Skip to main content

Coordination of Lewis Acids to Transition Metals: Z-Type Ligands

  • Chapter
  • First Online:

Part of the book series: Structure and Bonding ((STRUCTURE,volume 171))

Abstract

This chapter provides a comprehensive review of M→Z complexes, that is to say complexes featuring Lewis acids coordinated as σ-acceptor ligands. The preparation, structure and bonding, as well as the characteristic features of M→Z complexes are discussed. Only Lewis acids derived from the p-block elements are considered, with a focus on two-center M→Z interactions supported by donor sidearms. The chapter is organized according to (1) the nature of the Lewis acid moiety (based on group 13, 14, 15 or 16 elements), (2) the way the M→Z interaction is formed (by B–H activation of pro-ligands or direct coordination of preformed ambiphilic ligands) and (3) the type of complexes (M→Z interactions supported by 3, 2 or 1 donor sidearms, unsupported M→Z interactions).

This is a preview of subscription content, log in via an institution.

Buying options

Chapter
USD   29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD   259.00
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD   329.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD   329.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Learn about institutional subscriptions

Notes

  1. 1.

    For reviews on M→Z interactions, TM→borane complexes, and ambiphilic ligands, see [917].

  2. 2.

    M→Z interactions can be part of multicenter metal/ligand interactions as in the case of B–H bonds or BCn moieties; see [18] and [19].

  3. 3.

    A S-bridged dinuclear Pd complex is formed before addition of PMe3.

  4. 4.

    The 5-mercapto-1,2,4-triazolyl sidearm may coordinate through the N atom in β position to B, but only S-coordination was observed.

  5. 5.

    For a review on BCn multicenter coordination to TM, see [19].

  6. 6.

    The role of relativistic effects and spin-orbit coupling in M→Si interactions has been pointed out and analyzed thoroughly; see [128] and [129].

  7. 7.

    The geometry around P in phosphenium complexes can be trigonal planar or pyramidal. Planar phosphenium complexes feature MP bonds with double-bond character and can be assimilated to Fischer/Schrock-type carbene complexes. Pyramidal phosphenium complexes feature single MP bonds with a stereochemical active lone pair at P. Their bonding situation can correspond to phosphenium Z-type complexes or phosphido complexes without π(P→M) donation. The difference between the two resides in the nature of the σ interaction/bond between P and M.

  8. 8.

    For discussions on the description of M→Z complexes, see [101] and [157159].

