bates, G. D. Wignall, W. C. Koehler, Phys. Rev. Lett. 55, 2425 (1985).

    Article  CAS  Google Scholar 

  46. M. L. Ruegg, B. J. Beynolds, M. Y. Lin, D. J. Lohse, N. P. Balsara, Macromolecules, 39, 1125 (2006).

    Article  CAS  Google Scholar 

  47. The calculations presented in this paper are based on the w, li , and vi values given in Tables 19.1 and 19.2. These values differ slightly from those used in ref. 45.

    Google Scholar 

  48. T. P. Russell, Macromolecules 26, 5819 (1993).

    Article  CAS  Google Scholar 

  49. T. A. Callaghan, D. K. Paul, Macromolecules 26, 2439 (1993).

    Article  CAS  Google Scholar 

  50. B. Hammouda, R. M. Briber, B. J. Bauer, Polym. Commun. 33 1785 (1992).

    CAS  Google Scholar 

  51. A. Mocannachie, R. P. Kambour, D. M. White, S. Rostami, D. J. Walsh, Macromolecules 17, 2645 (1984).

    Article  Google Scholar 

  52. R. J. Composto, E. J. Kramer, D. M. White, Macromolecules 21, 2580 (1988).

    Article  CAS  Google Scholar 

  53. C. C. Lin, S. V. Jonnalagadda, P. K. Kesani, H. J. Dai, N. P. Balsara, Macromolecules 27, 7769 (1994).

    Article  CAS  Google Scholar 

  54. J. N. Owens, I. S. Gancarz, J. T. Koberstein, T. P. Russell, Macromol- ecules 22, 3380 (1989).

    Article  CAS  Google Scholar 

  55. E. Kim, E. J. Kramer, J. O. Osby, D. J. Walsh, J. Polym. Sci., Polym. Phys. Ed. 33, 467 (1995).

    Google Scholar 

  56. D. W. Schubert, V. Abetz, M. Stamm, T. Hack, W. Siol, Macromol- ecules 28, 2519 (1995).

    Article  CAS  Google Scholar 

  57. K. H. Dai, E. J. Kramer, Polymer 35, 157 (1994).

    Article  CAS  Google Scholar 

  58. D. Y. Ryu, M. S. Park, S. H. Chae, J. Jang, J. K. Kim, T. P. Russell, Macromolecules 35, 8676 (2002).

    Article  CAS  Google Scholar 

  59. B. Bauer, B. Hammouda, T. P. Russell, Macromolecules 27, 2357 (1994).

    Article  Google Scholar 

  60. J.-L. Lin, R.-J. Roe, Macromolecules 20, 2168 (1987).

    Article  CAS  Google Scholar 

  61. T. A. Callaghan, D. R. Paul, Macromolecules 26, 2439 (1993).

    Article  CAS  Google Scholar 

  62. L. L. Chang, E. M. Woo, Macromolecules 33, 6892 (2000).

    Article  CAS  Google Scholar 

  63. J. D. Londono, G. D. Wignall, Macromolecules 30, 3821 (1997).

    Article  CAS  Google Scholar 

  64. H. Hasegawa, S. Sakurai, M. Takenaka, T. Hashimoto, C. C. Han, Macromolecules 24, 1813 (1991).

    Article  CAS  Google Scholar 

  65. D. W. Tomlin, C. M. Roland, Macromolecules 25, 2994 (1992).

    Article  CAS  Google Scholar 

  66. S. Sakurai, H. Hasegawa, T. Hashimoto, I. G. Hargis, S. L. Aggarwal, C. C. Han, Macromolecules 23, 451 (1990).

    Article  CAS  Google Scholar 

  67. F. S. Bates, M. A. Hartney, Macromolecules 18, 2478 (1985).

    Article  CAS  Google Scholar 

  68. N. P. Balsara, C. C. Lin, H. J. Dai, R. Krishnamoorti, Macromolecules 27,1216 (1994).

    Article  CAS  Google Scholar 

  69. E. W. Cochran, F. S. Bates, Macromolecules 35, 7368 (2002).

    Article  CAS  Google Scholar 

  70. N. P. Balsara, D. J. Lohse, W. W. Graessley, R. Krishnamoorti, J. Chem. Phys. 100, 3905 (1994).

    Article  CAS  Google Scholar 

  71. W. W. Graessley, R. Krishnamoorti, N. P. Balsara, L. J. Fetters, D. J. Lohse, D. N. Schulz, J. A. Sissano, Macromolecules 27,2574 (1994).

    Article  CAS  Google Scholar 

  72. W. W. Graessley, R. Krishnamoorti, N. P. Balsara, B. Butera, L. J. Fetters, D. J. Lohse, D. N. Schulz, J. A. Sissano, Macromolecules 27, 3896 (1994).

    Article  CAS  Google Scholar 

  73. W. W. Graessley, R. Krishnamoorti, G. C. Reichart, N. P. Balsara, L. J. Fetters, D. J. Lohse, Macromolecules 28, 1260 (1995).

    Article  CAS  Google Scholar 

  74. R. Krishnamoorti, PhD Thesis, Princeton University (1994).

    Google Scholar 

  75. B. J. Reynolds, M. L. Ruegg, N. P. Balsara, C. J. Radke, T. D. Shaffer, M. Y. Lin, K. R. Shull, D. J. Lohse, Macromolecules 37, 7401 (2004).

