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Electro-Analytical Techniques in Fuel Cell Research and Development

  • Manikandan Ramani

Abstract

Fuel cells are electrochemical devices, which convert chemical energy of the fuel to electrical energy and heat energy. In a combustion engine, fuel is mixed with air in appropriate stoichiometric ratios to initiate a combustion reaction that further creates work. In a combustion reaction, the gas species are not spatially separated, but in proton exchange membrane fuel cell (PEMFC), these combustion reactions are split into two half-cell reactions, namely, fuel oxidation and oxygen reduction, that occurs in two separate chambers called anode and cathode, respectively. If all of the chemical energy can be converted into electrical energy, then we start with the following transfer function: ΔG = Electrical work (1) where ΔG (Gibbs free energy) determines the maximum useful work that can be extracted from the system of interest. For a fuel cell reaction with hydrogen as fuel at temperature 25°C, the overall exothermic chemical reaction is given as
$$ \Delta G = Electrical work $$
(1)

Keywords

Fuel Cell Electrochemical Impedance Spectroscopy Oxygen Reduction Reaction Methanol Oxidation Catalyst Layer 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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References

  1. Agarwal, P., Orazem, M.E., Garcia-Rubio, L.H., Journal of the Electrochemical Society, 142 (1995) 4159.CrossRefGoogle Scholar
  2. Baltruschat, H., Journal of American Society for Mass Spectrometry, 15 (2004) 1693.CrossRefGoogle Scholar
  3. Brankovic, S.R., Wang, J.X., Adzic, R.R., Electrochemical and Solid State Letters, 4 (2001) A217.CrossRefGoogle Scholar
  4. Brett, D.J.L., Atkins, S., Brandon, N.P., Vesovic, V., Vasileiadis, N., Kucernak, A.R., Electrochemical and Solid State Letters, 6 (2003) A63.CrossRefGoogle Scholar
  5. Brett, D.J.L., Atkins, S., Brandon, N.P., Vesovic, V., Vasileiadis, N., Kucernak, A.R., Journal of Power Sources, 133 (2004) 205.CrossRefGoogle Scholar
  6. Buchi, F.N., Marek, A., Scherer, G.S., Journal of the Electrochemical Society, 142 (1995) 1895.CrossRefGoogle Scholar
  7. Carbon, Electrochemical and Physico-chemical properties, John Wiley & Sons, 1992.Google Scholar
  8. Chan, B.C., Liu, R., Jambunathan, K., Zhang, H., Chen, G., Mallouk, T.E., Smotkin, E.S, Journal of the Electrochemical Society, 152 (2005) A594.CrossRefGoogle Scholar
  9. Ciureanu, M., Roberge, R., Journal of Physical Chemistry B, 105 (2001) 3531.CrossRefGoogle Scholar
  10. Damjanovic, A., Genshaw, M.A., and Bockris, J.O’M., Journal of Chemical Physics, 45, 1966, 4057.CrossRefGoogle Scholar
  11. Du, B., Plug Power Internal Communication, 2004.Google Scholar
  12. Dutta, S., Shimpalee S., Vanzee J.W., Journal of Applied Electrochemistry, 30 (2000) 135.CrossRefGoogle Scholar
  13. Eldrid, S., Shahnam, M., Prinkey, M.T., Dong, Z., First International Conference on Fuel Cell Science, Engineering and Technology, Rochester, NY, April 2003.Google Scholar
  14. Fuel Cells and Fuel Batteries—A Guide to the Research and Development, Liebhafsky & Cairns, John Wiley & Sons, New York, 1968.Google Scholar