References

  1. Shriver DF (1970) Acc Chem Res 3:231–238

    Article  CAS  Google Scholar 

  2. Pearson RG (1985) Chem Rev 85:41–49

    Article  CAS  Google Scholar 

  3. Angelici RJ (1995) Acc Chem Res 28:51–60

    Article  CAS  Google Scholar 

  4. King RB (1967) Adv Chem Ser 62:203–220

    Article  Google Scholar 

  5. Green MLH (1995) J Organomet Chem 500:127–148

    Article  CAS  Google Scholar 

  6. Burlitch JM, Leonowicz ME, Petersen RB, Hughes RE (1979) Inorg Chem 18:1097–1105

    Article  CAS  Google Scholar 

  7. Muir KW, Ibers JA (1969) Inorg Chem 8:1921–1928

    Article  CAS  Google Scholar 

  8. Hill AF, Owen GR, White AJP, Williams DJ (1999) Angew Chem Int Ed 38:2759–2761

    Article  CAS  Google Scholar 

  9. Kuzu I, Krummenacher I, Meyer J, Armbruster F, Breher F (2008) Dalton Trans 5836–5865

    Google Scholar 

  10. Fontaine FG, Boudreau J, Thibault MH (2008) Eur J Inorg Chem 2008:5439–5454

    Article  CAS  Google Scholar 

  11. Bouhadir G, Amgoune A, Bourissou D (2010) Adv Organomet Chem 58:1–106

    CAS  Google Scholar 

  12. Amgoune A, Bourissou D (2011) Chem Commun 47:859–871

    Article  CAS  Google Scholar 

  13. Braunschweig H, Dewhurst RD, Schneider A (2010) Chem Rev 110:3924–3957

    Article  CAS  Google Scholar 

  14. Braunschweig H, Dewhurst RD (2011) Dalton Trans 40:549–558

    Article  CAS  Google Scholar 

  15. Owen GR (2012) Chem Soc Rev 41:3535–3546

    Article  CAS  Google Scholar 

  16. Amgoune A, Bouhadir G, Bourissou D (2013) Top Curr Chem 334:281–311

    Article  Google Scholar 

  17. Kameo H, Nakazawa H (2013) Chem Asian J 8:1720–1734

    Article  CAS  Google Scholar 

  18. Pandey KK (2009) Coord Chem Rev 253:37–55

    Article  CAS  Google Scholar 

  19. Emslie DJH, Cowie BE, Kolpin KB (2012) Dalton Trans 41:1101–1117

    Article  CAS  Google Scholar 

  20. Bauer J, Braunschweig H, Dewhurst RD (2012) Chem Rev 112:4329–4346

    Article  CAS  Google Scholar 

  21. Braunschweig H, Gruss K, Radacki K (2007) Angew Chem Int Ed 46:7782–7784

    Article  CAS  Google Scholar 

  22. Braunschweig H, Gruss K, Radacki K (2008) Inorg Chem 47:8595–8597

    Article  CAS  Google Scholar 

  23. Bauer J, Braunschweig H, Brenner P, Kraft K, Radacki K, Schwab K (2010) Chem Eur J 16:11985–11992

    Article  CAS  Google Scholar 

  24. Bauer J, Braunschweig H, Damme A, Gruss K, Radacki K (2011) Chem Commun 47:12783–12785

    Article  CAS  Google Scholar 

  25. Bauer J, Bertermann R, Braunschweig H, Gruss K, Hupp F, Kramer T (2012) Inorg Chem 51:5617–5626

    Article  CAS  Google Scholar 

  26. Goedecke C, Hillebrecht P, Uhlemann T, Haunschild R, Frenking G (2009) Can J Chem 87:1470–1479

    Article  CAS  Google Scholar 

  27. Braunschweig H, Dewhurst RD, Hupp F, Kaufmann C, Phukan AK, Schneider C, Ye Q (2014) Chem Sci 5:4099–4104

    Article  CAS  Google Scholar 

  28. Bauer J, Braunschweig H, Radacki K (2012) Chem Commun 48:10407–10409

    Article  CAS  Google Scholar 

  29. Shriver DF (1963) J Am Chem Soc 85:3509–3510

    Article  CAS  Google Scholar 

  30. Johnson MP, Shriver DF (1966) J Am Chem Soc 88:301–304

    Article  CAS  Google Scholar 

  31. Scott RN, Shriver DF, Vaska L (1968) J Am Chem Soc 90:1079–1080

    Article  CAS  Google Scholar 

  32. Lehman DD, Shriver DF (1974) Inorg Chem 13:2203–2207

    Article  CAS  Google Scholar 

  33. Parshall GW (1964) J Am Chem Soc 86:361–364

    Article  CAS  Google Scholar 

  34. Braunschweig H, Wagner T (1994) Chem Ber 127:1613–1614

    Article  CAS  Google Scholar 

  35. Braunschweig H (1998) Angew Chem Int Ed 37:1786–1801

    Article  CAS  Google Scholar 

  36. Bauer J, Braunschweig H, Dewhurst RD, Radacki K (2013) Chem Eur J 19:8797–8805

    Article  CAS  Google Scholar 

  37. Braunschweig H, Radacki K, Rais D, Seeler F (2004) Organometallics 23:5545–5549

    Article  CAS  Google Scholar 

  38. Braunschweig H, Brenner P, Müller A, Radacki K, Rais D, Uttinger K (2007) Chem Eur J 13:7171–7176

    Article  CAS  Google Scholar 

  39. Bauer J, Braunschweig H, Kraft K, Radacki K (2011) Angew Chem Int Ed 50:10457–10460

    Article  CAS  Google Scholar 

  40. Braunschweig H, Fuss M, Radacki K, Uttinger K (2009) Z Anorg Allg Chem 635:208–210

