Principles and Applications of Solid Polymer Electrolyte Reactors for Electrochemical Hydrodehalogenation of Organic Pollutants
The ability to re-cycle halogenated liquid wastes, based on electrochemical hydrodehalogenation (EHDH), will provide a significant economic advantage and will reduce the environmental burden in a number of processes. The use of a solid polymer electrolyte (SPE) reactor is very attractive for this purpose. Principles and features of electrochemical HDH technology and SPE EHDH reactors are described. The SPE reactor enables selective dehalogenation of halogenated organic compounds in both aqueous and non-aqueous media with high current efficiency and low energy consumption. The influence of operating conditions, including cathode material, current density, reactant concentration and temperature on the HDH process and its stability are examined.
KeywordsCurrent Efficiency Catalyst Layer Solid Polymer Electrolyte Moderate Current Density High Current Efficiency
The authors thank the United Kingdom Engineering and Physical Sciences Research Council (EPSRC) for funding. The work was performed in research facilities provided through an EPSRC/HEFCE Joint Infrastructure Fund award (No. JIF4NESCEQ).
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