Designed Polymers for Ablation

  • Lukas Urech
  • Thomas Lippert
Part of the Springer Series in Optical Sciences book series (SSOS, volume 129)


Laser Ablation Irradiation Wavelength Ablation Rate Ablation Product Ablation Depth 
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  1. Andrew, J. E., Dyer, P. E., Forster, D. and Key, P. H., 1983, Direct etching of polymeric materials using a XeCl laser, Appl. Phys. Lett. 43(8): 717–719.CrossRefADSGoogle Scholar
  2. Aoki, H. (1998). U.S. Patent 5736999.Google Scholar
  3. Arnold, N. and Bityurin, N., 1999, Model for laser-induced thermal degradation and ablation of polymers, Appl. Phys. A-Mater. Sci. Process. 68(6): 615–625.CrossRefADSGoogle Scholar
  4. Bennett, L. S., Lippert, T., Furutani, H., Fukumura, H. and Masuhara, H., 1996, Laser induced microexplosions of a photosensitive polymer, Appl. Phys. A-Mater. Sci. Process. 63(4): 327–332.ADSCrossRefGoogle Scholar
  5. Bityurin, N., Luk’yanchuk, B. S., Hong, M. H. and Chong, T. C., 2003, Models for laser ablation of polymers, Chem. Rev. 103(2): 519–552.CrossRefGoogle Scholar
  6. Bonse, J., Wiggins, S. M., Solis, J. and Lippert, T., 2005a, Phase change dynamics in a polymer thin film upon femtosecond and picosecond laser irradiation, Appl. Surf. Sci. 247(1–4): 440–446.CrossRefADSGoogle Scholar
  7. Bonse, J., Wiggins, S. M., Solis, J., Lippert, T. and Sturm, H., 2005b, Femtosecond laser-induced decomposition in triazenepolymer thin films, Appl. Surf. Sci. 248(1–4): 157–162.CrossRefADSGoogle Scholar
  8. Bäuerle, D., 2000, Laser processing and chemistry, Springer Verlag, BerlinGoogle Scholar
  9. David, C., Wei, J., Lippert, T. and Wokaun, A., 2001, Diffractive grey-tone phase masks for laser ablation lithography, Microelectron. Eng. 57–8: 453–460.CrossRefGoogle Scholar
  10. Frankel, M. B., Grant, L. R. and Flanagan, J. E., 1992, Historical development of glycidyl azide polymer, J. Propul. Power 8(3): 560–563.CrossRefGoogle Scholar
  11. Furutani, H., Fukumura, H. and Masuhara, H., 1996, Photothermal transient expansion and contraction dynamics of polymer films by nanosecond interferometry, J. Phys. Chem. 100(17): 6871–6875.CrossRefGoogle Scholar
  12. Furutani, H., Fukumura, H., Masuhara, H., Kambara, S., Kitaguchi, T., Tsukada, H. and Ozawa, T., 1998, Laser-induced decomposition and ablation dynamics studied by nanosecond interferometry. 2. A reactive nitrocellulose film, J. Phys. Chem. B 102(18): 3395–3401.CrossRefGoogle Scholar
  13. Hauer, M., Dickinson, T., Langford, S., Lippert, T. and Wokaun, A., 2002, Influence of the irradiation wavelength on the ablation process of designed polymers, Appl. Surf. Sci. 197: 791–795.CrossRefADSGoogle Scholar
  14. Hauer, M., Funk, D. J., Lippert, T. and Wokaun, A., 2003, Laser ablation of polymers studied by ns-interferometry and ns-shadowgraphy measurements, Appl. Surf. Sci. 208: 107–112.CrossRefADSGoogle Scholar
  15. Hauer, M., Funk, D. J., Lippert, T. and Wokaun, A., 2004, Time resolved study of the laser ablation induced Shockwave, Thin Solid Films 453–54: 584–588.CrossRefGoogle Scholar
  16. Kawamura, Y., Toyoda, K. and Namba, S., 1982, Effective deep ultraviolet photoetching of poly(methyl methacrylate) by an excimer laser, Appl. Phys. Lett. 40(5): 374–375.CrossRefADSGoogle Scholar
  17. Kuhnke, M., Cramer, L., Dickinson, J. T., Lippert, T. and Wokaun, A., 2003, TOF-MS study of photoreaktive polymers ablated by F2 excimer laser (157 nm), Poster at COLA 2003.Google Scholar
  18. Köhler, J. and Meyer, R., 1998, Explosivstoffe, Wiley-VCH, WeinheimCrossRefGoogle Scholar