    Article  CAS  Google Scholar 

  41. Kameo H, Sakaki S (2015) Chem Eur J 21:13588–13597

    Article  CAS  Google Scholar 

  42. Foreman MRS, Hill AF, Owen GR, White AJP, Williams DJ (2003) Organometallics 22:4446–4450

    Article  CAS  Google Scholar 

  43. Rudolf GC, Hamilton A, Orpen AG, Owen GR (2009) Chem Commun 553–555

    Google Scholar 

  44. Crossley IR, Foreman MRS, Hill AF, Owen GR, White AJP, Williams DJ, Willis AC (2008) Organometallics 27:381–386

    Article  CAS  Google Scholar 

  45. Foreman MRS, Hill AF, White P, Williams DJ (2004) Organometallics 23:913–916

    Article  CAS  Google Scholar 

  46. Figueroa JS, Melnick JG, Parkin G (2006) Inorg Chem 45:7056–7058

    Article  CAS  Google Scholar 

  47. Crossley IR, Foreman MRS, Hill AF, White AJP, Williams DJ (2005) Chem Commun 221–223

    Google Scholar 

  48. Crossley IR, Hill AF, Willis AC (2006) Organometallics 25:289–299

    Article  CAS  Google Scholar 

  49. Crossley IR, Hill AF, Humphrey ER, Willis AC (2005) Organometallics 24:4083–4086

    Article  CAS  Google Scholar 

  50. Landry VK, Melnick JG, Buccella D, Pang K, Ulichny JC, Parkin G (2006) Inorg Chem 45:2588–2597

    Article  CAS  Google Scholar 

  51. Lopez-Gomez MJ, Connelly NG, Haddow MF, Hamilton A, Orpen AG (2010) Dalton Trans 39:5221–5230

    Article  CAS  Google Scholar 

  52. Mihalcik DJ, White JL, Tanski JM, Zakharov LN, Yap GPA, Incarvito CD, Rheingold AL, Rabinovich D (2004) Dalton Trans 1626–1634

    Google Scholar 

  53. Crossley IR, Hill AF (2004) Organometallics 23:5656–5658

    Article  CAS  Google Scholar 

  54. Crossley IR, Hill AF, Willis AC (2008) Organometallics 27:312–315

    Article  CAS  Google Scholar 

  55. Crossley IR, Hill AF (2008) Dalton Trans 201–203

    Google Scholar 

  56. Pang K, Quan SM, Parkin G (2006) Chem Commun 5015–5017

    Google Scholar 

  57. Senda S, Ohki Y, Hirayama T, Toda D, Chen JL, Matsumoto T, Kawaguchi H, Tatsumi K (2006) Inorg Chem 45:9914–9925

    Article  CAS  Google Scholar 

  58. Pang K, Tanski JM, Parkin G (2008) Chem Commun 1008–1010

    Google Scholar 

  59. Crossley IR, Hill AF, Willis AC (2005) Organometallics 24:1062–1064

    Article  CAS  Google Scholar 

  60. Crossley IR, Hill AF, Willis AC (2010) Organometallics 29:326–336

    Article  CAS  Google Scholar 

  61. Blagg RJ, Charmant JPH, Connelly NG, Haddow MF, Orpen AG (2006) Chem Commun 2350–2352

    Google Scholar 

  62. Blagg RJ, Adams CJ, Charmant JPH, Connelly NG, Haddow MF, Hamilton A, Knight J, Orpen AG, Ridgway BM (2009) Dalton Trans 8724–8736

    Google Scholar 

  63. Owen GR, Hugh G, Charmant JPH, Hamilton A, Saithong S (2010) Dalton Trans 39:392–400

    Article  CAS  Google Scholar 

  64. Owen GR, Gould PH, Hamilton A, Tsoureas N (2010) Dalton Trans 39:49–52

    Article  CAS  Google Scholar 

  65. Zech A, Haddow MF, Othman H, Owen GR (2012) Organometallics 31:6753–6760

    Article  CAS  Google Scholar 

  66. Dyson G, Zech A, Rawe BW, Haddow MF, Hamilton A, Owen GR (2011) Organometallics 30:5844–5850

    Article  CAS  Google Scholar 

  67. Nuss G, Saischek G, Harum BN, Volpe M, Gatterer K, Belaj F, Mösch-Zanetti NC (2011) Inorg Chem 50:1991–2001

    Article  CAS  Google Scholar 

  68. Nuss G, Saischek G, Harum BN, Volpe M, Belaj F, Mösch-Zanetti NC (2011) Inorg Chem 50:12632–12640

    Article  CAS  Google Scholar 

  69. Anju RS, Roy DK, Mondal B, Yuvaraj K, Arivazhagan C, Saha K, Varghese B, Ghosh S (2014) Angew Chem Int Ed 53:2873–2877

    Article  CAS  Google Scholar 

  70. Roy DK, Mondal B, Anju RS, Ghosh S (2015) Chem Eur J 21:3640–3648

    Article  CAS  Google Scholar 

  71. Roy DK, De A, Panda S, Varghese B, Ghosh S (2015) Chem Eur J 21:13732–13738

    Article  CAS  Google Scholar 

  72. Tsoureas N, Haddow MF, Hamilton A, Owen GR (2009) Chem Commun 2538–2540

    Google Scholar 

  73. Tsoureas N, Hamilton A, Haddow MF, Harvey JN, Orpen AG, Owen GR (2013) Organometallics 32:2840–2856

    Article  CAS  Google Scholar 

  74. Tsoureas N, Bevis T, Butts CP, Hamilton A, Owen GR (2009) Organometallics 28:5222–5232

    Article  CAS  Google Scholar 

  75. Bontemps S, Bouhadir G, Gu W, Mercy M, Chen CH, Foxman B, Maron L, Ozerov O, Bourissou D (2008) Angew Chem Int Ed 47:1481–1484

