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Potential Reuse of Chemical Sludge from Textile Dyeing Processes

  • S. PandeyEmail author
  • H. Patel
  • R. Johri
Chapter
Part of the The Handbook of Environmental Chemistry book series (HEC, volume 18)

Abstract

The textile industry plays a significant role in the Indian economy. The combined textile effluent from dyeing and printing clusters is treated in common effluent treatment plants (CETP) where the physicochemical treatment of the wastewater leads to the generation of chemical sludge in voluminous quantities. This sludge is considered a hazardous waste according to the Indian Hazardous Waste Management rules of 2008. Presently, the only option available to CETP operators for the disposal of this waste is a secure landfill, but this represents a costly option for them. The case study presented here attempts to find an environment-friendly and a cost-effective solution for the management of this chemical sludge. Sludge samples from various CETPs spread across the India were collected and they were physicochemically characterized; toxicity and microstructural aspects were also taken into consideration. To evaluate the suitability of the sludge as construction material, a solidification/stabilization (S/S) treatment of the chemical sludge was carried out using two binders: Ordinary Portland Cement (OPC) and Portland Pozzolona Cement (PPC). The evaluation of the solidified samples was carried out by considering their physical engineering properties, such as unconfined compressive strength and block density, and its chemical properties, such as leachability of heavy metals. A microstructural examination of the solidified samples was also performed using X-ray diffraction (XRD) and scanning electron microscopy (SEM). Characterization results revealed that the sludge samples were alkaline and had high electrical conductivity values. The concentration of heavy metals (Cr, Cu, Ni, Zn, Cd, and Pb) in the dried sludge, as well as in the leachate, was found to be less than that present in the prescribed limits (Indian Hazardous Waste Rules for sludge samples and US EPA limits for leachate). Oxides, such as SiO2, Al2O3, Fe2O3, MgO, and SO3, were present in a significant amount. Unconfined strength and block density data of the solidified blocks indicated that the chemical sludge had potential to be used as a construction material for different kinds of applications. The microstructural examination of the solidified samples indicated a modification of the cement patterns.

Keywords

Chemical sludge Compressive strength Leaching Sludge reuse Solidification Stabilization 

