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Silsesquioxanes: Advanced Model Supports in Developing Silica-Immobilized Polymerization Catalysts

  • Chapter
Nanostructured Catalysts

Part of the book series: Nanostructure Science and Technology ((NST))

Abstract

To gain more insight, at a molecular level, into processes taking place at silica surfaces, suitable model systems for silica surface silanol sites are of great importance. The major advantage of such homogeneous model systems is that their structural properties and reactivity can be studied in detail using a wide range of powerful techniques such as single crystal X-ray diffraction and multinuclear solution NMR spectroscopy. Several model supports for silica have been studied, ranging from mono-, di- and polysilanols to silsesquioxanes. The latter are probably the most realistic homogeneous model systems for silica surface silanol sites known to date and provide an excellent opportunity to finetune synthetic procedures to modify silica surfaces or to anchor metal complexes to the support. In this chapter, the usefulness of silsesquioxanes to provide information about synthetic strategies, stability and reactivity of silicasupported (co)catalysts will be outlined. Physisorption, grafting and tethering are immobilization techniques that will be discussed. As will be shown, metallasilsesquioxanes not only contribute to a molecular level understanding of known heterogeneous catalyst systems; with activities sometimes even exceeding that of commercial silica-supported catalysts, they are interesting catalysts themselves.

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References and Notes

  1. Harrison, P. G. J. Organomet. Chem. 1997, 542, 141.

    Article  CAS  Google Scholar 

  2. Voronkov, M. G.; Lavrent’yev, V. L. Top. Curr. Chem. 1982, 102, 199.

    CAS  Google Scholar 

  3. Feher, F. J.; Neman, D. A.; Walzer, J. F. J. Am. Chem. Soc. 1989, 111, 1741.

    Article  CAS  Google Scholar 

  4. For example see: Feher, F. J.; Budzichowski, T. A. J. Organomet. Chem. 1989, 373, 153.

    Article  CAS  Google Scholar 

  5. For example see: Feher, F. J.; Schwab, J. J.; Phillips, S. H.; Eklund, A.; Martinez, E. Organometallics 1995, 14, 4452.

