Abstract
The present chapter provides a general perspective on the occurrence, ecotoxicological risk, and prioritization of emerging and classical contaminants in Mediterranean river basins with special focus on the Iberian Peninsula as representative case, in the light of the results recently obtained. Risk assessment and prioritization criteria based on ecotoxicological risk with respect to different trophic levels are explained and applied to the Mediterranean basins studied. This enables to rank contaminants according to their ecotoxic risk and to quantify their joint effect as a mixture on a river site.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
Vörösmarty CJ, McIntyre PB, Gessner MO, Dudgeon D, Prusevich A, Green P, Glidden S, Bunn SE, Sullivan CA, Liermann CR et al (2010) Global threats to human water security and river biodiversity. Nature 467:555–561
Schwarzenbach RP, Escher BI, Fenner K, Hofstetter TB, Johnson CA, Von Gunten U, Wehrli B (2006) The challenge of micropollutants in aquatic systems. Science 313:1072–1077
Jackson RB, Carpenter SR, Dahm CN, McKnight DM, Naiman RJ, Postel SL, Running SW (2001) Water in a changing world. Ecol Appl 11:1027–1045
Guillén D, Ginebreda A, Farré M, Darbra RM, Petrovic M, Gros M, Barceló D (2012) Prioritization of chemicals in the aquatic environment based on risk assessment: analytical, modeling and regulatory perspective. Sci Total Environ 440:236–252
European Commission (2008) Directive 2008/105/EC of the European Parliament and of the council of 16 December 2008 on environmental quality standards in the field of water policy, amending and subsequently repealing Council Directives 82/176/EEC, 83/513/EEC, 84/156/EEC, 84/491/EEC, 86/280/EEC and amending Directive 2000/60/EC (European Parliament and of the Council), pp 84–97
Daughton CG, Ternes TA (1999) Pharmaceuticals and personal care products in the environment: agents of subtle change? Environ Health Perspect 107:907–938
Murray KE, Thomas SM, Bodour AA (2010) Prioritizing research for trace pollutants and emerging contaminants in the freshwater environment. Environ Pollut 158:3462–3471
Petrovic M, Ginebreda A, Acuna V, Batalla RJ, Elosegi A, Guasch H, Lopez de Alda M, Marce R, Munoz I, Navarro-Ortega A et al (2011) Combined scenarios of chemical and ecological quality under water scarcity in Mediterranean rivers. Trends Anal Chem 30:1269–1278
Boxall ABA, Kolpin DW, Halling-Sørensen B, Tolls J (2003) Are veterinary medicines causing environmental risks? Environ Sci Tech 37:286A–294A
von der Ohe PC, Dulio V, Slobodnik J, De Deckere E, Kuehne R, Ebert R-U, Ginebreda A, De Cooman W, Schueuermann G, Brack W (2011) A new risk assessment approach for the prioritization of 500 classical and emerging organic microcontaminants as potential river basin specific pollutants under the European Water Framework Directive. Sci Total Environ 409:2064–2077
European Commission (2000) Directive 2000/60/EC of the European Parliament and of the Council of 23 October 2000 establishing a framework for Community action in the field of water policy
Navarro-Ortega A, Acuña V, Batalla RJ, Blasco J, Conde C, Elorza FJ, Elosegi A, Francés F, La-Roca F, Muñoz I et al (2012) Assessing and forecasting the impacts of global change on Mediterranean rivers. The SCARCE Consolider project on Iberian basins. Environ Sci Pollut Res 19:918–933
Masiá A, Ibáñez M, Blasco C, Sancho JV, Picó Y, Hernández F (2013) Combined use of liquid chromatography triple quadrupole mass spectrometry and liquid chromatography quadrupole time-of-flight mass spectrometry in systematic screening of pesticides and other contaminants in water samples. Anal Chim Acta 761:117–127
Gorga M, Insa S, Petrovic M, Barceló D (2014) Occurrence and spatial distribution of EDCs and related compounds in waters and sediments of Iberian rivers. Sci Total Environ 503–504:69–86
Osorio V, Proia L, Ricart M, Pérez S, Ginebreda A, Cortina JL, Sabater S, Barceló D (2014) Hydrological variation modulates pharmaceutical levels and biofilm responses in a Mediterranean river. Sci Total Environ 472:1052–1061
Gago-Ferrero P, Mastroianni N, Díaz-Cruz MS, Barceló D (2013) Fully automated determination of nine ultraviolet filters and transformation products in natural waters and wastewaters by on-line solid phase extraction-liquid chromatography-tandem mass spectrometry. J Chromatogr A 1294:106–116
Mastroianni N, Postigo C, De Alda ML, Barcelo D (2013) Illicit and abused drugs in sewage sludge: method optimization and occurrence. J Chromatogr A 1322:29–37
