Abstract
It is not a coincidence that very often the materials and sensitization methodologies used in chemical sensing are basically the same as the ones practiced in the field of catalysis. In both fields, a chemical reaction on the surface of the sensor or catalyst is the origin of the desired reaction products (in catalysis) or the electrical signals (in sensing). These fields were widely explored during the past few decades but both are currently experiencing a renaissance thanks to exciting new opportunities offered by nanotechnology.1
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References
J.H. Sinfell. Catalysis: An old but continuing theme in chemistry, in: Proc. Am. Philos. Soc. 143, 388–399 (1999).
G.A. Somorjai and R.M. Rioux, High technology catalysts towards 100% selectivity: Fabrication, characterization and reaction studies, Catal, Today 100, 201–215 (2005).
U. Heiz and Li. Landman, Nanocatalysis, (Springer, Heidelberg, 2006).
M. Valden, X. Lai and D.W. Goodman. Onset of catalytic activity of gold clusters on titania with the appearance of nonmetallic properties, Science 281. 1647–1650 (1998).
A. Naitabdi, L.K. Ono, and B. Roldan Cuenya, Local investigation of the electronic properties of size-selected Au nanoparticles by scanning tunneling spectroscopy. Appl. Phys. Lett. 89. 043101 (2006).
D. Dalacu and L. Martinu, Optical properties of discontinuous gold films: Finite-size effects, J. Opt. Soc. Am. B 18, 85–92 (2001).
M. Haruta, Size-and support-dependency in the catalysis of gold, Catal. Today 36, 153–166 (1997).
H. Hakkinen, W. Abbet, A. Sanchez, U. Heiz and U. Landman, Structural, electronic, and impurity-doping effects in nanoscale chemistry: supported gold nanoclusters. Angew. Chem. Int. Ed. 42, 1297–1300 (2003).
J.D. Aiken and R.G. Finke, A review of modern transition-metal nanoclusters: Their synthesis, characterization, and applications in catalysis, J. Mol. Catal. A 145, 1–14 (1999).
C.T. Campbell, Ultrathin metal films and particles on oxide surfaces-Structural, electronic and chemisorptive properties, Surf. Sei. Rep. 27, 1–44 (1997).
U. Heiz, S. Abbet. A. Sanchez. W.D. Schneider, H. Hakkinen and U. Landman, Chemical reactions on size-selected clusters on surfaces, in: Proc. Nobel Symposium 117 (E. Campbell, M. Larsson. eds.) (World Scientific, Singapore, 2001).
A. Kolmakov and D.W. Goodman, Size effect in catalysis by supported metal clusters, in: Quantum Phenomena in Clusters and Nanostructures, (A.W. Castleman Jr. and S.N. Khanna. eds.) (Springer, New York, 2003).
M. Harula. Catalysis of gold nanoparticles deposited on metal oxides. CATTECH 6. 102–115 (2002).
N. Lopez, T.V.W. Janssens, B.S. Clausen, et al., On the origin of the catalytic activity of gold nanoparticles for low-temperature CO oxidation, J. Catal. 223. 232 (2004).
M. Mavrikakis, P. Stoltze and J. Norskov. Making gold less noble, Catal. Lett. 64, 101–106 (2000).
R. Meyer, C. Lemire, S.K. Shaikhutdinov and HJ. Freund, Surface chemistry of catalysis by gold. Gold Bulletin 37. 72 (2004).
S.K. Shaikhutdinov. R. Meyer, M. Naschitzki, M. Baumer and H.J. Freund, Size and support effects for CO adsoiption on gold model catalysts, Catal. Lett. 86, 211 (2003).
L.K. Ono. D. Sudfeid, B. Roldan Cuenya. In-situ gas-phase catalytic properties of TiC-supported size-selected gold nanoparticles synthesized by diblock copolymer encapsulation. Surf. Sei. 600, 5041–5050 (2006).
J.D. Aiken, Y. Lin and R.G. Finke. A perspective on nanocluster catalysis: Polyoxoanion and n-C4H9N+ stabilized Ir(O) nanoclusters “soluble heterogeneous catalysts”. J. Mol. Catal. A 114, 29–51 (1996).
O. Alexeev and B.C. Gates. Iridium clusters supported on γ-Al2O3: Structural characterization and catalysis of toluene hydrogenation, J. Catal. 176, 310–320 (1998).
A.M. Argo and B.C. Gates, Support effects in alkene and hydrogenation catalyzed by welldefined supported rhodium and iridium clusters, Absl. Papers Am. Chem. Soc. 221. U476–U476 (2001).
