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Modeling of Catalyst Structure Degradation in PEM Fuel Cells

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Modeling and Numerical Simulations

Part of the book series: Modern Aspects of Electrochemistry ((MAOE,volume 43))

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Abstract

In this chapter, the requirements of a high-performance catalyst layer are examined in order to understand the ways in which the structure might degrade with operation. The formation of oxide species on the surface of the platinum is examined to understand its role in both oxygen reduction and in setting the equilibrium state of the surface as a function of both pH and potential. Models of dissolution of platinum and subsequent migration through the cell are reviewed, along with an analysis of experimental studies aimed at determining the evolution of particle-size distributions with operation of a fuel cell. The mechanism of corrosion of the carbon supports is also examined, specifically under off-design points such as cell reveral and localized fuel starvation. Implications for material development and future modeling needs are reviewed.

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References

  1. Teliska, A.; O'Grady, W. E.; Ramaker, D. E. Journal of Physical Chemistry B 2005, 109, 8076–8084.

    Article  CAS  Google Scholar 

  2. Paik, C. H.; Jarvi, T. D.; O'Grady, W. E. Electrochemical and Solid State Letters 2004, 7, A82–A84.

    Article  CAS  Google Scholar 

  3. Uribe, F. A.; Zawodzinski, T. A. Electrochimica Acta 2002, 47, 3799–3806.

    Article  CAS  Google Scholar 

  4. Paik, C. H.; Saloka, G. S.; Graham, G. W. Electrochemical and Solid State Letters 2007, 10, B39–B42.

    Article  CAS  Google Scholar 

  5. Pourbaix, M. Atlas of electrochemical equilibria, 1966, Oxford, New York, Pergamon Press 1st edition.

    Google Scholar 

  6. Lee, J. B. Corrosion 1981, 37, 467–481.

    CAS  Google Scholar 

  7. Azaroul, M.; Romand, B.; Freyssinet, P.; Disnar, J. R. Geochimica et Cosmochimica Acta 2001, 65, 4453–4466.

    Article  Google Scholar 

  8. Bowles, F. W.; Gize, A. P.; Vaughan, D. J.; Norris, S. J. 1995. no 520: 65–73. Chronique de la Recherche Miniere 1995, 529, 65–73.

    Google Scholar 

  9. Bindra, P.; Clouser, S. J.; Yeager, E. Journal of the Electrochemical Society 1979, 126, 1631–1632.

    Article  CAS  Google Scholar 

  10. Ferreira, P. J.; la O', G. J.; Shao-Horn, Y.; Morgan, D.; Makharia, R.; Kocha, S.; Gasteiger, H. A. Journal of the Electrochemical Society 2005, 152, A2256–A2271.

    Article  Google Scholar 

  11. Wang, X. P.; Kumar, R.; Myers, D. J. Electrochemical and Solid State Letters 2006, 9, A225–A227.

    Article  CAS  Google Scholar 

  12. Mitsushima, S.; Koizumi, Y.; Ota, K.-I.; Kamiya, N. Electrochemistry Communications 2007, 75.

    Google Scholar 

  13. Mathias, M.; Gasteiger, H.; Makharia, R.; Kocha, S.; Fuller, T.; Pisco, J. Abstracts of Papers of the American Chemical Society 2004, 228, 002–FUEL.

    Google Scholar 

  14. Darling, R. M.; Meyers, J. P. Journal of the Electrochemical Society 2003, 150, A1523–A1527.

    Article  CAS  Google Scholar 

  15. Xie, J.; Wood, D. L.; More, K. L.; Atanassov, P.; Borup, R. L. Journal of the Electrochemical Society 2005, 152, A1011–A1020.

    Article  Google Scholar 

  16. Patterson, T. 2002 AIChE Spring National Meeting, 2002; pp. 313–318.

    Google Scholar 

  17. Darling, R. M.; Meyers, J. P. Journal of the Electrochemical Society 2005, 152, A242–A247.

    Article  CAS  Google Scholar 

  18. Komanicky, V.; Chang, K. C.; Menzel, A.; Markovic, N. M.; You, H.; Wang, X.; Myers, D. Journal of the Electrochemical Society 2006, 153, B446–B451.

