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Release of Additives and Monomers from Plastic Wastes

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Hazardous Chemicals Associated with Plastics in the Marine Environment

Part of the book series: The Handbook of Environmental Chemistry ((HEC,volume 78))

Abstract

Additives and monomers are integral components of plastics or polymers. Bisphenol A (BPA), nonylphenol (NP), and polybrominated diphenyl ethers (PBDEs) are the common monomer and additives used primarily to improve the quality of plastic materials. They are used as antioxidants, stabilizers, plasticizers, and flame retardants in plastics that are in turn used in the manufacture of a wide range of consumer and industrial products. In this chapter, the release of BPA, NP, and PBDEs from waste plastic materials is presented. A brief background of the physical and chemical characteristics of BPA, NP, and PBDEs, and other factors that influence the release of these monomer and additives from plastics, is also discussed. The overview of the consequential occurrence of these compounds in leachates from landfills and/or municipal solid waste (MSW) dumping sites provides evidence on the release of BPA, NP, and PBDEs from dumped plastic materials.

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References

  1. Teuten EL, Saquing JM, Knappe DRU, Barlaz MA, Jonsson S, Björn A, Rowland SJ, Thompson RC, Galloway TS, Yamashita R, Ochi D, Watanuki Y, Moore C, Viet PH, Tana TS, Prudente M, Boonyatumanond R, Zakaria MP, Akkhavong K, Ogata Y, Hirai H, Iwasa S, Mizukawa K, Hagino Y, Imamura A, Saha M, Takada H (2009) Transport and release of chemicals from plastics to the environment and to wildlife. Phil Trans R Soc B 364:2027–2045

    CAS  Google Scholar 

  2. Halden RU (2010) Plastic and health risks. Annu Rev Pub Health 31:179–194

    Google Scholar 

  3. King JAJ (2000) Synthesis of polycarbonates. In: LeGrand DG, Bendler GT (eds) Handbook of polycarbonate science and technology. Marcel Dekker Inc., New York, pp. 7–13 Available https://books.google.com.ph/books. Accessed 10 Oct 2015

    Google Scholar 

  4. Datla V, Shim E, Pourdeyhimi B (2012) Surface modifications of polypropylene with nonylphenol ethoxylates melt additives. Polym Eng Sci 52(9):1920–1927

    CAS  Google Scholar 

  5. Zhang Q-X, Song J-B, Wang S-Y, Mo Z-S (2005) Effect of polyoxyethylene nonylphenol on dynamic mechanical properties and crystallization of polypropylene. Polymer 46:11820–11828

    CAS  Google Scholar 

  6. Baun A, Ledin A, Reitzel LA, Bjerg PL, Christensen TH (2004) Xenobiotic organic compounds in leachates from ten Danish MSW landfills–chemical analysis and toxicity tests. Water Res 38:3845–3858

    CAS  Google Scholar 

  7. Bromine Science Environmental Forum (2013). Available http://www.bsef.com. Accessed 26 Oct 2013, 27 Jan 2016

  8. Hale R, La Guardia MJ, Harvey E, Mainor TM (2002) Potential role of fire retardant-treated polyurethane foam as a source of brominated diphenyl ethers to the US environment. Chemosphere 46(5):729–735

    CAS  Google Scholar 

  9. Hardy ML (2002) A comparison of the properties of the major commercial PBDPO/ PBDE product to those of major PBB and PCB products. Chemosphere 46(5):717–728

    CAS  Google Scholar 

  10. Stockholm Convention (Secretariat of the Stockholm Convention), 2009. The new POPs. Available http://chm.pops.int/Convention/ThePOPs/TheNewPOPs/tabid/2511/Default.aspx. Accessed 23 Jan 2012

  11. OECD Environment Directorate (1994) Risk reduction monograph No. 3: selected brominated flame retardants–background and national experience of reducing risk. Available http://www.oecd.org. Accessed 12 Nov 2012

  12. Rahman F, Langford KH, Scrimshaw MD, Lester JN (2001) Polybrominated diphenyl ether (PBDE) flame retardants. Sci Total Environ 275:1–17

    CAS  Google Scholar 

  13. de Wit CA (2002) An overview of brominated flame retardants in the environment. Chemosphere 46(5):583–624

    Google Scholar 

  14. Alaee M, Arias P, Sjödin A, Bergman Å (2003) An overview of commercially used brominated flame retardants, their applications, their use patterns in different countries/regions and possible modes of release. Environ Int 29(6):683–689

    CAS  Google Scholar 

  15. Feenstra L (2009) An inventory and assessment of options for reducing emissions: nonylphenols. Available www.socopse.se/download/18.3cd20f1b1243376c1168000577/1350483854313/SR+Nonylphenols.pdf. Accessed 20 Oct 2015

