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One Deck More: The Chemical “Big Mac”

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Landmarks in Organo-Transition Metal Chemistry

Part of the book series: Profiles in Inorganic Chemistry ((PIIC))

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References

  1. M. Rosenblum, Chemistry of Iron Group Metallocenes, Part 1 (Wiley, New York, 1965, Chap. 4).

    Google Scholar 

  2. E. Schumacher, and R. Taubenest, “Tripeldecker-Sandwiches” aus Ferrocen und Nickelocen, Helv. Chim. Acta 47, 1525–1529 (1964).

    Article  CAS  Google Scholar 

  3. S. M. Schildcrout, High-Pressure Mass Spectra and Gaseous Ion Chemistry of Ferrocene, J. Am. Chem. Soc. 95, 3846–3849 (1973).

    Article  CAS  Google Scholar 

  4. H. Werner, G. Mattmann, A. Salzer, and T. Winkler, Elektronentransfer-Reaktionen von Dicyclopentadienylnickel und –cobalt mit Triphenylmethyl-chlorid, J. Organomet. Chem. 25, 461–474 (1970).

    Article  CAS  Google Scholar 

  5. H. Werner, and A. Salzer, Die Synthese eines ersten Doppel-Sandwich-Komplexes: Das Dinickeltricyclopentadienyl-Kation, Synth. Inorg. Met.-Org. Chem. 2, 239–248 (1972).

    Article  CAS  Google Scholar 

  6. A. Salzer, and H. Werner, A New Route to Triple-Decker Sandwich Compounds, Angew. Chem. Int. Ed. Engl. 11, 930–932 (1972).

    Article  CAS  Google Scholar 

  7. E. Dubler, M. Textor, H. R. Oswald, and A. Salzer, X-Ray Structure Analysis of the Triple-Decker Sandwich Complex Tris(η-cyclopentadienyl)dinickel Tetrafluoroborate, Angew. Chem. Int. Ed. Engl. 13, 135 (1974).

    Article  Google Scholar 

  8. H. Werner, New Varieties of Sandwich Complexes, Angew. Chem. Int. Ed. Engl. 16, 1–9 (1977).

    Article  Google Scholar 

  9. U. Bertling, U. Englert, and A. Salzer, From the Tripeldecker to a Metallabenzene: A New Generation of Sandwich Complexes, Angew. Chem. Int. Ed. Engl. 33, 1003–1005 (1994).

    Article  Google Scholar 

  10. T. L. Court, and H. Werner, Concerning the Mechanism of Formation of the Cationic Triple Decker Sandwich Complex [Ni2(C5H5)3]+, and the Isolation of [NiC5H5]BF4, J. Organomet. Chem. 65, 245–251 (1974).

    Article  CAS  Google Scholar 

  11. R. B. King, Electron Impact Studies on Cyclopentadienyliron Carbonyl Tetramer: A Novel Route to a “Triple-decker” Sandwich Ion, Chem. Comm. 1969, 436–437.

    Google Scholar 

  12. J. W. Lauher, M. Elian, R. H. Summerville, and R. Hoffmann, Triple-Decker Sandwiches, J. Am. Chem. Soc. 98, 3219–3224 (1976).

    Article  CAS  Google Scholar 

  13. A. R. Kudinov, M. I. Rybinskaya, Yu. T. Struchkov, A. I. Yanovskii, and P. V. Petrovskii, Synthesis of the First 30-Electron Triple-Decker Complexes of the Iron Group Metals with Cyclopentadienyl Ligands. X-Ray Structure of [(η-C5H5)Ru (μ,η-C5Me5)Ru(η-C5Me5)]PF6, J. Organomet. Chem. 336, 187–197 (1987).

    Article  CAS  Google Scholar 

  14. A. R. Kudinov, A. A. Filchikov, and M. I. Rybinskaya, Deprotonation and Subsequent Functionalization of Methyl Groups in Cationic Ruthenium Triple-Decker Complexes, Mendeleev Comm. 1992, 64–65.

    Google Scholar 

  15. G. E. Herberich, U. Englert, F. Marken, and P. Hofmann, Triple-Decker Complexes with Bridging Cyclopentadienyl Ligands and Novel Cyclopentadienyl Transfer Reactions, Organometallics 12, 4039–4045 (1993).

    Article  CAS  Google Scholar 

  16. A. R. Kudinov, A. A. Filchikov, P. V. Petrovskii, and M. I. Rybinskaya, 30-Electron Cationic Iron- and Cobalt-containing Triple-Decker Complexes with a Central Cyclopentadienyl Ligand. The First Synthesis of the Parent Triple-Decker Iron Complex with Cyclopentadienyl Ligands, [(η5-C5H5)Fe(μ-η:η-C5H5)Fe(η5-C5H5)]PF6, Russ. Chem. Bull. 48, 1352–1355 (1999).