    Article  CAS  Google Scholar 

  6. Feher, F. J.; Wyndham, K. D. Chem. Commun. 1998, 323.

    Google Scholar 

  7. Feher, F. J.; Wyndham, K. D.; Knauer, D. J. Chem. Commun. 1998, 2393.

    Google Scholar 

  8. Haddad, T. S.; Farris, A. R.; Lichtenhan, J. D. ACS Polym. Prep. 1997, 38, 127.

    CAS  Google Scholar 

  9. Tsuchida, A.; Bolln, C.; Sernetz, F. G.; Frey, H.; Miilhaupt, R. Macromol. 1997, 30, 2818.

    Article  CAS  Google Scholar 

  10. Feher, F. J.; Schwab, J. J.; Tellers, D. M.; Burstein, A. Main Group Chem. 1998, 2, 169.

    Article  CAS  Google Scholar 

  11. Brown, J. F.; Vogt, L.; H.; Prescott, P. I. J. Am. Chem. Soc. 1964, 86, 1120.

    Article  CAS  Google Scholar 

  12. Feher, F. J.; Newman, D. A. J. Am. Chem. Soc. 1990, 112, 1931.

    Article  CAS  Google Scholar 

  13. Feher, F. J.; Budzichowski, T. A.; Blanski, R. L.; WeUer, K. J.; Ziller, J. W. Organometallics 1991, 10, 2526.

    Article  CAS  Google Scholar 

  14. Feher, F. J.; Phillips, S. H.; Ziller, J. W. Chem. Commun. 1997, 829.

    Google Scholar 

  15. For example, see: Feher, F. J. J. Am. Chem. Soc. 1986, 108, 3850.

    Article  CAS  Google Scholar 

  16. Feher, F. J.; Gonzales, S. L.; Ziller, J. W. Inorg. Chem. 1988, 27, 3442.

    Article  Google Scholar 

  17. Feher, F. J.; Budzichowski, T. A.; Weiler, K. J. J. Am. Chem. Soc. 1989, 111, 7288.

    Article  CAS  Google Scholar 

  18. Feher, F. J.; Walzer, J. F. Inorg. Chem. 1991, 30, 1689.

    Article  CAS  Google Scholar 

  19. Feher, F. J.; Budzichowski, T. A.; Ziller, J. W. Inorg. Chem. 1992, 31, 5100.

    Article  CAS  Google Scholar 

  20. Feher, F. J.; Budzichowski, T. A.; Ziller, J. W. Inorg. Chem. 1997, 36, 4082.

    Article  CAS  Google Scholar 

  21. Brown, J. F.; J. Am. Chem. Soc. 1965, 87, 4317.

    Article  CAS  Google Scholar 

  22. Feher, F. J.; Schwab, J. J.; Soulivong, D.; Ziller, J. W. Main Group Chem. 1997, 2, 123.

    Article  CAS  Google Scholar 

  23. Feher, F. J.; Phillips, S, H.; Ziller, J. W. Chem. Commun. 1997, 3397.

    Google Scholar 

  24. Feher, F. J.; Soulivong, D.; Lewis, G. T. J. Am. Chem. Soc. 1997, 119, 11323.

    Article  CAS  Google Scholar 

  25. Feher, F. J.; Soulivong, D.; Eklund, A. G. Chem. Commun. 1998, 399.

    Google Scholar 

  26. Feher, F. J.; Soulivong, D.; Nguyen, F. Chem. Commun. 1998, 1279.

    Google Scholar 

  27. Feher, F. J.; Nguyen, F.; Soulivong, D.; Ziller, J. W. Chem. Commun. 1999, 1705.

    Google Scholar 

  28. Feher, F, J.; Terroba, R.; Ziller, J. W. Chem. Commun. 1999, 2153.

    Google Scholar 

  29. Feher, F, J.; Terroba, R.; Ziller, J. W. Chem. Commun. 1999, 2309.

    Google Scholar 

  30. Feher, F. I; Terroba, R.; Jin, R.-Z. Chem. Commun. 1999, 2513.

    Google Scholar 

  31. Feher, F. J.; Budzichowski, T. A.; Rahimian, K.; Ziller, J. W. J. Am. Chem. Soc. 1992, 114, 3859.

    Article  CAS  Google Scholar 

  32. Duchateau, R.; Abbenhuis, H. C. L.; van Santen, R. A.; Thiele, S. K.-H.; van Tol, M. F. H. Organometallics 1998, 17, 5222.

    Article  CAS  Google Scholar 

  33. Duchateau, R.; Cremer, U.; Harmsen, R. J.; Mohamud, S. I.; Abbenhuis, H. C. L.; van Santen, R. A.; Meetsma, A.; Thiele, S. K.-H.; van Tol, M. F. H.; Kranenburg, M Organometallics 1999, 18, 5447.

    Article  CAS  Google Scholar 

  34. Feher, F. J.; Budzichowski, T. A.; Weller, K. J. J. Am. Chem. Soc. 1989, 111, 7288.

    Article  CAS  Google Scholar 

  35. Feher, F. J.; Weiler, K. J. Organometallics 1990, 9, 2638.

    Article  CAS  Google Scholar 

  36. Feher, F. J.; Weller, K. J.; Ziller, J. W. J. Am. Chem. Soc. 1992, 114, 9686.

    Article  CAS  Google Scholar 

  37. Edelmann, F. T.; Gun’ko, Y. K.; Giessmann, S.; Olbrich, F. Inorg. Chem. 1999, 38, 210.

    Article  CAS  Google Scholar 

  38. Duchateau, R.; Harmsen, R. J.; Abbenhuis, H. C. L.; van Santen, R. A.; Meetsma, A.; Thiele, S. K.-H.; Kranenburg, M. Chem. Eur. J. 1999, 5, 3130.