  16. Darnerud PO (2003) Toxic effects of brominated flame retardants in man and in wildlife. Environ Int 29(6):841–853

    CAS  Google Scholar 

  17. Slack RJ, Gronow JR, Voulvoulis N (2005) Household hazardous waste in municipal landfills: contaminants in leachate. Sci Total Environ 337:119–137

    CAS  Google Scholar 

  18. Bertanza G, Pedrazzani R (2008) Presence of EDCs (endocrine disrupting compounds) in landfill leachate and municipal wastewaters. In: Pawlowska M, Pawloski L (eds) Management of pollutant emission from landfills and sludge. Taylor & Francis/Balkema, Leiden, pp. 75–81

    Google Scholar 

  19. Cousins IT, Staples CA, Klĕcka GM, Mackay D (2002) A multimedia assessment of the environmental fate of bisphenol A. Hum Ecol Risk Assess 8(5):1107–1135

    Google Scholar 

  20. Asakura H, Matsuto T, Tanaka N (2004) Behavior of endocrine-disrupting chemicals in leachate from MSW landfill sites in Japan. Waste Manage 24:613–622

    CAS  Google Scholar 

  21. Watanabe I, Tatsukawa R (1990) Anthropogenic brominated aromatics in the Japanese environment. In: Freiji L (ed) Proceedings of workshop on brominated flame retardants. Swedish National Chemicals Inspectorate (KemI), Skokloster, pp. 63–71

    Google Scholar 

  22. Hites RA (2004) Polybrominated diphenyl ethers in the environment and in people: A meta-analysis of concentrations. Environ Sci Technol 38(4):945–956

    CAS  Google Scholar 

  23. Ross PS, Couillard CM, Ikonomou MG, Johannessen SC, Lebeuf M, Macdonald RW, Tomy GT (2009) Large and growing environmental reservoirs of deca-BDE present an emerging health risk for fish and marine mammals. Mar Pollut Bull 58(1):7–10

    CAS  Google Scholar 

  24. Osako M, Kim Y-J, Sakai S (2004) Leaching of brominated flame retardants in leachate from landfills in Japan. Chemosphere 57:1571–1579

    CAS  Google Scholar 

  25. Ogbobe O (1985) Dispersion of additive masterbatches in polyolefin plastics. Dissertation, Loughborough University of Technology, Loughborough

    Google Scholar 

  26. Kim Y-J, Osako M, Sakai S (2006) Leaching characteristics of polybrominated diphenyl ethers (PBDEs) from flame-retardant plastics. Chemosphere 65:506–513

    CAS  Google Scholar 

  27. Li X, Ying G, Su H-C, Yang X-B, Wang L (2010) Simultaneous determination and assessment of 4-nonylphenol, bisphenol A and triclosan in tap water, bottled water and baby bottles. Environ Int 36:557–562

    CAS  Google Scholar 

  28. Amiridou D, Voutsa D (2011) Alkylphenols and phthalates in bottled waters. J Mater 185(1):281–286

    CAS  Google Scholar 

  29. Vandenberg LN, Maffini MV, Sonnenschein C, Rubin BS, Soto AM (2009) Bisphenol-A and the great divide: a review of controversies in the field of endocrine disruption. Endocr Rev 30:75–95

    CAS  Google Scholar 

  30. Hopewell J, Dvorak R, Kosior E (2009) Plastics recycling: challenges and opportunities. Phil Trans R Soc London Ser B 364:2115–2126

    CAS  Google Scholar 

  31. Hoornweg D, Bhada-Tata P (2012) What a waste—a global review of solid waste management. Urban development series knowledge papers. Available www.sitesources.worldbank.org/INTURBANDEVELOPMENT/Resources/336387-1334852610766/What_a_Waste2012_Final.pdf. Accessed 23 Jan 2015

  32. Takada H (2013) International pellet watch studies of the magnitude and spatial variation of chemical risks associated with environmental plastics. In: Gabrys J, Hawkins G, Michael M (eds) Accumulation – The material politics of plastics. Routledge, London, pp. 201–205

    Google Scholar 

  33. Kjeldsen P, Barlaz MA, Rooker AP, Baun A, Ledin A, Christensen TH (2002) Present and long-term composition of MSW landfill leachate: a review. Crit Rev Environ Sci Technol 32(4):297–336

    CAS  Google Scholar 

  34. Masoner JR, Kolpin DW, Furlong ET, Cozzarelli IM, Gray JL, Schwab EA (2014) Contaminants of emerging concern in fresh leachate from landfills in the conterminous United States. Environ Sci Processes Impacts 16:2335–2354

