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Multifunctional Active Sites on Silica Surfaces by Grafting of Metal Complexes

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Nanostructured Catalysts

Part of the book series: Nanostructure Science and Technology ((NST))

Abstract

Supported metal catalysts containing more than one functionality can be created by routes involving simultaneous or sequential grafting of one or more molecular complexes. The resulting active sites are more complex than single component heterogeneous or homogeneous analogues, and may offer significant benefits in terms of catalytic selectivity and stability towards deactivation processes. Non-hydrolytic methods for the preparation of heterometallic active sites are potentially a powerful route to finely-tuned multicomponent heterogeneous catalysts. Strategies for using siloxane and surface hydroxyl sites to create such active sites are presented, with an emphasis on particularly well-characterized systems.

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Authors and Affiliations

  1. Centre for Catalysis Research and Innovation, Department of Chemistry, University of Ottawa, Ottawa, ON, Canada, KIN 6N5

    Susannah L. Scott & Eric W. Deguns

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  1. Susannah L. Scott
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  2. Eric W. Deguns
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Editors and Affiliations

  1. University of Ottawa, Ottawa, Ontario, Canada

    Susannah L. Scott

  2. Queen’s University, Kingston, Ontario, Canada

    Cathleen M. Crudden

  3. Georgia Institute of Technology, Atlanta, Georgia

    Christopher W. Jones

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© 2005 Springer Science + Business Media, Inc.

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Scott, S.L., Deguns, E.W. (2005). Multifunctional Active Sites on Silica Surfaces by Grafting of Metal Complexes. In: Scott, S.L., Crudden, C.M., Jones, C.W. (eds) Nanostructured Catalysts. Nanostructure Science and Technology. Springer, Boston, MA. https://doi.org/10.1007/978-0-387-30641-4_1

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  • DOI: https://doi.org/10.1007/978-0-387-30641-4_1

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-0-306-47484-2

  • Online ISBN: 978-0-387-30641-4

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