    Article  CAS  Google Scholar 

  39. Skowronska-Ptasinska, M. D.; Duchateau, R.; van Santen, R. A.; Yap, G. P. A. Eur. J. Inorg. Chem. 2001, 133.

    Google Scholar 

  40. Feher, F. J.; Budzichowski, T. A. J. Organomet. Chem. 1989, 379, 33.

    Article  CAS  Google Scholar 

  41. Feher, F. J.; Blanski, R. L. J. Chem. Soc, Chem. Comm. 1990, 1614.

    Google Scholar 

  42. Feher, F. J.; Tajima, T. L. J. Am. Chem. Soc. 1994, 116, 2145.

    Article  CAS  Google Scholar 

  43. Feher, F. J.; Rahimian, K.; Budzichowski, T. A.; Ziller, J. W. Organometallics 1995, 14, 3920.

    Article  CAS  Google Scholar 

  44. Krijnen, S.; Harmsen, R. J.; Abbenhuis, H. C. L.; van Hooff, J. H. C.; van Santen, R. A. Chem. Commun. 1999, 501.

    Google Scholar 

  45. For example, see: Baney, R. H.; Itoh, M.; Sakakibara, A.; Suzuki, T. Chem. Rev. 1995, 95, 1409.

    Article  CAS  Google Scholar 

  46. For example, see: Feher, F. J.; Budzichowski, T. A. Polyhedron 1995, 14, 3929.

    Article  Google Scholar 

  47. For example, see: Murugavel, R.; Voigt, A.; Walawalkar, M. G.; Roesky, H. W. Chem. Rev. 1996, 96, 2205.

    Article  CAS  Google Scholar 

  48. For example, see: Abbenhuis, H. C. L. Chem. Eur. J. 2000, 6, 25.

    Article  CAS  Google Scholar 

  49. For example, see: Lorenz, V.; Fischer, A.; Giessmann, S.; Gilje, J. W.; Gun’ko, Y.; Jacob, K.; Edelmann, F. T. Coord. Chem. Rev. 2000, 206-207, 321.

    Article  CAS  Google Scholar 

  50. Herrmann, W. A.; Anwander, R.; Dufaud, V.; Sherer, W. Angew. Chem., Int. Ed Eng. 1994, 33, 1285.

    Article  Google Scholar 

  51. Abbenhuis, H. C. L.; van Herwijnen, H. W. G.; van Santen, R. A. J. Chem. Soc., Chem. Comm. 1996, 1941.

    Google Scholar 

  52. Feher, F. J.; Tajima, T. L. J. Am. Chem. Soc. 1994, 116, 2145.

    Article  CAS  Google Scholar 

  53. Abbenhuis, H. C. L.; Krijnen, S.; van Santen, R. A. Chem. Commun. 1997, 331. Maschmeyer, T.; Klunduk, M. C.; Martin, C. M.; Shephard, D. S.; Thomas, J. M.; Johnson, B. F. G. Chem. Commun. 1997, 1847.

    Google Scholar 

  54. Crocker, M.; Herold, R. H. M.; Orpen, A. G. Chem. Commun. 1997, 2411.

    Google Scholar 

  55. Klunduk, M. C.; Maschmeyer, T.; Thomas, J. M.; Johnson, B. F. G. Chem. Eur. J. 1999, 5, 1481.

    Article  CAS  Google Scholar 

  56. Crocker, M.; Herold, R. H. M. PCT Int. Appl. 96/05873.

    Google Scholar 

  57. Maschmeyer, T.; Klunduk, M. C.; Martin, C. M.; Shephard, D. S.; Thomas, J. M.; Johnson, B. F. G. Inorg. Chem. 1997, 1847.