    CAS  Google Scholar 

  35. Kalmykova Y, Björklund K, Strömvall A-M, Blom L (2013) Partitioning of polycyclic aromatic hydrocarbons, alkyphenols, bisphenol A and phthalates in landfill leachates and stormwater. Water Res 47:1317–1328

    CAS  Google Scholar 

  36. Kalmykova Y, Moona N, Strömvall A-M, Björklund K (2014) Sorption and degradation of petroleum hydrocarbons, polycyclic aromatic hydrdocarbons, alkylphenols, bisphenol A and phthalates in landfill leachate using sand, activated carbon and peat filters. Water Res 56:246–257

    CAS  Google Scholar 

  37. Kwan CS, Takada H, Mizukawa K, Yamashita R, Torii M, Koike T, Saha M, Rinawati (2013) PBDEs in leachates from municipal solid waste dumping sites in tropical Asian countries: phase distribution and debromination. Environ Sci Pollut Res 20:4188–4204

    Google Scholar 

  38. Kurata Y, Ono Y, Ono Y (2008) Occurrence of phenols in leachates from municipal solid waste landfill sites in Japan. J Mater Cycles Waste Manage 10:144–152

    CAS  Google Scholar 

  39. Gerecke AC, Hartmann PC, Heeb NV, Kohler H-PE Giger W, Schmid P, Zennegg M, Kohler M (2005) Anaerobic degradation of decabromodiphenyl ether. Environ Sci Technol 39(4):1078–1083

    CAS  Google Scholar 

  40. Robrock KR, Korytár P, Alvarez-Cohen L (2008) Pathways for the anaerobic microbial debromination of polybrominated diphenyl ethers. Environ Sci Technol 42(8):2845–2852

    CAS  Google Scholar 

  41. Tokarz JA, Ahn M-Y, Leng J, Filey TR, Nies L (2008) Reductive debromination of polybrominated diphenyl ethers in anaerobic sediment and a biomimetic system. Environ Sci Technol 42(4):1157–1164

    CAS  Google Scholar 

  42. Mizukawa K, Takada H, Takeuchi I, Ikemoto T, Omori K, Tsuchiya K (2009) Bioconcentration and biomagnification of polybrominated diphenyl ethers (PBDEs) through lower-trophic-level coastal marine food web. Mar Pollut Bull 58:1217–1224

    CAS  Google Scholar 

  43. Canadian Ministry of Environment and Energy (1994) Policies guidelines provincial water quality objectives–Ontario. P1BS 33 03E

    Google Scholar 

  44. Yasuhara A, Shiraishi H, Nishikawa M, Yamamoto T, Uehiro T, Nakasugi O, Okumura T, Kenmotsu K, Fukui H, Nagase M, Ono Y, Kawagoshi Y, Baba K, Noma Y (1997) Determination of organic components in leachates from hazardous waste disposal sites in Japan by gas chromatography/mass spectrometry. J Chromatogr A 774:321–332

    Google Scholar 

  45. Yasuhara A, Shiraishi H, Nishikawa M, Yamamoto T, Nakasugi O, Okumura T, Kenmotsu K, Fukui H, Nagase M, Kawagoshi Y (1999) Organic components in leachates from hazardous waste disposal sites. Waste Manage Res 17:186–197

    CAS  Google Scholar 

  46. Yamamoto T, Yasuhara A, Shiraishi H, Nakasugi O (2001) Bisphenol A in hazardous waste landfill leachates. Chemosphere 42:415–418

    CAS  Google Scholar 

  47. Fromme H, Kuchler T, Otto T, Pilz K, Muller J, Wenzel A (2002) Occurrence of phthalates and bisphenol A and F in the environment. Water Res 36:1429–1438

    CAS  Google Scholar 

  48. EC (2013) Directive 2013/39/EU of the European Parliament and of the Council of 12 August 2013 amending Directive 2000/60/EC and 2008/105/EC as regards priority substances in the field of water policy. Official Journal of the European Union 24.8.2013 L226/1

    Google Scholar 

  49. Coors A, Jones PD, Giesy JP, Ratte HT (2003) Removal of estrogenic activity from municipal waste landfill leachate assessed with a bioassay based on reporter gene expression. Environ Sci Technol 37:3430–3434

    CAS  Google Scholar 

  50. Sajiki J, Yonekubo J (2004) Leaching of bisphenol A (BPA) from polycarbonate plastic to water containing amino acids and its degradation by radical oxygen species. Chemosphere 55(6):861–867