    Article  CAS  Google Scholar 

  19. Benke, G.; Gnot, W. Hydrometallurgy 2002, 64, 205–218.

    Article  CAS  Google Scholar 

  20. Johnson, D. C.; Napp, D.T; Bruckenstein, S. Electrochimica Acta 1970, 15, 1493–1509.

    Article  CAS  Google Scholar 

  21. Kinoshita, K.; Lundquist, J.T; Stonehart, P. Journal of Electroanalytical Chemistry 1973, 48, 157–166.

    Article  CAS  Google Scholar 

  22. Mitsushima, S.; Kawahara, S.; Ota, K. I.; Kamiya, N. Journal of the Electrochemical Society 2007, 154, B153–B158.

    Article  CAS  Google Scholar 

  23. Rand, D. A. J. a. R. W. Journal of Electroanalytical Chemistry 1972, 35, 209–218.

    Article  CAS  Google Scholar 

  24. Arvia, A. J.; Canullo, J. C.; Custidiano, E.; Perdriel, C. L.; Triaca, W. E. Electrochimica Acta 1986, 31, 1359–1368.

    Article  CAS  Google Scholar 

  25. Canullo, J. C.; Triaca, W. E.; Arvia, A. J. Journal of Electroanalytical Chemistry 1986, 200, 397–400.

    Article  CAS  Google Scholar 

  26. Egli, W. A.; Visintin, A.; Triaca, W. E.; Arvia, A. J. Applied Surface Science 1993, 68, 583–593.

    Article  CAS  Google Scholar 

  27. Ota, K. I.; Nishigori, S.; Kamiya, N. Journal of Electroanalytical Chemistry 1988, 257, 205–215.

    Article  CAS  Google Scholar 

  28. Schulze, M.; Schneider, A.; Gulzow, E. Journal of Power Sources 2004, 127, 213–221.

    Article  CAS  Google Scholar 

  29. Yasuda, K.; Taniguchi, A.; Akita, T.; Ioroi, T.; Siroma, Z. Physical Chemistry Chemical Physics 2006, 8, 746–752.

    Article  CAS  Google Scholar 

  30. Guilminot, E.; Corcella, A.; Charlot, F.; Maillard, F.; Chatenet, M. Journal of the Electrochemical Society 2007, 154, B96–B105.

    Article  CAS  Google Scholar 

  31. Akita, T.; Taniguchi, A.; Maekawa, J.; Sirorna, Z.; Tanaka, K.; Kohyama, M.; Yasuda, K. Journal of Power Sources 2006, 159, 461–467.

    Article  CAS  Google Scholar 

  32. Yasuda, K.; Taniguchi, A.; Akita, T.; Ioroi, T.; Siroma, Z. Journal of the Electrochemical Society 2006, 153, A1599–A1603.

    Article  CAS  Google Scholar 

  33. More, K. L.; Reeves, K.S. DOE Hydrogen Program Review 2005, www.hydrogen.energy.gov/pdfs/review05/fc39_more.pdf.

  34. Borup, R.; Davey, J.; Garzon, F.H. ECS Transactions 2006, 3, 879.

    Article  Google Scholar 

  35. More, K. L.; Borup, R; Reeves, K.S. ECS Transations 2006, 3.

    Google Scholar 

  36. Ascarelli, P., V. Contini, R. Giorgi Journal of Applied Physics 2002, 91, 4556.

    Article  Google Scholar 

  37. Landsman, D. A.; Luczak, F. J. In Handbook of Fuel Cells-Fundamentals, Technology, and Applications; Vielstich, W., Gasteiger, H. A., Lamm, A., Eds.; Wiley: West Sussex, England, 2003; Vol. 4.