    Google Scholar 

  58. For example, see: Hungenberg, K. H.; Keith, J.; Langhauser, F.; Marczinke, B.; Schlund, R. in Ziegler Catalysts, Fink, G.; Mülhaupt, R; Brintzinger, H. H. Eds., Springer-Verlag: New York, 1995, Chapter 20.

    Google Scholar 

  59. Hlatky, G. G. Chem. Rev. 2000, 100, 1347.

    Article  CAS  Google Scholar 

  60. Feher, F. J.; Walzer, J. F.; Blanski, R. L. J. Am. Chem. Soc. 1991, 113, 3618.

    Article  CAS  Google Scholar 

  61. Feher, F. J.; Blanski, R. L. J. Am. Chem. Soc. 1992, 114, 5886.

    Article  CAS  Google Scholar 

  62. 26. (a) Feher, F. J.; Blanski, R. L. Makromol. Chem., Macromol. Symp. 1993, 66, 95.

    CAS  Google Scholar 

  63. Abbenhuis, H. C. L.; Vorstenbosch, M. L. W.; van Santen, R. A.; Smeets, W. J. J.; Spek, A. L. Inorg. Chem. 1997, 36, 6431.

    Article  CAS  Google Scholar 

  64. Liu, J.-C. Chem. Commun. 1996, 1109.

    Google Scholar 

  65. For example, see: Scott, S.; Basset, J.-M.; Niccolai, G. P.; Santini, C. C.; Candy, J.-P.; Lecuyer, C.; Quignard, F.; Choplin, A. New. J. Chem. 1994, 18, 115.

    CAS  Google Scholar 

  66. For example, see: Vidal, V.; Théolier, A.; Thivolle-Cazat, J.; Basset, J.-M.; Corker, J. J. Am. Chem. Soc. 1996, 118, 4595.

    Article  CAS  Google Scholar 

  67. For example, see: Rosier, C.; Niccolai, G. P.; Basset, J.-M. J. Am Chem. Soc. 1997, 119, 12408.

    Article  CAS  Google Scholar 

  68. For example, see: Dufaud, V.; Basset, J.-M. Angew. Chem. 1998, 110, 848.

    Article  Google Scholar 

  69. For example, see: Amor Nait Ajjou, J.; Scott, S. L. Organometallics 1997, 16, 86.

    Article  Google Scholar 

  70. Karapinka, G. L. US Patent 3,709,853, 1973.

    Google Scholar 

  71. Karol, F. J. US Patent 4,015,059, 1977.

    Google Scholar 

  72. Karol, F. J.; Karapinka, G. L.; Wu, C.; Dow, A. W.; Johnson, R. N.; Carrick, W. L. J. Polym. Sci.: Part A1, 1972, 10, 2621.

    Article  CAS  Google Scholar 

  73. Fu, S.-L.; Lunsford, J. H. Langmut, 1990, 6, 1774.

    Article  CAS  Google Scholar 

  74. For example, see: Thomas, B. J.; Theopold, K. H. J. Am. Chem. Soc, 1988, 110, 5902.

    Article  CAS  Google Scholar 

  75. For example, see: White, P. A.; Calabrese, J.; Theopold, K. H. Organometallics, 1996, 15, 5473.

    Article  CAS  Google Scholar 

  76. For example, see: Theopold, K. H. Eur. J. Inorg. Chem., 1998, 15.

    Google Scholar 

  77. Ittel, S. D. J. Macromol Sci., Chem. 1990, A27, 1133.

    Article  CAS  Google Scholar 

  78. Ittel, S. D.; Nelson, L. T. J. Polym. Prepr. 1994, 35, 665.

    CAS  Google Scholar 

  79. Duchateau, R.; Abbenhuis, H. C. L.; van Santen, R. A.; Meetsma, A.; Thiele, S. K.-H.; van Tol, M. F. H. Organometallics 1998, 17, 5663.