    CAS  Google Scholar 

  51. La Guardia MJ, Hale RC, Harvey E (2006) Detailed polybrominated diphenyl ether (PBDE) congener composition of the widely used penta-, octa-, and deca-PBDE technical flame-retardant mixtures. Environ Sci Technol 40(20):6247–6254

    CAS  Google Scholar 

  52. Oliaei F, King P, Phillips L (2002) Polybrominated flame retardants: occurrence and concentrations of polybrominated diphenyl ethers (PBDEs) in Minnesota environment. Organohalogen Compd 58:185–188

    CAS  Google Scholar 

  53. Danon-Schaffer M (2010) Polybrominated diphenyl ethers in landfills from electronic waste. Dissertation, University of British Columbia, Vancouver

    Google Scholar 

  54. Li B, Danon-Schaffer MN, Li LY, Ikonomou MG, Grace JR (2012) Occurrence of PFCs and PBDEs in landfill leachates from across Canada. Water Air Soil Pollut 223:3365–3372

    CAS  Google Scholar 

  55. Öman CB, Junestedt C (2008) Chemical characterization of landfill leachates–400 parameters and compounds. Waste Manage 28:1876–1891

    Google Scholar 

  56. Ilyas M, Sudaryanto A, Setiawan IT, Isobe T, Takahashi S, Tanabe S (2011) Characterization of polychlorinated biphenyls and brominated flame retardants in sediments from riverine and coastal waters of Surabaya, Indonesia. Mar Pollut Bull 62:89–98

    CAS  Google Scholar 

  57. Odusanya DO, Okonkwo JO, Botha B (2009) Polybrominated diphenyl ethers (PBDEs) in leachates from selected landfill sites in South Africa. Waste Manage 29:96–102

    CAS  Google Scholar 

  58. Daso AP, Fatoki OS, Odendaal JP, Olujimi OO (2013) Polybrominated diphenyl ethers (PBDEs) and 2,2′,4,4′,5,5′-hexabromobiphenyl (BB-153) in landfill leachate in Cape Town, South Africa. Environ Monit Assess 185:431–439

    CAS  Google Scholar 

  59. Ehrig H-J (1989) Water and element balances of landfills. In: Baccini P (ed) The landfill–lecture notes in earth sciences. Springer-Verlag, Berlin, pp. 83–115

    Google Scholar 

  60. Fang L, Huang J, Yu G, Wang L (2008) Photochemical degradation of six polybrominated diphenyl ether congeners under ultraviolet irradiation in hexane. Chemosphere 71:258–267

    CAS  Google Scholar 

  61. Christiansson A, Eriksson J, Teclechiel D, Bergman Å (2009) Identification and quantification of products formed via photolysis of decabromdiphenyl ether. Environ Sci Pollut Res 16(3):312–321

    CAS  Google Scholar 

  62. Kajiwara N, Noma Y, Takigami H (2008) Photolysis studies of technical decabromodiphenyl ether (DecaBDE) and ethane (DeBDethane) in plastics under natural sunlight. Environ Sci Technol 42(12):4404–4409

    CAS  Google Scholar 

  63. Stapleton HM, Dodder NG (2008) Photodegradation of decabromodiphenyl ether in house dust by natural sunlight. Environ Toxicol Chem 27:306–312

    CAS  Google Scholar 

  64. Ngoc UN, Schnitzer H (2009) Sustainable solutions for solid waste management in Southeast Asian countries. Waste Manage 29(6):1982–1995

    Google Scholar 

  65. Bożyk P (2006) Globalization and the transformation of foreign economic policy–(transition and development). Ashgate Publishing Ltd., Hampshire

    Google Scholar 

  66. United Nations Department of Economic and Social Affairs. (2010) World population prospects: The 2010 revision, CD-ROM edn. Population Division. Available http://esa.un.org/wpp/Excel-Data/population.htm. Accessed 24 April 2012

  67. United Nations Environmental Program (2007) E-waste volume 1: inventory assessment manual. Division of Technology, Industry and Economics, International Environmental Technology Centre. Available http://www.umep.or.jp/ietc/Publications/spc/EwasteManual_Vol1.pdf. Accessed 25 Oct 2013

  68. Basel Convention – Control of transboundary movements of hazardous wastes and their disposal. Available at http://www.basel.int/theconvention/overview/tabid/1271/default.aspx. Accessed 18 Jan 2016

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Correspondence to Charita S. Kwan .

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Kwan, C.S., Takada, H. (2016). Release of Additives and Monomers from Plastic Wastes. In: Takada, H., Karapanagioti, H.K. (eds) Hazardous Chemicals Associated with Plastics in the Marine Environment. The Handbook of Environmental Chemistry, vol 78. Springer, Cham. https://doi.org/10.1007/698_2016_122

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