  15. Gasteiger, H., Mathias, M., Yan, S., Catalyst Development Needs, Presented at the NSF Workshop, Washington DC, Nov. 2001.Google Scholar
  16. Gottesfeld, S., Pafford, J., Journal of the Electrochemical Society, 135, 2651, (1988).CrossRefGoogle Scholar
  17. Haug, A.T., White, R.E., Weidner, J.W., Huang, W., Journal of the Electrochemical Society, 149 (2002) A862.CrossRefGoogle Scholar
  18. Hicks, M., DoE Hydrogen Program Review, Washington DC, May 2005.Google Scholar
  19. Jambunathan, K., Hillier, A.C., Journal of the Electrochemical Society, 150 (2003) E312.CrossRefGoogle Scholar
  20. Karuppaiah, C., Plug Power Internal Communication, 2000.Google Scholar
  21. Lefebvre, M.C., Martin, R.B., Pickup, P.G., Electrochemical and Solid State Letters, 2 (1999) 259.CrossRefGoogle Scholar
  22. Liu, R., Smotkin, E.S., Journal of Electroanalytical Chemistry, 535 (2002) 49.CrossRefGoogle Scholar
  23. Makharia, R., Mathias, M.F., Baker, D.R., Journal of the Electrochemical Society, 152 (2005) A970.CrossRefGoogle Scholar
  24. Mitsushima, S., Araki, N., Kamiya, N., Ota, K., Journal of the Electrochemical Society, 149 (2002) A1370.CrossRefGoogle Scholar
  25. Mohtadi, R., Lee, W-K., Cowan, S., Van Zee, J.W., Murthy, M., Electrochemical and Solid State Letters, 6 (2003) A272.CrossRefGoogle Scholar
  26. Natarajan, D., Nguyen, T.V., Journal of Power Sources, 135 (2004) 95.CrossRefGoogle Scholar
  27. Norskov, J.K., Bligaard, T., Logadottir, A., Kitchin, J.R., Chen, J.G., Pandelov, S., Stimming, U., Journal of the Electrochemial Society, 152 (2005) J23.CrossRefGoogle Scholar
  28. Norskov, J.K., Rossmeisl, J., Logadottir, A., Lindqvist, L., Kitchin, J.R., Bligaard, T., Jonsson, H., Journal of Physical Chemistry B, 108 (2004) 17886.CrossRefGoogle Scholar
  29. O’Hyare, R., Prinz, F.B., Journal of the Electrochemical Society, 151 (2004) A756.CrossRefGoogle Scholar
  30. Paulus, U.A., Schmidt, T.J., Gasteiger, H.A., Behm, R.J., Journal of Electroanalytical Chemistry, 495 (2001) 134.CrossRefGoogle Scholar
  31. Springer, T.E., Raistrick, I.D., Journal of the Electrochemical Society, 136 (1989) 1594.CrossRefGoogle Scholar
  32. Springer, T.E., Zawodzinski, T.A., Wilson, M.S., Gottesfeld, S., Journal of the Electrochemical Society, 143 (1996) 587.CrossRefGoogle Scholar
  33. Ticianelli, E.A., Beery, J.G., Srinivasan, S., Journal of Applied Electrochemistry, 21 (1991) 597.CrossRefGoogle Scholar
  34. Uribe, F.A., Springer, T.E., Gottesfeld, S., Journal of the Electrochemical Society, 139 (1992) 765.CrossRefGoogle Scholar
  35. Uribe, F.A., Zawodzinski, T.A., Electrochimica Acta, 47 (2002) 3799.CrossRefGoogle Scholar
  36. Wagner, N., Schulze, M., Electrochimica Acta, 48 (2003) 3899.CrossRefGoogle Scholar
  37. Wilson, M.S., Gottesfeld, S., Journal of Electrochemical Society, 139 (1992) L28.CrossRefGoogle Scholar
  38. Zhang, J., Dutta, R., Journal of the Electrochemical Society, 149 (2002) A1423.CrossRefGoogle Scholar

Copyright information

© Anamaya Publishers, New Delhi, India 2007

Authors and Affiliations

  • Manikandan Ramani
    • 1
  1. 1.Plug PowerLathamUSA

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