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Nanocomposites pp 247–271Cite as

Mössbauer Spectroscopy and New Composite Electrodes for Li-ion batteries

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Part of the book series: Electronic Materials: Science and Technology ((EMST,volume 10))

Lithium-ion batteries have become one of the most promising power sources for portable equipment because of their high specific energy and working voltage. Many studies have been devoted to negative electrodes, which are actually carbonbased materials, in order to improve their electrochemical performances, especially the energetic capacities and the safety. For example, the theoretical specific and volumetric capacities of graphite are 372 Ah kg−1 and about 800 Ah L−1, respectively [1]. Different families of new compounds have been proposed, especially tin- or silicon-based materials that form alloys with lithium and have specific and volumetric theoretical capacities higher than about 1,000 Ah kg−1 and 7,000 Ah L−1, respectively. These materials differ by the chemical nature of the elements and Li insertion mechanisms [2–10]. The study of such complex mechanisms requires different experimental tools, especially at the atomic scale, since commonly used techniques such as X-ray diffraction (XRD) fail to characterize small particles or amorphous phases.

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Authors and Affiliations

  1. AIME, Institut Charles Gerhardt, UMR 5253 CNRS, Université Montpellier II, Place Eugène Bataillon, F-34095, Montpellier, France

    Pierre-Emmanuel Lippens & Jean-Claude Jumas

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  1. Pierre-Emmanuel Lippens
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  2. Jean-Claude Jumas
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Editors and Affiliations

  1. Université de Provence, UMR 6121 CNRS, F- 13397, Marseille, France

    Philippe Knauth

  2. Delft Institute for Sustainable Energy, 5045, 2600 GA, Delft, Netherlands

    Joop Schoonman

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Lippens, PE., Jumas, JC. (2008). Mössbauer Spectroscopy and New Composite Electrodes for Li-ion batteries. In: Knauth, P., Schoonman, J. (eds) Nanocomposites. Electronic Materials: Science and Technology, vol 10. Springer, Boston, MA. https://doi.org/10.1007/978-0-387-68907-4_8

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