    Article  CAS  Google Scholar 

  17. A. R. Kudinov, and M. I. Rybinskaya, New Triple-Decker Complexes Prepared by the Stacking Reactions of Cationic Metallofragments with Sandwich Compounds, Russ. Chem. Bull. 48, 1615–1621 (1999).

    Article  CAS  Google Scholar 

  18. A. H. Cowley, C. L. B. Macdonald, J. S. Silverman, J. D. Gorden, and A. Voigt, Triple-Decker Main Group Cations, Chem. Comm. 2001, 175–176.

    Google Scholar 

  19. A. W. Duff, K. Jonas, R. Goddard, H.-J. Kraus, and C. Krüger, The First Triple-Decker Sandwich with a Bridging Benzene Ring, J. Am. Chem. Soc. 105, 5479–5480 (1983).

    Article  CAS  Google Scholar 

  20. W. M. Lamanna, Metal Vapor Synthesis of a Novel Triple-Decker Sandwich Complex: (η6-Mesitylene)2(μ-η6:η6-mesitylene)Cr2, J. Am. Chem. Soc. 108, 2096–2097 (1986).

    Article  CAS  Google Scholar 

  21. F. N. Cloke, K. A. E. Courtney, A. A. Sameh, and A. C. Swain, Bis(η-arene) Complexes of the Early Transition Metals Derived From the 1,3,5-Tri-t-butylbenzene Ligand, Polyhedron 8, 1641–1648 (1989).

    Article  CAS  Google Scholar 

  22. J. L. Priego, L. H. Doerrer, L. H. Rees, and M. L. H. Green, Weakly Coordinating Anions Stabilise the Unprecedented Monovalent and Divalent η-Benzene Nickel Cations [(η5-C5H5)Ni(η6-C6H6)Ni(η5-C5H5)]2+ and [Ni(η6-C6H6)2]2+, Chem. Comm. 2000, 779–780.

    Google Scholar 

  23. V. Beck, and D. O’Hare, Triple-Decker Transition Metal Complexes Bridged by a Single Carbocyclic Ring, J. Organomet. Chem. 689, 3920–3938 (2004).

    Article  CAS  Google Scholar 

  24. W. J. Evans, M. A. Johnston, M. A. Greci, and J. W. Ziller, Synthesis, Structure, and Reactivity of Unsolvated Triple-Decked Bent Metallocenes of Divalent Europium and Ytterbium, Organometallics 18, 1460–1464 (1999).

    Article  CAS  Google Scholar 

  25. H. Sitzmann, M. D. Walter, and G. Wolmershäuser, A Triple-Decker Sandwich Complex of Barium, Angew. Chem. Int. Ed. 41, 2421–2422 (2002).

    Google Scholar 

  26. D. C. Beer, V. R. Miller, L. G. Sneddon, R. N. Grimes, M. Mathew, and G. J. Palenik, Triple-Decked Sandwich Compounds. Planar C2B3H5 4– Cyclocarborane Ligands Analogous to C5H5 –, J. Am. Chem. Soc. 95, 3046–3048 (1973).

    Article  CAS  Google Scholar 

  27. R. N. Grimes, Small Carboranes as Building Blocks in Designed Organometallic Synthesis, Pure Appl. Chem. 63, 369–372 (1991).

    Article  CAS  Google Scholar 

  28. W. Siebert, Boron Heterocycles as Ligands in Transition-Metal Chemistry, Adv. Organomet. Chem. 18, 301–340 (1980).

    Article  CAS  Google Scholar 

  29. W. Siebert, 2,3-Dihydro-1,3-diborole-metal Complexes with Activated Carbon-Hydrogen Bonds. Building Blocks for Multilayer Sandwich Compounds, Angew. Chem. Int. Ed. Engl. 24, 943–958 (1985).

    Article  Google Scholar 

  30. G. E. Herberich, B. Hessner, W. Boveleth, H. Lüthe, R. Saive, and L. Zelenka, A Novel and General Route to (η5-Borole)metal Complexes: Compounds of Manganese, Ruthenium, and Rhodium, Angew. Chem. Int. Ed. Engl. 22, 996 (1983).

    Article  Google Scholar 

  31. W. Siebert, T. Renk, K. Kirnberger, M. Bochmann, and C. Krüger, μ-Thiadiborolenebis (η-cyclopentadienyliron) – Preparation and Structure of a New Triple-Decker Sandwich, Angew. Chem. Int. Ed. Engl. 15, 779–780 (1976).

    Article  Google Scholar 

  32. G. E. Herberich, and B. Ganter, Synthesis of the First Triple-Decker Complexes with a Bridging Phospholyl Ligand. Structures of the Triple-Decker Complex [(μ-C4Me4P)-{Fe(C5Me4CH2C6H11)}(RuCp*)]CF3SO3⋅ and the Related Sandwich Complex Fe(C4Me4P)(C5Me4CH2C6H11), Organometallics 16, 522–524 (1997).