    Article  CAS  Google Scholar 

  76. Sircoglou M, Bontemps S, Bouhadir G, Saffon N, Miqueu K, Gu W, Mercy M, Chen CH, Foxman BM, Maron L, Ozerov OV, Bourissou D (2008) J Am Chem Soc 130:16729–16738

    Article  CAS  Google Scholar 

  77. Sircoglou M, Saffon N, Miqueu K, Bouhadir G, Bourissou D (2013) Organometallics 32:6780–6784

    Article  CAS  Google Scholar 

  78. Sircoglou M, Mercy M, Saffon N, Coppel Y, Bouhadir G, Maron L, Bourissou D (2009) Angew Chem Int Ed 48:3454–3457

    Article  CAS  Google Scholar 

  79. Derrah EJ, Sircoglou M, Mercy M, Ladeira S, Bouhadir G, Miqueu K, Maron L, Bourissou D (2011) Organometallics 30:657–660

    Article  CAS  Google Scholar 

  80. Kameo H, Hashimoto Y, Nakazawa H (2012) Organometallics 31:3155–3162

    Article  CAS  Google Scholar 

  81. Kameo H, Hashimoto Y, Nakazawa H (2012) Organometallics 31:4251–4258

    Article  CAS  Google Scholar 

  82. Moret ME, Peters JC (2011) Angew Chem Int Ed 50:2063–2067

    Article  CAS  Google Scholar 

  83. Moret ME, Peters JC (2011) J Am Chem Soc 133:18118–18121

    Article  CAS  Google Scholar 

  84. Fong H, Moret ME, Lee Y, Peters JC (2013) Organometallics 32:3053–3062

    Article  CAS  Google Scholar 

  85. Anderson JS, Moret ME, Peters JC (2013) J Am Chem Soc 135:534–537

    Article  CAS  Google Scholar 

  86. Anderson JS, Cutsail GE, Rittle J, Connor BA, Gunderson WA, Zhang L, Hoffman BM, Peters JC (2015) J Am Chem Soc 137:7803–7809

    Article  CAS  Google Scholar 

  87. Comba P, Schiek W (2003) Coord Chem Rev 238–239:21–29

    Article  CAS  Google Scholar 

  88. Broda H, Tuczek F (2014) Angew Chem Int Ed 53:632–634

    Article  CAS  Google Scholar 

  89. Anderson JS, Rittle J, Peters JC (2013) Nature 501:84–87

    Article  CAS  Google Scholar 

  90. Suess DLM, Tsay C, Peters JC (2012) J Am Chem Soc 134:14158–14164

    Article  CAS  Google Scholar 

  91. Gunderson WA, Suess DLM, Fong H, Wang X, Hoffmann CM, Cutsail GE III, Peters JC, Hoffman BM (2014) J Am Chem Soc 136:14998–15009

    Article  CAS  Google Scholar 

  92. Del Castillo TJ, Thompson NB, Suess DLM, Ung G, Peters JC (2015) Inorg Chem 54:9256–9262

    Article  CAS  Google Scholar 

  93. Moret ME, Zhang L, Peters JC (2013) J Am Chem Soc 135:3792–3795

    Article  CAS  Google Scholar 

  94. Rudd PA, Liu S, Gagliardi L, Young VG, Lu CC (2011) J Am Chem Soc 133:2072

    Article  CAS  Google Scholar 

  95. Rudd PA, Planas N, Bill E, Gagliardi L, Lu CC (2013) Eur J Inorg Chem 2013:3898–3906

    Article  CAS  Google Scholar 

  96. Cammarota RC, Lu CC (2015) J Am Chem Soc 137:12486–12489

    Google Scholar 

  97. Bontemps S, Gornitzka H, Bouhadir G, Miqueu K, Bourissou D (2006) Angew Chem Int Ed 45:1611–1614

    Article  CAS  Google Scholar 

  98. Bontemps S, Sircoglou M, Bouhadir G, Puschmann H, Howard JAK, Dyer PW, Miqueu K, Bourissou D (2008) Chem Eur J 14:731–740