Sabater S, Ginebreda A, Barceló D (2012) The Llobregat: the story of a polluted Mediterranean River, The handbook of environmental chemistry. Springer, Berlin, pp 1–26
Kuzmanović M, Ginebreda A, Petrović M, Barceló D (2015) Risk assessment based prioritization of 200 organic micropollutants in 4 Iberian rivers. Sci Total Environ 503–504:289–299
Kuzmanović M, López-Doval JC, De Castro-Català N, Guasch H, Muñoz I, Petrović M, Ginebreda A, Barceló D (2015) Ecotoxicological risk assessment of chemical pollution in four Iberian river basins and its relationship with the aquatic macroinvertebrate community status. Sci Total Environ. doi:10.1016/j.scitotenv.2015.06.112
Sprague JB (1970) Measurement of pollutant toxicity to fish, II-Utilizing and applying bioassay results. Water Res 4:3–32
PAN Pesticide Database. http://www.pesticideinfo.org/
ECHA Registered Substances. http://echa.europa.eu/information-on-chemicals/registered-substances
Di Toro DM, Zarba CS, Hansen DJ, Berry WJ, Swartz RC, Cowan CE, Pavlou SP, Allen HE, Thomas NA, Paquin PR (1991) Technical basis for establishing sediment quality criteria for nonionic organic chemicals using equilibrium partitioning. Environ Toxicol Chem 10:1541–1583
Schäfer RB, Pettigrove V, Rose G, Allinson G, Wightwick A, Von Der Ohe PC, Shimeta J, Kühne R, Kefford BJ (2011) Effects of pesticides monitored with three sampling methods in 24 sites on macroinvertebrates and microorganisms. Environ Sci Tech 45:1665–1672
Backhaus T, Faust M (2012) Predictive environmental risk assessment of chemical mixtures: a conceptual framework. Environ Sci Tech 46:2564–2573
Malaj E, Von Der Ohe PC, Grote M, Kühne R, Mondy CP, Usseglio-Polatera P, Brack W, Schäfer RB (2014) Organic chemicals jeopardize the health of freshwater ecosystems on the continental scale. Proc Natl Acad Sci U S A 111:9549–9554
Schäfer RB, Von Der Ohe PC, Kühne R, Schüürmann G, Liess M (2011) Occurrence and toxicity of 331 organic pollutants in large rivers of north Germany over a decade (1994 to 2004). Environ Sci Tech 45:6167–6174
Schäfer RB, Von Der Ohe PC, Rasmussen J, Kefford BJ, Beketov MA, Schulz R, Liess M (2012) Thresholds for the effects of pesticides on invertebrate communities and leaf breakdown in stream ecosystems. Environ Sci Tech 46:5134–5142
Van Wijngaarden RPA, Brock TCM, Van Den Brink PJ (2005) Threshold levels for effects of insecticides in freshwater ecosystems: a review. Ecotoxicology 14:355–380
Ahlers J, Riedhammer C, Vogliano M, Ebert RU, Kühne R, Schüürmann G (2006) Acute to chronic ratios in aquatic toxicity – variation across trophic levels and relationship with chemical structure. Environ Toxicol Chem 25:2937–2945
Heger W, Jung SJ, Martin S, Peter H (1995) Acute and prolonged toxicity to aquatic organisms of new and existing chemicals and pesticides. 1. Variability of the acute to prolonged ratio 2. Relation to logPow and Water Solubility. Chemosphere 31:2707–2726
Länge R, Hutchinson TH, Scholz N, Solbé J (1998) Analysis of the ECETOC Aquatic Toxicity (EAT) database. II – comparison of acute to chronic ratios for various aquatic organisms and chemical substances. Chemosphere 36:115–127
Beketov MA, Foit K, Schäfer RB, Schriever CA, Sacchi A, Capri E, Biggs J, Wells C, Liess M (2009) SPEAR indicates pesticide effects in streams – comparative use of species- and family-level biomonitoring data. Environ Pollut 157:1841–1848
Liess M, Von Der Ohe PC (2005) Analyzing effects of pesticides on invertebrate communities in streams. Environ Toxicol Chem 24:954–965
PPDB Management Team (2009) http://sitem.herts.ac.uk/aeru/footprint/index2.htm Accessible at 2009
USEPA (2008) ECOTOX 4.0 ecotoxicology database. http://cfpub.epa.gov/ecotox
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2015 Springer International Publishing Switzerland
About this chapter
Cite this chapter
Kuzmanovic, M., Ginebreda, A., Petrovic, M., Barceló, D. (2015). Contaminants of Emerging Concern in Mediterranean Watersheds. In: Petrovic, M., Sabater, S., Elosegi, A., Barceló, D. (eds) Emerging Contaminants in River Ecosystems. The Handbook of Environmental Chemistry, vol 46. Springer, Cham. https://doi.org/10.1007/698_2015_5016
Download citation
DOI: https://doi.org/10.1007/698_2015_5016
Published:
Publisher Name: Springer, Cham
Print ISBN: 978-3-319-29374-5
Online ISBN: 978-3-319-29376-9
eBook Packages: Earth and Environmental ScienceEarth and Environmental Science (R0)