    Article  CAS  Google Scholar 

  80. Hungenberg, K. H.; Kerth, J.; Langhauser, F.; Marczinke, B.; Schlund, R. in Ziegler Catalysts, eds. Fink, G.; Mülhaupt, R; Brintzinger, H. H., Springer-Verlag, New York, 1995, Chapter 20.

    Google Scholar 

  81. Chien, J. C. W.; He, D. J. Polym. Sci.: PartA: Pol. Chem. 1991, 1603.

    Google Scholar 

  82. For example, see: Chen, Y.-X.; Rausch, M. D.; Chien, J. C. W. J. Polym. Sci., A: Polym. Chem. 1995, 33, 2093.

    Article  CAS  Google Scholar 

  83. For example, see: Hlatky, G. G.; Upton, D. J. Macromol. 1996, 29, 8019.

    Article  CAS  Google Scholar 

  84. For example, see: Roscoe, S. B.; Fréchet, J. M. J.; Walzer, J. F.; Dias, A. J. Science 1998, 280, 270.

    Article  CAS  Google Scholar 

  85. For example, see: Bochmann, M.; Pindado, G. J.; Lancaster, S. J. J. Mol. Catal, A: Chem. 1999, 146, 179.

    Article  CAS  Google Scholar 

  86. For example, see: Turner, H. W. U.S. Pat. Appl. 5,427,991 (1995).

    Google Scholar 

  87. For example, see: Ono, M.; Hinokuma, S.; Miyake, S.; Inazawa, S. Eur. Pat. Appl. 710,663 (1996).

    Google Scholar 

  88. For example, see: Jacobsen, G. B.; Wijkens, P.; Jastrzebski, J.; van Koten, G. PCTInt. Appl. 96/28480 (1996).

    Google Scholar 

  89. For example, see: Kaneko, T.; Sato, M. Eur. Pat. Appl. 727,433 (1996).

    Google Scholar 

  90. For example, see: Hinokuma, S.; Miyake, S.; Ono, M.; Inazawa, S. Eur. Pat. Appl. 775,707 (1997).

    Google Scholar 

  91. For example, see: Carnahan, E. M.; Carney, M. J.; Neithamer, D. R.; Nickias, P. N.; Shih, K.-Y.; Spencer, L. PCT Int. Appl. 97/19959.

    Google Scholar 

  92. For example, see: Kaneko, T.; Sato, M. U.S. Pat. Appl. 5.807,938 (1998).

    Google Scholar 

  93. Hlatky, G. G.; Upton, D. J.; Turner, H. W. PCT Int. Appl. 91/09822.

    Google Scholar 

  94. Turner, H. W.; US Pat. Appl. 5,427,991 (1995).

    Google Scholar 

  95. Walzer, J. F. Jr. PCT Int. Appl. 95/04319.

    Google Scholar 

  96. Ward, D. G.; Carnahan, E. M. PCT Int. Appl. 96/23005.

    Google Scholar 

  97. Walzer, J. F. Jr. U.S. Pat. Appl. 5.643,847 (1997).

    Google Scholar 

  98. Buys, I. E.; Hambley, T. W.; Houlton, D. J.; Maschmeyer, T.; Masters, A. F.; Smith, A. K. J. Mol. Catal. 1994, 86, 309–318.

    Article  CAS  Google Scholar 

  99. Edelmann, F. T.; Gießmann, S.; Fischer, A. Chem. Commun. 2000, 2153–2154.

    Google Scholar 

  100. Edelmann, F. T.; Gießmann, S.; Fischer, A. J. Organomet. Chem. 2001, 620, 80.

    Article  CAS  Google Scholar 

  101. For example, see: Gao, H.; Angelici, R. J. Organometallics 1999, 18, 989.

    Article  CAS  Google Scholar 

  102. For example, see: Clark, J. H.; Macquarrie, D. J. Chem. Commun. 1998, 853.

    Google Scholar 

  103. For example, see: Johnson, B. F. G.; Raynor, S. A.; Shephard, D.S.; Maschmeyer, T.; Meurig Thomas, J.; Sankar, G.; Bromley, S.; Oldroyd, R.; Gladden, L.; Mantle, M. D. Chem. Commun. 1999, 1167.