    Article  CAS  Google Scholar 

  33. P. B. Hitchcock, J. A. Johnson, and J. F. Nixon, Syntheses and Structures of Diruthenium Triple-Decker Complexes with Bridging 1,2,4-Triphospholyl and 1-Arsa-3,4-Diphospholyl Anions, Organometallics 14, 4382–4389 (1995).

    Article  CAS  Google Scholar 

  34. G. E. Herberich, U. Englert, and D. Pubanz, Der Boratabenzol-Ring als Brückenligand in Tripeldeckerkomplexen. Synthese und Struktur von [(μ,η6,η6-C5H5BMe)(RuCp*)2]CF3SO3⋅0.5CH2Cl2 und Übertragung eines Boratabenzolrings von einem RuCp*-Fragment auf ein RhCp*-Fragment, J. Organomet. Chem. 459, 1–9 (1993).

    Article  CAS  Google Scholar 

  35. G. E. Herberich, B. Hessner, G. Huttner, and L. Zsolnai, A Triple-Decker Sandwich Complex of Rhodium with Diborabenzene as the Bridging Ligand, Angew. Chem. Int. Ed. Engl. 20, 472–473 (1981).

    Article  Google Scholar 

  36. G. E. Herberich, U. Büschges, B. Hessner, and H. Lüthe, (η5-Borol)rhodium-Komplexe und Nucleophiler Abbau von μ-(η5-1-Phenylborol)-bis[(η5-1-phenylborol)rhodium], J. Organomet. Chem. 312, 13–25 (1986).

    Article  CAS  Google Scholar 

  37. G. E. Herberich, B. A. Dunne, and B. Hessner, Triple-Decker Complexes as Intermediates in Ring Ligand Transfers, Angew. Chem. Int. Ed. Engl. 28, 737–738 (1989).

    Article  Google Scholar 

  38. D. A. Loginov, D. V. Muratov, P. V. Petrovskii, Z. A. Starikova, M. Corsini, F. Laschi, F. de Biani Fabrizi, P. Zanello, and A. R. Kudinov, Reactions of the B-Phenylborole Complex [CpRh(η5-C4H4BPh)] with Metalloelectrophiles [(ring)M]2+, Eur. J. Inorg. Chem. 2005, 1737–1746.

    Google Scholar 

  39. K. B. Dillon, F. Mathey, and J. F. Nixon, Phosphorus: The Carbon Copy, (Wiley, New York, 1998).

    Google Scholar 

  40. O. J. Scherer, Complexes with Substituent-free Acyclic and Cyclic Phosphorus, Arsenic, Antimony, and Bismuth Ligands, Angew. Chem. Int. Ed. Engl. 29, 1104–1122 (1990).

    Article  Google Scholar 

  41. O. J. Scherer, Pn and Asn Ligands: A Novel Chapter in the Chemistry of Phosphorus and Arsenic, Acc. Chem. Res. 32, 751–762 (1999).

    Article  CAS  Google Scholar 

  42. H. J. Breunig, N. Burford, and R. Rösler, Stabilization of a Pentastibacyclopentadienyl Ligand in the Triple-Decker Sandwich Complexes [{(η5-1,2,4-tBu3C5H2)Mo}2(μ,η5-Sb5)] and [(η5-1,2,4-tBu3C5H2)Mo(μ,η5-Sb5)Mo(η5-1,4-tBu2-2-MeC5H2)], Angew. Chem. Int. Ed. 39, 4148–4150 (2000).

    CAS  Google Scholar 

  43. M. Baudler, D. Düster, and D. Ouzounis, Existenz und Charakterisierung des Pentaphosphacyclopentadienid-Anions P5 –, des Tetraphosphacyclopentadienid-Ions P4CH–, und des Triphosphacyclobutadienid-Ions P3CH2 –, Z. anorg. allg. Chem. 544, 87–94 (1987).

    Article  CAS  Google Scholar 

  44. T. Kuhlmann, S. Roth, J. Roziere, and W. Siebert, Polymeric (η5,μ-2,3-Dihydro-1,3-diborolyl)nickel, the First Multilayer Sandwich Compound, Angew. Chem. Int. Ed. Engl. 25, 105–106 (1986).

    Article  Google Scholar 

  45. E. D. Jemmis, and A. C. Reddy, Electronic Structure and Bonding in Tetradecker Sandwich Complexes, J. Am. Chem. Soc. 112, 722–727 (1990).

    Article  CAS  Google Scholar 

  46. A. Edelmann, S. Blaurock, V. Lorenz, L. Hilfert, and F. T. Edelmann, Angew. Chem. Int. Ed. 46, 6732–6734 (2007).

    Article  CAS  Google Scholar 

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  1. University of Würzburg, Germany

    Helmut Werner (Prof.Dr)

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Werner, H. (2009). One Deck More: The Chemical “Big Mac”. In: Landmarks in Organo-Transition Metal Chemistry. Profiles in Inorganic Chemistry. Springer, New York, NY. https://doi.org/10.1007/978-0-387-09848-7_6

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