    Article  CAS  Google Scholar 

  76. M. Harada, T. Suzuki, M. Ohya, D. Kawaguchi, A. Takano, Y. Mat- sushita, Macromolecules 38, 1868 (2005).

    Article  CAS  Google Scholar 

  77. D. A. Durkee, PhD Thesis, University of California, Berkeley, in preperation.

    Google Scholar 

  78. R. Krishnamoorti, W. W. Graessley, L. J. Fetters, R. T. Garner, D. J. Lohse, Macromolecules 28, 1252 (1995).

    Article  CAS  Google Scholar 

  79. F. S. Bates, J. H. Rosedale, P. Stepanek, T. P. Lodge, P. Wiltzius, G. H. Fredrickson, R. P. Hjelm, Phys. Rev. Lett. 65, 1893 (1990).

    Article  CAS  Google Scholar 

  80. D. A. Davidock, M. A. Hillmyer, T. P. Lodge, Macromolecules 37, 397 (2004).

    Article  CAS  Google Scholar 

  81. F. S. Bates, J. H. Rosedale, G. H. Fredrickson, J. Chem. Phys. 92, 6255 (1990).

    Article  CAS  Google Scholar 

  82. F. S. Bates, G. D. Wignall, Phys. Rev. Lett. 57, 1429 (1986).

    Article  CAS  Google Scholar 

  83. F. S. Bates, L. J. Fetters, G. D. Wignall, Macromolecules 21,1086 (1988).

    Article  CAS  Google Scholar 

  84. H. Ito, T. P. Russell, G. D. Wignall, Macromolecules 20,2213 (1987).

    Article  CAS  Google Scholar 

  85. L. Zhu, S. Z. D. Cheng, B. H. Calhoun, Q. Ge, R. P. Quirk, E. L. Thomas, B. S. Hsiao, F. Yeh, B. Lotz, Polymer 42, 5829 (2001).

    Article  CAS  Google Scholar 

  86. G. Floudas, R. Ulrich, U. Wiesner, J. Chem. Phys. 110, 652 (1999).

    Article  CAS  Google Scholar 

  87. S.-M. Mai, J. P. Fairclough, I. W. Hamley, M. W. Matsen, R. C. Denny, B.-X. Liao, C. Booth, A. J. Ryan, Macromolecules 29, 6212 (1996).

    Article  CAS  Google Scholar 

  88. H. B. Eitouni, N. P. Balsara, J. Am. Chem. Soc. 126, 7446 (2004).

    Article  CAS  Google Scholar 

  89. H. B. Eitouni, N. P. Balsara, H. Hahn, J. A. Pople, M. A. Hempenius, Macromolecules 35, 7765 (2002).

    Article  CAS  Google Scholar 

  90. Y. Ren, T. P. Lodge, M. A. Hillmyer, Macromolecules 33, 868 (2000).

    Google Scholar 

  91. Y. Ren, T. P. Lodge, M. A. Hillmyer, Macromolecules 35, 3889 (2002).

    Article  CAS  Google Scholar 

  92. G. Meier, B. Momper, E. W. Fischer, J. Chem. Phys. 97, 5884 (1992).

    Article  CAS  Google Scholar 

  93. E. W. Cochran, D. C. Morse, F. S. Bates, Macromolecules 36, 782 (2003).

    Article  CAS  Google Scholar 

  94. J. K. Kim, H. H. Lee, H. W. Son, C. D. Han, Macromolecules 31, 8566 (1998).

    Article  CAS  Google Scholar 

  95. A. Maconnachie, J. R. Fried, P. E. Tomlins, Macromolecules 22, 4606 (1989).

    Article  CAS  Google Scholar 

  96. C. E. Eastman, T. P. Lodge, Macromolecules 27, 5591 (1994).

    Article  CAS  Google Scholar 

  97. M. Shibayama, H. Yang, R. S. Stein, C. C. Han, Macromolecules 18, 2179 (1985).

    Article  CAS  Google Scholar 

  98. E. Kim, G. Krausch, E. J. Kramer, J. O. Osby, Macromolecules 27, 5927 (1994).

    Article  CAS  Google Scholar 

  99. J. Scherble, B. Stark, B. Stuhn, J. Kressler, H. Budde, S. Horing, D. W. Schubert, P. Simon, M. Stamm, Macromolecules 32, 1859 (1999).

    Article  CAS  Google Scholar 

  100. L. J. Fetters, D. J. Lohse, D. Richter, T. A. Witten, A. Zirkel, Macro- molecules 27, 4639 (1994).

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemical Engineering, University of California at Berkeley, 94720, Berkeley, CA

    Hany B. Eitouni

  2. Department of Chemical Engineering, University of California at Berkeley, 94720, Berkeley, CA

    Nitash P. Balsara

Authors
  1. Hany B. Eitouni
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Nitash P. Balsara
    View author publications

    You can also search for this author in PubMed Google Scholar

Editor information

Editors and Affiliations

  1. Department of Chemistry, University of Cincinnati, Crosley Tower, Martin Luther King Drive, 45221-0172, Cincinnati, OH

    James E. Mark (Distinguished Research Profess) (Distinguished Research Profess)

Rights and permissions

Reprints and permissions

Copyright information

© 2007 Springer Science+Business Media, LLC

About this chapter

Cite this chapter

Eitouni, H.B., Balsara, N.P. (2007). Thermodynamics of Polymer Blends. In: Mark, J.E. (eds) Physical Properties of Polymers Handbook. Springer, New York, NY. https://doi.org/10.1007/978-0-387-69002-5_19

Download citation

Publish with us

Policies and ethics

Search

Navigation