    Google Scholar 

  104. For example, see: de Vos, D. E.; Jacobs, P. A. Catal. Today 2000, 57, 105.

    Article  Google Scholar 

  105. For example, see: Liu, C.-J.; Yu, W.-Y.; Li, S.-G.; Che, C.-M. J. Org. Chem. 1998, 63, 7364.

    Article  CAS  Google Scholar 

  106. For example, see: Petrucci, M. G. L.; Kakkar, A. K. Chem. Mater. 1999, 11, 269.

    Article  CAS  Google Scholar 

  107. For example, see: Jorna, A. M. J.; Boeldijk, A. E. M.; Hoorn, H. J.; Reedijk, J. React. Polym. 1996, 29, 101.

    Article  CAS  Google Scholar 

  108. For example, see: Lee, D.-H.; Yoon, K.-B. Macromol. Rapid Commun. 1997, 18, 427.

    Article  CAS  Google Scholar 

  109. For example, see: Galan-Fereres, M.; Koch, T.; Hey-Hawkins, E.; Eisen, M. S. J. Organomet. Chem. 1999, 580, 145.

    Article  CAS  Google Scholar 

  110. For example, see: Juvaste, H.; Iiskola, E. I.; Pakkanen, T. T. J. Mol. Catal. A: Chem. 1999, 150, 1.

    Article  CAS  Google Scholar 

  111. For example, see: Iiskola, E. I.; Timonen, S.; Pakkanen, T. T.; Kärkki, O.; Seppälä, J. V. Appl. Surf. Sci. 1997, 121/122, 372.

    Google Scholar 

  112. For example, see: Uusitalo, A.-M; Pakkanen, T. T.; Iiskola, E. I. J. Mol. Catal. A: Chem. 2000, 156, 181.

    Article  CAS  Google Scholar 

  113. Severn, J. R.; Duchateau, R.; van Santen, R. A.; Yap, G. P. A.; Ellis, D. D.; Spek, A. L. Organometallics 2002, 21, 4.