    Google Scholar 

  38. Yu, P. T.; Gu, W.; Makharia, R.; Wagner, F.T.; Gasteiger, H.A. ECS Transactions 2007, 3, 797.

    Article  Google Scholar 

  39. Mathias, M. F.; Makharia, R.; Gasteiger, H. A.; Conley, J. J.; Fuller, T. J.; Gittleman, C. J.; Kocha, S. S.; Miller, D. P.; Mittelsteadt, C. K.; Xie, T.; Yan, S. G.; Yu, P. T. Interface 2005, 14, 24.

    Google Scholar 

  40. Roen, L. M.; Paik, C. H.; Jarvi, T. D. Electrochemical and Solid-State Letters 2004, 7, A19–A22.

    Article  CAS  Google Scholar 

  41. Willsau, J.; Heitbaum, J. Journal of Electroanalytical Chemistry 1984, 161, 93–101.

    Article  CAS  Google Scholar 

  42. Kangasniemi, K. H.; Condit, D. A.; Jarvi, T. D. Journal of the Electrochemical Society 2004, 151, E125–E132.

    Article  CAS  Google Scholar 

  43. Siroma, Z.; Ishii, K.; Yasuda, K.; Miyazaki, Y.; Inaba, M.; Tasaka, A. Electrochemistry Communications 2005, 7, 1153–1156.

    Article  CAS  Google Scholar 

  44. Kinumoto, T.; Takai, K.; Iriyama, Y.; Abe, T.; Inaba, M.; Ogumi, Z. Journal of the Electrochemical Society 2006, 153, A58–A63.

    Article  CAS  Google Scholar 

  45. Chaparro, A. M.; Mueller, N.; Atienza, C.; Daza, L. Journal of Electroanalytical Chemistry 2006, 591, 69–73.

    Article  CAS  Google Scholar 

  46. Wang, X.; Li, W.; Chen, Z.; Waje, M.; Yan, Y. Journal of Power Sources 2006, 158, 154–159.

    Article  CAS  Google Scholar 

  47. Barton, H. R.; Ballard Power Systems Inc.: United States of America, 2004, US patent #6,724,194. “Cell VoltageMonitor for a Fuel Cell Stack” issued April 20, 2004.

    Google Scholar 

  48. Reiser, C. A.; Bregoli, L.; Patterson, T. W.; Yi, J. S.; Yang, J. D.; Perry, M. L.; Jarvi, T. D. Electrochemical and Solid-State Letters 2005, 8, A273–A276.

    Article  CAS  Google Scholar 

  49. Makharia, R.; Kocha, S.S.; Yu, P.T.; Sweikart, M.A.; Gu, W.; Wagner, F.T.; Gasteiger, H.A. ECS Transactions 2006, 1, 3.

    Article  Google Scholar 

  50. Patterson, T. W.; Darling, R. M. Electrochemical and Solid-State Letters 2006, 9, A183–A185.

    Article  CAS  Google Scholar 

  51. Pekula, N.; Heller, K.; Chuang, P. A.; Turhan, A.; Mench, M. M.; Brenizer, J. S.; Unlu, K. Nuclear Instruments & Methods in Physics Research Section a-Accelerators Spectrometers Detectors and Associated Equipment 2005, 542, 134–141.

    Article  CAS  Google Scholar 

  52. Meyers, J. P.; Darling, R. M. Journal of the Electrochemical Society 2006, 153, A1432–A1442.

    Article  CAS  Google Scholar 

  53. Perry, M. L.; Patterson, T. W.; Reiser, C. ECS Transactions 2006, 3, 783–795.

    Article  CAS  Google Scholar 

  54. Yan, X. Q.; Hou, M.; Sun, L. Y.; Cheng, H. B.; Hong, Y. L.; Liang, D.; Shen, Q.; Ming, P. W.; Yi, B. L. Journal of Power Sources 2007, 163, 966–970.

    Article  CAS  Google Scholar 

  55. Kusoglu, A.; Karlsson, A. M.; Santare, M. H.; Cleghorn, S.; Johnson, W. B. Journal of Power Sources 2006, 161, 987–996.