A.M. Argo, J.F. Odzak and B.C. Gates. Role of cluster size in catalysis: Spectroscopic investigation of γ-Al2O3-supporled Ir4 and Ir6 during ethene hydrogenation, J. Am. Chem. Soc. 125. 7107–7115 (2003).
A.T. Ashcroft. A.K. Cheetham, P.J.F. Hams, et al., Particle-size studies of supported metalcatalysts—a comparative-study by X-ray-diffraction. EXAFS and electron-microscopy, Catal. Lett. 24, 47–57 (1994).
A. Berko and F. Solymosi. Effects of different gases on the morphology of Ir nanoparticles supported on the TiO2(110)-(1 × 2) surface, J. Phys. Chem. B 104, 10215–10221 (2000).
D.S. Cunha and G.M. Cruz, Hydrogenation of benzene and toluene over Ir particles supported on γ-Al2O3, Appl. Catal. A 236, 55–66 (2002).
S.E. Deutsch, J.T. Miller, K. Tomishige, Y. Iwasawa, W.A. Weber and B.C. Gates. Supported Ir and Pt clusters: Reactivity with oxygen investigated by extended X-ray absorption fine structure spectroscopy. J. Phys. Chem. 100, 13408–13415 (1996).
S.E. Deutsch, F.S. Xiao and B.C. Gates. Near absence of support effects in toluene hydrogenation catalyzed by MgO-supported iridium clusters, J. Catal. 170, 161–167 (1997).
J.D. Grunwaldt, P. Kappen, L. Basini and B.S. Clausen. Iridium clusters for catalytic partial oxidation of methane—an in situ transmission and fluorescence XAFS study, Catal. Lett. 78, 13–21 (2002).
S. Kawi and B.C. Gales, MgO-supported [Ir-6(CO)(15)]2-:Catalyst for CO hydrogenation. J. Catal. 149, 317–325 (1994).
F.C.C. Moura, R.M. Lago, E.N. dos Santos and M.H. Araujo, Unique catalytic behavior of Ir-4 clusters for the selective hydrogénation of 1,5-cyciooctadiene, Catal. Comm. 3, 541–545 (2002).
L. Slievano, S. Calogero, R. Psaro and F.E. Wagner, Advances in the application of Mössbauer spectroscopy with less-common isotopes for the characterization of bimetallic supported nanoparticles: 193Ir Mössbauer spectroscopy. Comm. Inorg. Chem. 22. 275–292 (2001).
M.S. Ureta-Zanariu, C. Yanez, G. Reyes, J.R. Gancedo and J.F. Marco, Electrodeposited Pt-Ir electrodes: Characterization and electrocatalytic activity for the reduction of the nitrate ion, .J. Solid. State Electmchem. 2, 191–197 (1998).
Z. Xu, P.S. Xiao, S.K. Purneil, et at., Size-dependent catalytic activity of supported metal-clusters, Nature 372, 346–348 (1994).
A. Zhao and B.C. Gates, Toluene hydrogénation catalyzed by tetrairidium clusters supported on γ-Al2O3, J. Catal. 168, 60–69 (1997).
O.B. Yang. S.I. Woo and Y.G. Kim, Comparison of platinum iridium bimetallic catalysts supported on gamma-alumina and hy-zeolite in n-hexane reforming reaction. Appl. Catal. A 115, 229–241 (1994).
M. Frank and M. Baumer, From atoms to crystallites: Adsorption on oxide-supported metal particles, Phys. Chem. Chem. Phys. 2, 3723–3737 (2000).
L.M.P. Gruijthuijsen, G.J. Howsmon. W.N. Delgass. D.C. Koningsberger, R.A. van Santen and J.W. Niemantsverdriet, Structure and reactivity of bimetallic Felr/SiO2 catalysts after reduction and during high-pressure CO hydrogénation, J. Catal, 170, 331–345 (1997).
M.M. Bhasin, W.J. Bartley, P.C. Ellgen and T.P. Wilson, J. Catal. 54, 120 (1978).
T. Fukushima. Y. Ishii, Y. Onda, M. Ichikawa, Promoting role of Fe in enhancing activity and selectivity of MeOH production from CO and H2 catalyzed by SiO2-supported Ir, J. Chem. Soc. Chem. Comm. 24, 1752–1754 (1985).
J. R. Croy, S. Mosiafa, Jing Liu, Yong-ho Sohn, B. Roldan Cuenya. Size-dependent study of MeOH decomposition over size-selected Pi nanoparticles synthesized via micelle encapsulation, Catal Lett., DOI:I0.1007/S10562-007-9162-01 (in press 2007).