    Article  CAS  Google Scholar 

  114. Chang, M. U.S. Pat. 5,008,228, 1991.

    Google Scholar 

  115. Tsutsui, T.; Ueda, T. U.S. Patent 5,234,878, 1993.

    Google Scholar 

  116. Giirtzgen, S. U.S. Patent 5,446,001, 1995.

    Google Scholar 

  117. Herrmann, H. F.; Bachmann, B.; Spaleck, W. Eur. Pat. Appl. 578,838, 1994.

    Google Scholar 

  118. Becker, R.-J.; Rieger, R. Eur. Pat. Appl. 763,546, 1997.

    Google Scholar 

  119. Becker, R.-J.; Giirtzgen, S.; Kutschera, D. U.S. Patent 5,534,474, 1996.

    Google Scholar 

  120. Kutschera, D.; Rieger, R. U.S. Patent 5,789,332, 1998.

    Google Scholar 

  121. Skowronska-Ptasinska, M. D.; Duchateau, R.; van Santen, R. A.; Yap, G. P. A. Organometallics 2001, 20, 3519.

    Article  CAS  Google Scholar 

  122. Harlan, C. J.; Bott, S. G.; Barron, A. R. J. Am. Chem. Soc. 1995, 117, 6465.

    Article  CAS  Google Scholar 

  123. Ann, H.; Marks, T. J. J. Am. Chem. Soc. 1998, 120, 13533.

    Article  Google Scholar 

  124. Yang, X.; Stern, C. L.; Marks, T. J. J. Am. Chem. Soc. 1994, 116, 10015.

    Article  CAS  Google Scholar 

  125. Bochmann, M.; Dawson, D. M. Angew. Chem., Int. Ed. Engl. 1996, 35, 2226.

    Article  CAS  Google Scholar 

  126. Coles, M. P.; Jordan, R. F. J. Am. Chem. Soc. 1997, 119, 8125.

    Article  CAS  Google Scholar 

  127. Amor, F.; Butt, A.; du Plooy, K. E.; Spaniol, T. P.; Okuda, J. Organometallics 1998, 17, 5836.

    Article  CAS  Google Scholar 

  128. Song, X.; Thornton-Pett, M.; Bochmann, M. Organometallics 1998, 17, 1004.

    Article  CAS  Google Scholar 

  129. Green, M. L. H.; Saßmannhausen, J. Chem. Commun. 1999, 115.

    Google Scholar 

  130. Guérin, F.; Stephan, D. W. Angew. Chem., Int. Ed. 2000, 39, 1298.

    Article  Google Scholar 

  131. See also: Siedle, A. R.; Newmark, R. A.; Lamanna, W. M.; Schroepfer, J. N. Polyhedron 1990, 9, 301.

    Article  CAS  Google Scholar 

  132. See also: Harlan, C. J.; Bott, S. G.; Barron, A. R. J. Am. Chem. Soc. 1995, 117, 6465.

    Article  CAS  Google Scholar 

  133. See also: Koide, Y.; Bott, S. G.; Barron, A. R. Organometallics 1996, 15, 2213.

    Article  CAS  Google Scholar 

  134. See also: Metz, M. V.; Schwartz, D. J.; Stern, C. L.; Nickias, P. N.; Marks, T. J. Angew. Chem., Int. Ed. 2000, 39, 1312 and references cited therein.

    Article  CAS  Google Scholar 

  135. Duchateau, R.; van Santen, R. A.; Yap. G. P. A. Organometallics 2000, 19, 809.

    Article  CAS  Google Scholar 

  136. Metcalfe, R. A.; Kreller, D. I.; Tian, J.; Kim, H.; Corrigan, J. F.; Taylor, N. J.; Collins, S. Organometallics 2002, 21, 1719.

    Article  CAS  Google Scholar 

  137. Krijnen, S.; Abbenhuis, H. C. L.; Hanssen, R. W. J. M.; van Hooff, J. H. C.; van Santen, R. A. Angew. Chem. Int. Ed. Eng. 1998, 37, 356.

    Article  CAS  Google Scholar 

  138. Smet, P.; Rioandato, J.; Pauwels, T.; Moens, L.; Verdonck, L. Inorg. Chem. Commun. 2000, 3, 557.

    Article  CAS  Google Scholar 

  139. Maxim, N.; Abbenhuis, H. C. L.; Magusin, P. C. M. M.; van Santen, R. A. Chin. J. Chem. 2001, 19, 30.

    CAS  Google Scholar 

  140. Wada, K.; Nakashita, M.; Yamamoto, A.; Mitsuda, T. Chem. Commun. 1998, 133.

    Google Scholar 

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  1. Dutch Polymer Institute, Department of Inorganic Chemistry and Catalysis, Eindhoven University of Technology, P.O.Box 513, 5600 MB, Eindhoven, The Netherlands

    R. Duchateau

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  1. University of Ottawa, Ottawa, Ontario, Canada

    Susannah L. Scott

  2. Queen’s University, Kingston, Ontario, Canada

    Cathleen M. Crudden

  3. Georgia Institute of Technology, Atlanta, Georgia

    Christopher W. Jones

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Duchateau, R. (2005). Silsesquioxanes: Advanced Model Supports in Developing Silica-Immobilized Polymerization Catalysts. In: Scott, S.L., Crudden, C.M., Jones, C.W. (eds) Nanostructured Catalysts. Nanostructure Science and Technology. Springer, Boston, MA. https://doi.org/10.1007/978-0-387-30641-4_3

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