    Article  CAS  Google Scholar 

  56. Huang, X. Y.; Solasi, R.; Zou, Y.; Feshler, M.; Reifsnider, K.; Condit, D.; Burlatsky, S.; Madden, T. Journal of Polymer Science Part B-Polymer Physics 2006, 44, 2346–2357.

    Article  CAS  Google Scholar 

  57. Borup, R. L.; Davey, J. R.; Garzon, F. H.; Wood, D. L.; Inbody, M. A. Journal of Power Sources 2006, 163, 76–81.

    Article  CAS  Google Scholar 

  58. Knights, S. D.; Colbow, K. M.; St-Pierre, J.; Wilkinson, D. P. Journal of Power Sources 2004, 127, 127–134.

    Article  CAS  Google Scholar 

  59. Gasteiger, H. A.; Kocha, S. S.; Sompalli, B.; Wagner, F. T. Applied Catalysis B: Environmental 2005, 56, 9–35.

    Article  CAS  Google Scholar 

  60. Jalan, V.; Taylor, E. J. Journal of the Electrochemical Society 1983, 130, 2299–2302.

    Article  CAS  Google Scholar 

  61. Mukerjee, S.; Srinivasan, S.; Soriaga, M. P.; McBreen, J. Journal of the Electrochemical Society 1995, 142, 1409–1422.

    Article  CAS  Google Scholar 

  62. Stamenkovic, V.; Schmidt, T. J.; Ross, P. N.; Markovic, N. M. Journal of Physical Chemistry B 2002, 106, 11970–11979.

    Article  CAS  Google Scholar 

  63. Norskov, J. K.; Rossmeisl, J.; Logadottir, A.; Lindqvist, L.; Kitchin, J. R.; Bligaard, T.; Jonsson, H. Journal of Physical Chemistry B 2004, 108, 17886–17892.

    Article  CAS  Google Scholar 

  64. Anderson, A. B. Electrochimica Acta 2002, 47, 3759–3763.

    Article  CAS  Google Scholar 

  65. Roques, J.; Anderson, A. B.; Murthi, V. S.; Mukerjee, S. Journal of the Electrochemical Society 2005, 152, E193–E199.

    Article  CAS  Google Scholar 

  66. Piela, P.; Eickes, C.; Brosha, E.; Garzon, F.; Zelenay, P. Journal of the Electrochemical Society 2004, 151, A2053–A2059.

    Article  CAS  Google Scholar 

  67. Antolini, E.; Salgado, J. R. C.; Gonzalez, E. R. Journal of Power Sources 2006, 160, 957–968.

    Article  CAS  Google Scholar 

  68. Mathias, M. F.; Makharia, R.; Gasteiger, H. A.; Conway, J. J.; Fuller, T. J.; Gittleman, C. J.; Kocha, S. S.; Miller, D. P.; Mitelsteadt, C. K.; Xie, T.; Yan, S. G.; Yu, P. T. Interface 2005, 14, 24–35.

    CAS  Google Scholar 

  69. Mukundan, R.; Kim, Y. S.; Garzon, F.; Pivovar, B. ECS Transactions 2005, 1, 403–413.

    Article  Google Scholar 

  70. Colon-Mercado, H. R.; Popov, B. N. Journal of Power Sources 2006, 155, 253–263.

    CAS  Google Scholar 

  71. Ball, S.; Hudson, S.; Theobald, B.; Thompsett, D. ECS Transactions 2006, 1.

    Google Scholar 

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  1. Department of Mechanical Engineering, The University of Texas at Austin, Austin, TX, USA

    Jeremy P. Meyers

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Meyers, J.P. (2008). Modeling of Catalyst Structure Degradation in PEM Fuel Cells. In: Modeling and Numerical Simulations. Modern Aspects of Electrochemistry, vol 43. Springer, New York, NY. https://doi.org/10.1007/978-0-387-49582-8_6

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