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Synthetic Approaches to 1,2-Heteraphosphacyclanes

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Phosphorous Heterocycles I

Part of the book series: Topics in Heterocyclic Chemistry ((TOPICS,volume 20))

Abstract

1,2-Heteraphosphacyclanes have drawn the attention of synthetic chemists due to their association with various biological activities and their unusual properties. The focus of this chapter is on the synthetic approaches to heterocyclic compounds of this type, which are principally different from the compounds with three-membered, four-membered and larger ring size and differ greatly depending on the nature of the heteroatom in the ring.

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Notes

  1. 1.

    Chloroalkyl-substituted thiophosphinates and thiophosphonates are thermally stable and represent easily distilled liquids (b.p. = 105–165 °C/2–3 Hg). 3-Chloropropyl(phenyl)thiophosphinate (R = Ph, n = 3), which undergoes the intramolecular thione–thiol rearrangement into 2-oxo-2-phenyl-1,2-thiaphospholane under distillation in vacuo, is the only exception.

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Authors and Affiliations

  1. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Vavilova str. 28, Moscow, 119991, Russian Federation

    Irina L. Odinets & Inga M. Aladzheva

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  1. Irina L. Odinets
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  2. Inga M. Aladzheva
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Correspondence to Irina L. Odinets .

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  1. Dept. Chemistry, University of Rajasthan, Jaipur, 302004, India

    Raj K. Bansal

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Odinets, I.L., Aladzheva, I.M. (2009). Synthetic Approaches to 1,2-Heteraphosphacyclanes. In: Bansal, R. (eds) Phosphorous Heterocycles I. Topics in Heterocyclic Chemistry, vol 20. Springer, Berlin, Heidelberg. https://doi.org/10.1007/7081_2008_13

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