J. R. Croy. S. Mostafa, J. Liu, Yongho Sohn, H. Heinrich and B. Roldan Cuenya, Support dependence of MeOH decomposition over size-selected Pi nanoparticles. Catal. Lett, (accepted, 2007).
M. Valden and D.W. Goodman, Structure-activity correlations for Au nanoclusters supported on TiO2, Israel J. Chem. 38, 285–292 (1998).
M. Valden, S. Pak. X. Lai and D.W. Goodman, Structure sensitivity of CO oxidation over model Au/TiO2 catalysts, Catal. Lett. 56, 7–10 (1998).
A. Szabo, M.A. Henderson and J.T. Yates, Oxidation of CO by oxygen on a stepped platinum surface: Identification of the reaction site. J. Chem. Phys. 96, 6191–6202 (1992).
C. Duriez, H. C.R. and C. Chapon, Molecular beam study of the chemisorption of CO on wellshaped palladium particles epitaxially oriented on MgO(100), Surf. Sei. 253, 190 (1991).
M. Frank, S. Andersson, J. Libuda, el al., Panicle size dependent CO dissociation on aluminasupported Rh: A model study, Chem. Phys. Lett. 279, 92–99 (1997).
L.K. Ono and B. Roldan Cuenya, Effect of inierparticle interaction on the low temperature oxidation of CO over size-selected Au nanocatalysts supported on ullrathin TiC films, Catal. Lett. 113, 86–93 (2007).
E. Comini, A. Cristalli, G. Faglia and G. Sberveglieri, Light enhanced gas sensing properties of indium oxide and tin dioxide sensors. Sens. Actuators B 65, 260–263 (2000).
M. Law, H. Kind, B. Messer, F. Kim and P.D. Yang, Photochemical sensing of NO2 with SnO2 nanoribbon nanosensors at room temperature, Angew. Chem. Int. Ed. 41, 2405–2408 (2002).
Y. Cui, Q.Q. Wei, H.K. Park and C.M. Lieber, Nanowire nanosensors for highly sensitive and selective detection of biological and chemical species, Science 293, 1289–1292 (2001).
E. Comini, G. Faglia, G. Sberveglieri Z.W. Pan and Z.L. Wang, Stable and highly sensitive gas sensors based on semiconducting oxide nanobelts, Appl. Phys. Lett. 81, 1869–1871 (2002).
A. Kolmakov, Y Zhang, G. Cheng and M. Moskovits, Detection of CO and oxygen using tin oxide nanowire sensors. Adv. Mater. 15. 997–1000 (2003).
D.H. Zhang, Z.Q. Liu, C. Li, et al., Detection of NO2 down to ppb levels using individual and multiple In2O3 nanowire devices, Nana Letters 4, 1919–1924 (2004).
CM. Lieber. Nanoscale science and technology: Building a big future from small things. MRS Bulletin 28, 486–491 (2003).
Y.N. Xia, P.D. Yang, Y.G. Sun, et al., One-dimensional nanostructures: Synthesis, characterization, and applications,Adv. Mater. 15, 353–389 (2003).
Z.L. Wang, Functional oxide nanobelts: Materials, properties and potential applications in nanosystenis and biotechnology, Ann. Rev. Phys. Chem. 55, 159–196 (2004).
E. Rothenberg, M. Kazes, E. Shaviv and U. Banin, Electric field induced switching of the fluorescence of single semiconductor quantum rods, Nano tetters 5. 1581–1586 (2005).
H.J. Freund, J. Libuda, M. Baumer, T. Risse and A. Carlsson, Cluster, facets, and edges: Sitedependent selective chemistry on model catalysts. Chem. Record 3, 181–200 (2003).
L. Aballe, A. Barinov, A. Locatelli, S. Heun and M. Kiskinova, Tuning surface reactivity via electron quantum confinement, Phys. Rev. Lett. 93, 196103 (2004).
N. Yamazoe. New approaches for improving semiconductor gas sensors, Sens. Actuators B, 5. 7–19 (1991).
N.M. White and J.D. Turner. Thick-film sensors: Past, present and future, Meas. Sei. Techn. 8. 1–20 (1997).
W. Göpel. Solid-state chemical sensors—Atomistic models and research trends, Sens. Actuators 16, 167–193 (1989).
D. Kohl, Function and applications of gas sensors, J. Phys.D 34, RI25–RI49 (2001).
P.T. Moseley. New trends and future-Prospects of thick-film and thin-film gas sensors, Sens. Actuators B 3, 167–174 (1991).