  19. Küper, S. and Stuke, M., 1989, UV-excimer-laser ablation of polymethylmethacrylate at 248 nm — characterization of incubation sites with fourier-transform IR-spectroscopy and UV-spectroscopy, Appl. Phys. A-Mater. Sci. Process. 49(2): 211–215.CrossRefADSGoogle Scholar
  20. Lazare, S. and Granier, V., 1989, Ultraviolet-laser photoablation of polymers — a review and recent results, Laser Chem. 10(1): 25–40.CrossRefGoogle Scholar
  21. Lippert, T. (2004). Laser application of polymers, Polymers and light. Berlin, Springer-Verlag Berlin. 168: pp. 51–246.Google Scholar
  22. Lippert, T., 2005, Interaction of photons with polymers: From surface modification to ablation, Plasma Processes And Polymers 2: 525–546.CrossRefGoogle Scholar
  23. Lippert, T., Bennett, L. S., Nakamura, T., Niino, H. and Yabe, A., 1996, Single pulse threshold and transmission behaviour of a triazeno-polymer during pulsed UV-laser irradiation, Appl. Surf. Sci. 96–8: 601–604.CrossRefADSGoogle Scholar
  24. Lippert, T., David, C., Dickinson, J. T., Hauer, M., Kogelschatz, U., Langford, S. C., Nuyken, O., Phipps, C., Robert, J. and Wokaun, A., 2001a, Structure property relations of photoreactive polymers designed for laser ablation, J. Photochem. Photobiol. A-Chem. 145(3): 145–157.CrossRefGoogle Scholar
  25. Lippert, T., David, C., Hauer, M., Masubuchi, T., Masuhara, H., Nomura, K., Nuyken, O., Phipps, C., Robert, J., Tada, T., Tomita, K. and Wokaun, A., 2002a, Novel applications for laser ablation of photopolymers, Appl. Surf. Sci. 186(1–4): 14–23.CrossRefADSGoogle Scholar
  26. Lippert, T., David, C., Hauer, M., Wokaun, A., Robert, J., Nuyken, O. and Phipps, C., 2001b, Polymers for UV and near-IR irradiation, J. Photochem. Photobiol. A-Chem. 145(1–2): 87–92.CrossRefGoogle Scholar
  27. Lippert, T. and Dickinson, J. T., 2003, Chemical and spectroscopic aspects of polymer ablation: Special features and novel directions, Chem. Rev. 103(2): 453–485.CrossRefGoogle Scholar
  28. Lippert, T., Dickinson, J. T., Hauer, M., Kopitkovas, G., Langford, S. C., Masuhara, H., Nuyken, O., Robert, J., Salmio, H., Tada, T., Tomita, K. and Wokaun, A., 2002b, Polymers designed for laser ablation-influence of photochemical properties, Appl. Surf. Sci. 197: 746–756.CrossRefADSGoogle Scholar
  29. Lippert, T., Hauer, M., Phipps, C. R. and Wokaun, A., 2003, Fundamentals and applications of polymers designed for laser ablation, Appl. Phys. A-Mater. Sci. Process. 77(2): 259–264.ADSGoogle Scholar
  30. Lippert, T., Langford, S. C., Wokaun, A., Savas, G. and Dickinson, J. T., 1999a, Analysis of neutral fragments from ultraviolet laser irradiation of a photolabile triazeno polymer, J. Appl. Phys. 86(12): 7116–7122.CrossRefADSGoogle Scholar
  31. Lippert, T., Stebani, J., Nuyken, O., Stasko, A. and Wokaun, A., 1994, Photolysis of 1-aryl-3,3-dialkyltriazenes, J. Photochem. Photobiol. A-Chem. 78(2): 139–148.CrossRefGoogle Scholar
  32. Lippert, T., Wokaun, A., Langford, S. C. and Dickinson, J. T., 1999b, Emission of neutral molecules during UV laser ablation of a photolabile triazeno polymer, Appl. Phys. A-Mater. Sci. Process. 69: S655–S658.CrossRefADSGoogle Scholar
  33. Lippert, T., Wokaun, A., Stebani, J., Nuyken, O. and Ihlemann, J., 1993, Dopant-induced laser-ablation of PMMA at 308-nm — influence of the molecular-weight of PMMA and of the photochemical activity of added chromophores, Angew. Makromol. Chem. 213: 127–155.CrossRefGoogle Scholar
  34. Lippert, T., Yabe, A. and Wokaun, A., 1997, Laser ablation of doped polymer systems, Adv. Mater. 9(2): 105–119.CrossRefGoogle Scholar
  35. Nuyken, O., Stebani, J., Lippert, T., Wokaun, A. and Stasko, A., 1995a, Photolysis, thermolysis, and protolytic decomposition of a triazene polymer in solution, Macromol. Chem. Phys. 196(3): 751–761.CrossRefGoogle Scholar