References

  1. 1.
    Misra V, Pandey SD (2005) Hazardous waste, impact on health and environment for development of better waste management strategies in future in India. Environ Int 31:417–431CrossRefGoogle Scholar
  2. 2.
    CPCB (2009) National inventory of hazardous waste generating industries & hazardous waste management system in India. http://www.indiaenvironmentportal.org.in/files/hazardous-waste_inventory_final_report_2009.pdf. Accessed 22 July 2009
  3. 3.
    Blackman WC Jr (1996) Basic hazardous waste management. CRC Press Lewis Publishers, Boca RatonGoogle Scholar
  4. 4.
    Idachaba MA, Nyavor K, Egiebor NO, Rogers RD (2001) Stability evaluation of a cement based waste form to microbially induced degradation. Waste Manag Res 19:284–291CrossRefGoogle Scholar
  5. 5.
    Soundararajan R (1990) An overview of present day immobilization technologies. J Hazard Mater 24:199–212CrossRefGoogle Scholar
  6. 6.
    Baker PG, Bishop PL (1997) Prediction of metal leaching rates from solidified/stabilized wastes using the shrinking unreacted core leaching procedure. J Hazard Mater 52:311–333CrossRefGoogle Scholar
  7. 7.
    Gervais C, Ouki SK (2002) Performance study of cementitious systems containing zeolite and silica fume: effects of four metal nitrates on the setting time, strength and leaching characteristics. J Hazard Mater B93:187–200CrossRefGoogle Scholar
  8. 8.
    Olmo IF, Chacon E, Irabien A (2001) Influence of lead, zinc, iron (III) and chromium (III) oxides on the setting time and strength development of Portland cement. Cement Conc Res 31:1213–1219CrossRefGoogle Scholar
  9. 9.
    Stegemann JA, Cote PL (1990) Summary of an investigation of test methods for solidified waste evaluation. Waste Manag 10:41–52CrossRefGoogle Scholar
  10. 10.
    Bishop PL (1988) Leaching of inorganic hazardous constituents from stabilized/solidified hazardous wastes. Hazard Waste Hazard Mater 5:129–143CrossRefGoogle Scholar
  11. 11.
    Hills CD, Pollard SJT (1997) The influence of interference effects on the mechanical, microstructural and fixation characteristics of cement-solidified hazardous waste form. J Hazard Mater 52:171–191CrossRefGoogle Scholar
  12. 12.
    Malviya R, Chaudhary R (2006) Study of treatment effectiveness of solidification/stabilization process for waste bearing heavy metals. J Mater Cycles Waste Manag 6:147–153CrossRefGoogle Scholar
  13. 13.
    Dutre V, Vandecasteele C (1996) An evaluation of the solidification/stabilization of industrial arsenic containing waste using extraction and semi-dynamic leach tests. Waste Manag 16:625–631CrossRefGoogle Scholar
  14. 14.
    Leist M, Casey RJ, Caridi D (2003) The fixation and leaching of cement stabilized arsenic. Waste Manag 23:353–359CrossRefGoogle Scholar
  15. 15.
    Singh TS, Pant KK (2006) Solidification/stabilization of arsenic containing solid wastes using Portland cement, fly ash and polymeric materials. J Hazard Mater B31:29–36CrossRefGoogle Scholar
  16. 16.
    Kundu S, Gupta AK (2008) Immobilization and leaching characteristics of arsenic from cement and/or lime solidified/stabilized spent adsorbent containing arsenic. J Hazard Mater 153:434–443CrossRefGoogle Scholar
  17. 17.
    Singhal A, Tiwari VK, Prakash S (2008) Characterisation of stainless steel pickling bath sludge its solidification/stabilization. Build Environ 43(6):1010–1015CrossRefGoogle Scholar
  18. 18.
    Asavapisit S, Chotklang D (2004) Solidification of electroplating sludge using alkali-pulverised fuel ash as cementitious binder. Cement Conc Res 34:349–353CrossRefGoogle Scholar
  19. 19.
    Sophia AC, Swaminathan K (2005) Assessment of the mechanical stability and chemical leachability of immobilized electroplating waste. Chemosphere 58:75–82CrossRefGoogle Scholar
  20. 20.
    Andres A, Velasco FM, Coz A, Ruiz C, Viguri JR, Irabien JA (2002) Treatment of foundry sludges by stabilization/solidification with cement and siliceous binders. Fresenius Environ Bull 11:849–853Google Scholar
  21. 21.
    Hamilton IE, Sammes NM (1999) Encapsulation of steel foundry bag house dusts in cement mortar. Cement Concr Res 29:55–61CrossRefGoogle Scholar
  22. 22.
    Skvara F, Kastanek F, Pavelkova I, Solcova O, Maleterova Y, Schneider P (2002) Solidification of waste steel foundry dust with Portland cement. J Hazard Mater B 89:67–81CrossRefGoogle Scholar
  23. 23.
    Fuessle RW, Taylor MA (2004) Long-term solidification/stabilization and toxicity characteristics leaching procedure for an electric arc furnace dust. J Environ Eng – ASCE 130:492–498CrossRefGoogle Scholar
  24. 24.
    Salihoglu G, Pinarli V, Salihoglu NK, Karaca G (2007) Properties of steel foundry electric arc furnace dust solidified/stabilized with Portland cement. J Environ Manage 85:190–197CrossRefGoogle Scholar
  25. 25.
    Yin CY, Ali WSW, Lim YP (2008) Oil palm ash as partial replacement of cement for solidkfikcation/ stabilisation of nickel hydroxide sludge. J Hazard Mater 150:413–418CrossRefGoogle Scholar
  26. 26.
    Montogomery DM, Sollars CJ, Perry R, Tariing SE, Barnes P, Henderson E (1991) Treatment of organic-contaminated industrial wastes using cement-based solidification/ stabilization – microstructural analysis of cement – organic interaction. Waste Manag Res 9:103–111Google Scholar
  27. 27.
    Athanasios KK, Voudrias EA (2007) Cement-based stabilization/solidification of oil refinery sludge: leaching behavior of alkanes and PAHs. J Hazard Mater 148:122–135CrossRefGoogle Scholar
  28. 28.