A. Dieguez, A. Romano-Rodriguez, J.R. Morante, J. Kappler, N. Barsan and W. Gopel. Nanoparticle engineering for gas sensor optimization: Improved sol-gel fabricated nanocrystalline SnO2 thick film gas sensor for NO2 detection by calcination, catalytic metal introduction and grinding treatments, Sens. Actuators B 60, 125–137 (1999).
N. Barsan. Conduction models in gas-sensing SnO2 layers—Grain-size effects and ambient atmosphere influence. Sens. Actuators B 17, 241–246 (1994).
G. Sberveglieri. Recent developments in semiconducting thin-film gas sensors, Sens. Actuators B 23 103–109 (1995).
A. Cabot, A. Dieguez, A. Romano-Rodriguez, J.R. Morante and N. Barsan, Influence of the catalytic introduction procedure on the nano-SnO2 gas sensor performances—Where and how stay the catalytic atoms?, Sens. Actuators B 79, 98–106 (2001).
N. Barsan and U. Weimar. Understanding the fundamental principles of metal oxide based gas sensors; the example of CO sensing with Sn1O2 sensors in the presence of humidity. J. Phys. Condens. Matter. 15, R813–R839 (2003).
K. Thompson, J.H. Booske, D.J. Larson and T.F. Kelly, Three-dimensional atom mapping of dopants in Si nanostructures. Appl. Phys. ten. 87, 052108 (2005).
R. Skomski, Nanomagnetics, J. Phys. Condens. Matter. 15, 841–896 (2003).
S.D. Bader, Magnetism in low dimensionality, Suif. Sei. 500, 172–188 (2002).
S.D. Bader, Colloquium: Opportunities in nanomagnetism. Rev. Mod. Phys. 78. 1–15 (2006).
M.N. Baibich, J.M. Broto, A. Pert, et al., Giant magnetoresistance of Fe(001)/Cr(001), Phys. Rev. Lett. 61, 2472–2475 (1988).
S.A. Wolf, D.D. Awschalom, R.A. Buhrman, et al., Spintronic: A spin-based electronics vision of the future, Science 294, 1488–1495 (2001).
D.A. Thonson and J.S. Best, The future of magnetic data storage technology. IBM J. Res. Develop. 44, 311 (2000).
B. Roldan Cuenya, A. Naitabdi. E. Schuster, R. Peters, M. Doi, and W. Keune. Epitaxial growth. magnetic properties and lattice dynamics of Fe nanoclusters on GaAs(00l). (accepted in Phys. Rev. B 2007).
L. Fu, V.P. Dravid, K. Klug, X. Liu and CA. Mirkin, Synthesis and patterning of magnetic nanostructures, Europ. Cells and Mater. 3, 156 (2002).
T.F. Jaramillo, S.H. Baeck, B. Roldan Cuenya and E.W. McFarland, Catalytic activity of supported Au nanoparticles deposited from block copolymer micelles, J. Am. Chem. Soc, 125, 7148–7149 (2003).
B. Roldan Cuenya, S.U. Baeck, T.F. Jaramillo and E.W. McFarland. Size and support dependent electronic and catalytic properties of Auo/Au3+ nanoparticles synthesized from block co-polymer micelles, J. Am. Chem. Soc. 125, 12928–12934 (2003).
N. Cordente, C. Amiens, B. Chaudret, M. Respaud, F. Senocq and M.-J. Casanove, Chemisorption on nickel nanoparticles of various shapes: Influence on magnetism, J. Appl. Phys. 94, 6358–6365 (2003).
H.G. Boyen, G. Kästle, K. Zum, et al., A miceliar route to ordered arrays of magnetic nanoparticles: From size-selected pure cobalt dots to cobalt-cobalt oxide core-shell systems. Adv. Fund. Mater. 13, 359–364 (2003).
M. Giersig and M. Hilgendorff, The preparation of ordered colloidal magnetic particles by magnetophoretic deposition, J. Phys. D 32, L111–L113 (1999).
J.C. Hulteen and R.R. Van Duyne, Nanosphere lithography: A materials general fabrication process for periodic particle array surfaces, J. Vac. Sci. Technol. A 13, 1553–1558 (1995).
A. Naitabdi and B. Roldan Cuenya. Formation, thermal stability and surface composition of size-selected AuFe nanoparticles. Appl. Phys. Lett., (accepted, 2007).
J. Chen, M. Drakaki and J.L. Erskine, Chemisorption-induced change in thin-film spin anisotropy: Oxygen adsorption on the p( 1 × 1 )Fe/Ag( 100) system. Phys. Rev. B 45, 3636–3643 (1992).
M.B. Knickelbein, Nickel cluster: The influence of adsorbates on magnetic moments, J. Chem. Phys. 116, 9703–9311 (2002).