  36. Nuyken, O., Stebani, J., Lippert, T., Wokaun, A. and Stasko, A., 1995b, Synthesis and characterization of novel triazeno-group containing photopolymers, Macromol. Chem. Phys. 196(3): 739–749.CrossRefGoogle Scholar
  37. Patel, R. S. and Wassick, T. A., 1997, Proc. SPIE-Int. Soc. Opt. Eng. Google Scholar
  38. Phipps, C. and Luke, J., 2002, Diode laser-driven microthrusters: A new departure for micropropulsion, AIAA Journal 40(2): 310–318.ADSCrossRefGoogle Scholar
  39. Phipps, C., Luke, J. and Lippert, T., 2004a, Laser ablation of organic coatings as a basis for micropropulsion, Thin Solid Films 453–454: 573–583.CrossRefGoogle Scholar
  40. Phipps, C., Luke, J., Lippert, T., Hauer, M. and Wokaun, A., 2004b, Micropropulsion using a laser ablation jet, J. Propul. Power 20(6): 1000–1011.CrossRefGoogle Scholar
  41. Phipps, C. R., Luke, J. R., McDuff, G. G. and Lippert, T., 2002, Laser ablation powered mini-thruster, Proc. SPIE 4760: 833–842.ADSCrossRefGoogle Scholar
  42. Phipps, C. R., Luke, J. R., McDuff, G. G. and Lippert, T., 2003, Laser-driven micro-rocket, Appl. Phys. A-Mater. Sci. Process. 77(2): 193–201.ADSGoogle Scholar
  43. Pique, A., Wu, P., Ringeisen, B. R., Bubb, D. M., Melinger, J. S., McGill, R. A. and Chrisey, D. B., 2002, Processing of functional polymers and organic thin films by the matrix-assisted pulsed laser evaporation (MAPLE) technique, Appl. Surf. Sci. 186(1–4): 408–415.CrossRefADSGoogle Scholar
  44. Richner, R. P., 2001, Entwicklung neuartig gebundener kohlenstoffmaterialien für elektrische doppelschichtkondensatorelektroden, DISS. ETH Nr. 14413, ETH, ZürichGoogle Scholar
  45. Srinivasan, R. and Braren, B., 1984, Ablative photodecomposition of polymer-films by pulsed far-ultraviolet (193 nm) laser-radiation — dependence of etch depth on experimental conditions, J. Polym. Sci. Pol. Chem. 22(10): 2601–2609.Google Scholar
  46. Srinivasan, R. and Braren, B., 1989, Ultraviolet-laser ablation of organic polymers, Chem. Rev. 89(6): 1303–1316.CrossRefGoogle Scholar
  47. Srinivasan, R., Braren, B. and Casey, K. G., 1990, Nature of incubation pulses in the ultraviolet-laser ablation of polymethyl methacrylate, J. Appl. Phys. 68(4): 1842–1847.CrossRefADSGoogle Scholar
  48. Srinivasan, R. and Mayne-Banton, V., 1982, Self-developing photoetching of poly(ethylene-terephthalate) films by far ultraviolet excimer laser-radiation, Appl. Phys. Lett. 41(6): 576–578.CrossRefADSGoogle Scholar
  49. Stasko, A., Adamcik, V., Lippert, T., Wokaun, A., Dauth, J. and Nuyken, O., 1993, Photochemical decomposition of triazenes — (electron-paramagnetic-resonance study), Makromolekulare Chemie-Macromolecular Chemistry And Physics 194(12): 3385–3391.Google Scholar
  50. Suzuki, K., Matsuda, M., Ogino, T., Hayashi, N., Terabayashi, T. and Amemiya, K., 1997, Proc. SPIE. Google Scholar
  51. Urech, L., Hauer, M., Lippert, T., Phipps, C. R., Schmid, E., Wokaun, A. and Wysong, I., 2004, Designed polymers for laser-based microthrusters — correlation of thrust with material, plasma, and Shockwave properties, Proc. SPIE 5448: 52–64.ADSCrossRefGoogle Scholar
  52. Wen, X. N., Hare, D. E. and Dlott, D. D., 1994, Laser polymer ablation threshold lowered by nanometer hot-spots, Appl. Phys. Lett. 64(2): 184–186.CrossRefADSGoogle Scholar

Copyright information

© Springer Science+Business Media LLC 2007

Authors and Affiliations

  • Lukas Urech
    • 1
  • Thomas Lippert
    • 1
  1. 1.General Energy Research DepartmentPaul Scherrer InstitutVilligen PSISwitzerland

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