    Chan YM, Agamuthu P, Mahalingam R (2000) Solidification and stabilization of asbestos waste from an automobile brake manufacturing facility using cement. J Hazard Mater B77:209–226CrossRefGoogle Scholar
  29. 29.
    Shieh CS, Roethel FJ (1989) Physical and chemical behavior of stabilized sewage sludge blocks in sea water. Environ Sci Technol 23:121–125CrossRefGoogle Scholar
  30. 30.
    Bednarik V, Vondruska M, Sild M, Vondruska E (2000) Characterisation of products from fluidized-bed combustion of coal. J Air Waste Manag Assoc 50:1920–1926Google Scholar
  31. 31.
    Rouf MA, Hossain MD (2003) Effects of using arsenic-iron sludge in brick making. In: Fate of arsenic in the Environment, Proceedings of the BUET –UNU International Symposium, Dhaka, Bangladesh, February 5–6Google Scholar
  32. 32.
    Okuno N, Takahashi S (1997) Full scale application of manufacturing bricks from sewage. Water Sci Technol 36(11):243–250CrossRefGoogle Scholar
  33. 33.
    Wiebusch B, Seyfried CF (1997) Utilization of sewage sludge ashes in the brick and tile industry. Water Sci Technol 26(11):251–258Google Scholar
  34. 34.
    Bhatty JI, Reid KJ (1989) Moderate strength concrete from lightweight sludge ash aggregates. Cement Compos Lightweight Concrete 11:179–187CrossRefGoogle Scholar
  35. 35.
    Bhatty JI, Mallisci A, Iwasaki I, Reid KJ (1992) Sludge as pellets as coarse aggregates in concrete. Cement, Concrete and Aggregates, CCAGDP 14(1):55–61CrossRefGoogle Scholar
  36. 36.
    Correia VM, Stephenson T, Judd SJ (1994) Characterisation of textile wastewaters – a review. Environ Technol 15:917–929CrossRefGoogle Scholar
  37. 37.
    Ministry of Environment and Forests (MoEF) (2008–2009) Abatment of pollution. Ministry of Environment and Forests annual report 2008–2009. http://www.envfor.nic.in/report/0708/chap04.pdf. Accessed 26 July 2009
  38. 38.
    Ansari AA, Thakur BD (2001) Sludge management in textile industry; disposal, recycling and reuse of primary sludge. Asian Textil J 10:55Google Scholar
  39. 39.
    Balasubramanian J, Sabumon PC, Lazar UL, Ilangovan R (2005) Reuse of textile effluent treatment plant sludge in building materials. Waste Manag 26(1):22–28CrossRefGoogle Scholar
  40. 40.
    Baskar R, Meera Sheriffa Begum KM, Sundaram S (2006) Characterisation and reuse of textile effluent treatment plant waste sludge in clay bricks. J Univ Chem Technol Metallurgy 41(4):473–478Google Scholar
  41. 41.
    Bureau of Indian Standard (1987) Specification for 43-grade ordinary Portland cement IS 12269:1987. BIS, New DelhiGoogle Scholar
  42. 42.
    Bureau of Indian Standard (1991) Specification for Portland pozzolona cement Part I Flyash based (Third Revision) IS 1489: Part 1:1991. BIS, New DelhiGoogle Scholar
  43. 43.
    Bureau of Indian Standard (1980) Methods of physical test for hydraulic cement –determination of compressive strength of hydraulic cement IS 4031 (6). BIS, New DelhiGoogle Scholar
  44. 44.
    Bhalerao NA, Moghe CA, Bhavasar RS, Kharat RB (1997) Sludge management process – a review of its application to industrial sludges. Indian J Environ Prot 17(7):535–541Google Scholar
  45. 45.
    Palanivelu K, Kumar R (2001) Characterisation and leachability studies in textile effluent treatment plant sludge. Environ Pollut Control J 5(1):38–40Google Scholar
  46. 46.
    Ehrig H-J (1989) Leachate quality. In: Christensen TH, Cossu R, Stegmann R (eds) Sanitary landfilling: process, technology and environmental impact. Academic Press, London, pp 213–230Google Scholar
  47. 47.
    Bureau of Indian Standard (1992) Common burnt clay building bricks – specifications (fifth revision). BIS, New DelhiGoogle Scholar
  48. 48.
    Bureau of Indian Standard (2005) Methods of testing for cement masonry units- hollow bricks and solid blocks IS: 2185 (part-I). BIS, New DelhiGoogle Scholar
  49. 49.
    Bureau of Indian Standard (2005) Methods of testing for cement masonry units- hollow bricks and solid blocks IS: 2185 (part-II). BIS, New DelhiGoogle Scholar
  50. 50.
    Bureau of Indian Standard (1982) Specifications for soil based blocks used in general building construction IS: 1725. BIS, New DelhiGoogle Scholar
  51. 51.
    Bureau of Indian Standard (1982) Specifications for lime pozzolona concrete blocks for paving IS: 10360. BIS, New DelhiGoogle Scholar
  52. 52.
    Bureau of Indian Standard (1972) (Revised 2001) Methods of test for autoclaved cellular concrete products (Determination of unit weight or bulk density & moisture) Part 1,2,3,4,5,6 & 8. IS:6441Google Scholar
  53. 53.
    Trussell S, Spence RD (1994) A review of solidification/stabilization interferences. Waste Management, vol. 14, no. 6, pp. 507–519Google Scholar
  54. 54.
    Batchelor B, Overview of waste stabilization with cement, Waste Management (2006) 26:689–698Google Scholar
  55. 55.
    Thevenin G, Pera J Interactions between lead and different binders, Cem. Concr. Res. 29 (1999) 1605–1610.Google Scholar
  56. 56.
    Palomo A, Palacios M Alkali-activated cementitious materials: Alternative matrices for the immobilisation of hazardous wastes Part II. Stabilisation of chromium and lead, Cement and Concrete Research 33 (2003) 289–295Google Scholar
  57. 57.
    Conner J, Chemical fixation and solidification of hazardous waste, Van Nostrand Reinhold, New York, 1990.Google Scholar

Copyright information

© Springer-Verlag Berlin Heidelberg 2011

Authors and Affiliations

  1. 1.The Energy and Resources InstituteIndia Habitat CentreNew DelhiIndia
  2. 2.TERI UniversityNew DelhiIndia

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