P.W. Seiwood (Ed.), Chemisorption and magnetization (Academic Press, New York, 1975).
M. Primet, J.A. Dalmon and G.A. Martin, Adsorption of CO on well-defined Ni/SiO2 catalysts in the 195–373 K range studied by infrared spectroscopy and magnetic methods, J. Catal. 46, 25–36 (1977).
Q. Ge, S.J. Jenkins and D.A. King. Localization of adsorbale-induced demagnetization: CO chemisorbed on Ni(100), Chem. Phys. Lett. 327, 125–130 (2000).
T. Hill, M. Mozaffari-Afshar, J. Schmidt, et al., Influence of CO adsorption on the magnetism of small CO nanoparticles deposited on Al2O3, Chem. Phys. Lett. 292, 524–530 (1988).
S. Pick and H. Dreysse, Tight-binding study of ammonia and hydrogen adsorption on magnetic cobalt systems, Surf. Sci. 460, 153–161 (2000).
M. Boudait, J.A. Dumesic and H. Topsoe, Surface, catalytic, and magnetic properties of small 94.iron particles: The effect of chemisorption of hydrogen on magnetic anisotropy, in: Proc. Natl. Acad. Sci. USA 74, 806–810 (1977).
I. Lundström, S. Shivaraman, C. Svensson and L. Lundkvist, A hydrogen-sensitive MOS field-effect transistor, Appl. Phys. Lett. 26, 55 (1975).
K.l. Lurtdstrom, M.S. Shivaraman and C.M. Svensson, Hydrogen-sensitive Pd-gate MOS-transistor, J. Appl. Phys. 46, 3876–3881 (1975).
M.C. Steele, J.W. Hile and B.A. Maciver, Hydrogen-sensitive palladium gate MOS capacitors, Appl. Phys. 47, 2537–2538 (1976).
R. Morrison, Semiconductor gas sensors. Sens. Actuators 2, 329–341 (1982).
D. Filippini, M. Rosch, R. Aragon and U. Weimar, Field-effect NO: sensors with group 1B metal gates, Sens. Actuators B 81, 83–87 (2001).
S.J. Fonash, H. Huston and S. Ashok, Conducting MIS diode gas detectors—The Pd/SiOx/Si hydrogen sensor. Sens. Actuators 2, 363–369 (1982).
H. Geistlinger, I. Eisele, B. Flietner and R. Winter, Dipole-and charge transfer contributions to the work function change of semiconducting thin films: Experiment and theory. Sens. Actuators B 34, 499–505 (1996).
I. Lundström and L.G. Petersson. Chemical sensors with catalytic metal gates. J. Vac. Sci. Technol. A 14, 1539–1545 (1996).
I. Lundström, Why bother about gas-sensitive field-effect devices?, Sens. Actuators A 56, 75–82 (1996) and references therein.
M. Eriksson and L.G. Ekedahl, Hydrogen adsorption slates al the Pd/SiO2 interface and simulation of the response of a Pd metal-oxide-semiconductor hydrogen sensor, J Appl. Phys. 83, 3947–3951 (1998).
M. Johansson, I. Lundström and L.G. Ekedahl. Bridging the pressure gap for palladium metal-insulator-semiconductor hydrogen sensors in oxygen containing environments, J. Appl. Phys. 84, 44–51 (1998).
D. Filippini, R. Aragon and U. Weimar, NO2 sensitive Au gate metai-oxide-semiconduclor capacitors, J. Appl. Phys. 90, 1883–1886 (2001).
D. Filippini, L. Fraigi, R. Aragon and U. Weimar, Thick film Au-gate field-effect devices sensitive to NO2, Sens. Actuators B 81, 296–300 (2002).
D. Filippini and I. Lundström, Chemical images generated by large area homogeneous illumination of metal-insulator-semiconductor structures, Appl. Phys. Lett. 82, 3791–3793 (2003).
W.-C. Liu, H.J. Pan, H.-l. Chen, K.-W. Lin and C.K. Wang, Comparative hydrogen-sensing study of Pd/GaAs and Pd/lnP metal-oxide-semiconductor Schottky diodes, Japn. J. Appl. Phys. 40, 6254–6259 (2001).
A. Spetz, M. Armgarth and I. Lundström. Hydrogen and ammonia response of metal-silicon dioxide-silicon structures with thin platinum gates, J. Appl. Phys. 64, 1274–1283 (1988).
H. Nienhaus, S.J. Weyers, B. Gergen and E.W. McFarland, Thin Au/Ge Schottky diodes for detection of chemical reaction induced electron excitation, Sens. Actuators B 87, 421–424 (2002).
H. Nienhaus, Electronic excitations by chemical reactions on metal surfaces, Surf. Sci. Rep. 45, 3–78 (2002).
H. Nienhaus, U.S. Bergh, B. Gergen, A. Majumdar, W.U. Weinberg and E.W. McFarland, Direct detection of electron-hole pairs generated by chemical reactions on metal surfaces. Surf. Sci. 445, 335–342 (2000).
H. Nienhaus, H.S. Bergh, B. Gergen, A. Majumdar, W.H. Weinberg and E.W. McFarland, Electron-hole pair creation at Ag and Cu surfaces by adsorption of atomic hydrogen and deuterium, Phys. Rev. Lett. 82, 446–449 (1999).
H. Nienhaus, H.S. Bergh, B. Gergen, A. Majumdar, W.H. Weinberg and E.W. McFarland, Selective H atom sensors using ultrathin Ag/Si Schottky diodes, Appl. Phys. Lett. 74, 4046–4048 (1999).
H. Nienhaus, H.S. Bergh, B. Gergen, A. Majumdar, W.H. Weinberg and E.W. McFarland, Ultrathin Cu films on Si(111): Schottky barrier formation and sensor applications, J. Vac. Sci. Technol. A 17, 1683–1687 (1999).
B. Gergen, H. Nienhaus, W.H. Weinberg and E.W. McFarland. Chemically induced electronic excitations at metal surfaces, Science 294, 2521–2523 (2001).
B. Gergen, S.J. Weyers, H. Nienhaus, W.H. Weinberg and E.W. McFarland. Observation of excited electrons from nonadiabatic molecular reactions of NO and O2 on polycrystalline Ag. Surf. Sci. 488, 123–132 (2001).
U.S. Bergh, B. Gergen, H. Nienhaus, A. Majumdar, W.H. Weinberg and E.W. McFarland, An ultrahigh vacuum system for the fabrication and characterization of ultrathin metal-semiconductor films and sensors. Rev. Sci. Instr. 70, 2087–2094 ( 1999).
H. Nienhaus, B. Gergen, W.H. Weinberg and E.W. McFarland, Detection of chemically induced hot charge carriers with ultrathin metal film Schottky contacts. Surf. Sci. 514, 172–181 (2002).
B. Gergen, H. Nienhaus, W.H. Weinberg and E.M. McFarland. Morphological investigation of ultrathin Ag and Ti films grown on hydrogen terminated Si(111), J. Vac. Sei. Technol. B 18, 2401–2405 (2000).
B. Gergen. Observations of electronic excitations in gas-metal interactions, PhD thesis. (University of California Santa Barbara. 2001)
B. Roidan Cuenya and E.W. McFarland, Sensors based on chemicurrents. in: Dekker Encyclopedia Nanosci. Nanotechnol., edited by James A. Schwarz, Cristian I. Contescu, Karol Putyera, p. 3527 (Marcel Dekker, New York, 2004).
B. Roldan Cuenya, H. Nienhaus and E.W. McFarland. Chemically induced charge carrier production and transport in Pd/SiO2/n-Si(111) MOS Schottky diodes, Phys. Rev. B 70, 115322 (2004).
X. Liu, B. Roldan Cuenya and E.W. McFarland, A MIS device structure for detection of chemically induced charge carriers, Sens. Actuators B 99, 556–561 (2004).
C.R. Crowell, L.E. Howarth, W.G. Spitzer and E.E. Labate, Attenuation length measurements of hot electrons in metal films, Phys. Rev. 127, 2006–2015 (1962).
J. Y. Park and G.A. Somorjai. The catalytic nanodiode: Detecting continuous electron flow at oxide-metal interfaces generated by a gas-phase exothermic reaction, Chem. Phys. Chem. 7, 1409–1413 (2006).
J. Y. Park and G.A. Somorjai, Energy conversion from catalytic reaction to hot electron current with metal-semiconductor Schottky nanodiodes, J. Vac. Sei. Technol. B 24, 1967–1971 (2006).
M.S. Arnold, P. Avouris, Z.W. Pan and Z.L. Wang, Field-effect transistors based on single semi-conducting oxide nanobelts, J. Phys. Chem. B 107, 659–663 (2003).
C. Li, D.H. Zhang, X.L. Liu. et al., In2O3 nanowires as chemical sensors, Appl. Phys. Lett. 82, 1613–1615 (2003).
Y.L. Wang, X.C. Jiang and Y.N. Xia, A solution-phase, precursor route to polycrystalline SnO2 nanowires that can be used for gas sensing under ambient conditions, J. Am. Chem. Soc. 125, 16176–16177 (2003).
Z.Y. Fan, D.W. Wang, P.C. Chang, W.Y Tseng and J.G. Lu, ZnO nanowire field-effect transistor and oxygen sensing property, Appl. Phys. Lett. 85, 5923–5925 (2004).
B.J. Murray, J.T. Newberg, E.C. Walter, Q. Li, J.C. Hemminger and R.M. Penner, Reversible resistance modulation in mesoscopic silver wires induced by exposure to amine vapor. Anal. Chem. 77, 5205–5214 (2005).
D.J. Zhang, C. Li, X.L. Liu, S. Han, T. Tang and C.W. Zhou, Doping dependent NH3 sensing of indium oxide nanowires, Appl. Phys. Lett. 83, 1845–1847 (2003).
S. Semancik, R.E. Cavicchi, M.C. Wheeler, et al., Microhotplate platforms for chemical sensor research, Sens. Actuators B 77, 579–591 (2001).
T. Rantala, V. Lantto and T. Rantala, Computational approaches to the chemical sensitivity of semiconducting tin dioxide, Sens. Actuators B 47, 59–64 (1998).
V.E. Henrich and P.A. Cox, Surface science of metal oxides (Cambridge University Press, New York, 1996).
U. Diebold, The surface science of titanium dioxide, Surf. Sci. Rep. 48, 53–229 (2003).
M. Batzill and U. Diebold. The surface and materials science of tin oxide. Progr. Surf. Sci. 79, 47–154 (2005).
V. Lantto, T.T. Rantala and T.S. Rantala. Atomistic understanding of semiconductor gas sensors, J. Europ. Ceram. Soc. 21, 1961–1965 (2001).
W. Göpel, J. Hesse and J. N. Zemel, Sensors: A comprehensive survey (VCH, Weinheim, 1995).
P.T. Moseley and B.C. Tofield., Solid-state gas sensors, (Adam Hilger, Bristol and Philadelphia, 1987).
G. Sberveglieri, Gas sensors: Principles, operation and developments, (Kluwer Academic, Boston, 1992).
T. Wolkenstein, Electronic processes on semiconductor surfaces during chemisorption (Springer, New York, 1991).
O.V. Krylov and V.F. Kiselev, Electronic phenomena in adsorption and catalysis on semiconductors and dielectrics. Springer Series Surf. Sci. 7 (Springer, Berlin, 1987).
C. Li, D.H. Zhang, B. Lei, S. Han, X.L. Liu and C.W. Zhou, Surface treatment and doping dependence of In2O3 nanowires as ammonia sensors. J. Phys. Chem. B 107, 12451–12455 (2003).
A. Kolmakov and M. Moskovits. Chemical sensing and catalysis by one-dimensional metal-oxide nanostructures, Ann. Rev. Mater. Res. 34, 151–180 (2004).
Y. Zhang, A. Kolmakov, Y. Lilach and M. Moskovits, Electronic control of chemistry and catalysis at the surface of an individual tin oxide nanowire, J. Phys. Chem, B 109, 1923–1929 (2005).
Y. Zhang, A. Kolmakov, S. Chretien, H. Metiu and M. Moskovits, Control of catalytic reactions at the surface of a metal oxide nanowire by manipulating electron density inside it, Nano Lett. 4, 403–407 (2004).
X.F. Duan, Y. Huang and C.M. Lieber, Nonvolatile memory and programmable logic from molecule-gated nanowires, Nano Lett. 2, 487–490 (2002).
C. Li, W.D. Fan, B. Lei, et al., Multilevel memory based on molecular devices, Appl. Phys. Lett. 84, 1949–1951 (2004).
Z.Y. Fan and J.G. Lu, Gate-refreshable nanowire chemical sensors, Appl. Phys. Lett. 86, (2005).
S.V. Kalinin, J. Shin, S. Jesse, et al., Electronic transport imaging in a multiwire SnO2 chemical field-effect transistor device, J. Appl. Phys. 98, (2005).
J. Goldberger, D.J. Sirbuly, M. Law and P. Yang, ZnO nanowire transistors, J. Phys. Chem. B 109, 9–14 (2005).
W.I. Park, G.C. Yi, M. Kim and S.J. Pennycook, Quantum confinement observed in ZnO/ZnMgO nanorod helerostructures. Adv. Mater. 15, 526–529 (2003).
Y. Lilach, J.P. Zhang, M. Moskovits and A. Kolmakov, Encoding morphology in oxide nanos-tructures during their growth, Nano Lett, 5, 2019–2022 (2005).
M. Batzill, K. Katsiev, D.J. Caspar and U. Diebold. Variations of the local electronic surface properties of TiO2(110) induced by intrinsic and extrinsic defects, Phys. Rev. B 66, 235401 (2002).
M. Batzill, E.L.D. Hebenstreit, W. Hebenstreit and U. Diebold. Influence of subsurface. charged impurities on the adsorption of chlorine at TiO2(110). Chem. Phys. Lett. 367, 319–323 (2003).
V.P. Zhdanov. Nm-sized metal particles on a semiconductor surface. Schottky model, etc, Surf. Sci, 512, L331–L334 (2002).
A. Kolmakov, D.O. Klenov, Y Lilach, S. Stemmer and M. Moskovits. Enhanced gas sensing by individual SnO2 nanowires and nanobelts functionalized with Pd catalyst particles, Nano Lett. 5, 667–673 (2005).
Z.L. Wang, New developments in transmission electron microscopy for nanotechnology, Adv. Mater. 15, 1497–1514 (2003).
A. Kolmakov, X. Chen and M. M. Moskovits, Functionalizing nanowires with catalytic nanoparticles for gas sensing applications, J. Nanosci. Nanolech. (in press) (2007).
B.H. Frazer, M. Girasole, L.M. Wiese, T. Franz and G. De Stasio, Speclromicroscope for the photoelectron imaging of nanostructures with X-Rays (SPHINX): Performance in biology, medicine and geology, Ultramieroscopy 99, 87–94 (2004).
S. Gunther, B. Kaulich, L. Gregoratti and M. Kiskinova, Prog. Surf. Set. 70, 187–260 (2002).
J.W. Chiou, C.L. Yuen, J.C. Jan, et al., Electronic structure of the carbon nanotube tips studied by X-ray-absorption spectroscopy and scanning photoelectron microscopy, Appl. Phys. Lett. 81, 4189–4191 (2002).
A. Goldoni, R. Larciprete, L. Gregoratti, et al., X-ray photoelectron microscopy of the C Is core level of free-standing single-wall carbon nanotube bundles, Appl. Phys. Lett. 80, 2165–2167 (2002).
S. Suzuki, Y. Watanabe, T. Ogino, et al., Extremely small diffusion constant of Cs in multiwalled carbon nanotubes, J. Appl. Phys. 92, 7527–7531 (2002).
S. Suzuki, Y. Watanabe, T. Ogino, et al., Electronic structure of carbon nanotubes studied by photoelectron spectromicroscopy, Phys. Rev. B 66, 035414 (2002).
J.W. Chiou, J.C. Jan, U.M. Tsai, et al., Electronic structure of GaN nanowire studied by X-rayabsorplion spectroscopy and scanning photoeleciron microscopy, Appl. Phys. Lett. 82, 3949–3951 (2003).
I.H. Hong, J.W. Chiou, S.C Wang, et al., Electronic structure of aligned carbon nanotubes studied by scanning photoelectron microscopy. J. Phys. IV 104, 467–470 (2003).
S. Suzuki, Y. Watanabe, T. Ogino, et al., Observation of single-walled carbon nanotubes by photoemission microscopy, Carbon 42, 559–563 (2004).
R. Larciprete, A. Goldoni, S. Lizzit and L. Pelaccia, The Electronic properties of carbon nanotubes studied by high resolution photocmission spectroscopy. Appl. Surf. Sci. 248, 8–13 (2005).
S. Gunther, A. Kolmakov, J. Kovac and M. Kiskinova. Artifact formation in scanning photoelectron emission microscopy, Ulinimicroscopy 75, 35–51 (1998).
B. Gilten, R. Andres, P. Perfetti, G. Margaritondo, G. Rempfer and G. De Stasio. Charging phenomena in PEEM imaging and spectroscopy, Ulinimicroscopy 83, 129–139 (2000).
A. Kolmakov, U. Lanke, R. Karam, J. Shin, S. Jesse and S.V. Kalinin, Local origins of sensor activity in 1D oxide nanostructures: From spectromicroscopy to device, Nanotechnology 17 (16): 4014–4018 (2006)
A. Kolmakov. The effect of morphology and surface doping on sensitization of quasi-1D metal oxide nanowire gas sensor, Proc. SPIE 6370, 63700X–5 (2007).
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Cuenya, B.R., Kolmakov, A. (2008). Nanostructures: Sensor and Catalytic Properties. In: Seal, S. (eds) Functional Nanostructures. Nanostructure Science and Technology. Springer, New York, NY. https://doi.org/10.1007/978-0-387-48805-9_6
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