    Article  CAS  Google Scholar 

  99. Conifer CM, Law DJ, Sunley GJ, White AJP, Britovsek GJP (2011) Organometallics 30:4060–4066

    Article  CAS  Google Scholar 

  100. Kameo H, Nakazawa H (2012) Organometallics 31:7476–7484

    Article  CAS  Google Scholar 

  101. Sircoglou M, Bontemps S, Mercy M, Saffon N, Takahashi M, Bouhadir G, Maron L, Bourissou D (2007) Angew Chem Int Ed 46:8583–8586

    Article  CAS  Google Scholar 

  102. Inagaki F, Matsumoto C, Okada Y, Maruyama N, Mukai C (2015) Angew Chem Int Ed 54:818–822

    Article  CAS  Google Scholar 

  103. Sircoglou M, Bouhadir G, Saffon N, Miqueu K, Bourissou D (2008) Organometallics 27:1675–1678

    Article  CAS  Google Scholar 

  104. Sircoglou M, Bontemps S, Mercy M, Miqueu K, Ladeira S, Saffon N, Maron L, Bouhadir G, Bourissou D (2010) Inorg Chem 49:3983–3990

    Article  CAS  Google Scholar 

  105. Harman WH, Peters JC (2012) J Am Chem Soc 134:5080–5082

    Article  CAS  Google Scholar 

  106. Harman WH, Lin TP, Peters JC (2014) Angew Chem Int Ed 53:1081–1086

    Article  CAS  Google Scholar 

  107. Devillard M, Bouhadir G, Bourissou D (2015) Angew Chem Int Ed 54:730–732

    Article  CAS  Google Scholar 

  108. Schindler T, Lux M, Peters M, Scharf LT, Osseili H, Maron L, Tauchert ME (2015) Organometallics 34:1978–1984

    Article  CAS  Google Scholar 

  109. Suess DLM, Peters JC (2013) J Am Chem Soc 135:4938–4941

    Article  CAS  Google Scholar 

  110. Nesbit MA, Suess DLM, Peters JC (2015) Organometallics 34:4741–4752

    Article  CAS  Google Scholar 

  111. Suess DLM, Peters JC (2013) J Am Chem Soc 135:12580–12583

    Article  CAS  Google Scholar 

  112. Cowie BE, Emslie DJH (2014) Chem Eur J 20:16899–16912

    Article  CAS  Google Scholar 

  113. Cowie BE, Tsao FA, Emslie DJH (2015) Angew Chem Int Ed 54:2165–2169

    Article  CAS  Google Scholar 

  114. Bontemps S, Bouhadir G, Miqueu K, Bourissou D (2006) J Am Chem Soc 128:12056–12057

    Article  CAS  Google Scholar 

  115. Barnett BR, Moore CE, Rheingold AL, Figueroa JS (2014) J Am Chem Soc 136:10262–10265

    Article  CAS  Google Scholar 

  116. Devillard M, Nicolas E, Ehlers AW, Backs J, Mallet-Ladeira S, Bouhadir G, Slootweg JC, Uhl W, Bourissou D (2015) Chem Eur J 21:74–79

    Article  CAS  Google Scholar 

  117. Devillard M, Nicolas E, Appelt C, Backs J, Mallet-Ladeira S, Bouhadir G, Slootweg JC, Uhl W, Bourissou D (2014) Chem Commun 50:14805–14808

    Article  CAS  Google Scholar 

  118. Grobe J, Krummen N, Wehmschulte R, Krebs B, Laege M (1994) Z Anorg Allg Chem 620:1645–1658

    Article  CAS  Google Scholar 

  119. Grobe J, Wehmschulte R, Krebs B, Laege M (1995) Z Anorg Allg Chem 621:583–596

    Article  CAS  Google Scholar 

  120. Grobe J, Lutke-Brochtrup K, Krebs B, Lage M (2007) Z Naturforsch 62b:55–65

    Google Scholar 

  121. Gualco P, Lin TP, Sircoglou M, Mercy M, Ladeira S, Bouhadir G, Perez LM, Amgoune A, Maron L, Gabbai FP, Bourissou D (2009) Angew Chem Int Ed 48:9892–9895

    Article  CAS  Google Scholar 

  122. Gualco P, Mercy M, Ladeira S, Coppel Y, Maron L, Amgoune A, Bourissou D (2010) Chem Eur J 16:10808–10817

    Article  CAS  Google Scholar 

  123. Kameo H, Kawamoto T, Bourissou D, Sakaki S, Nakazawa H (2015) Organometallics 34:1440–1448

    Article  CAS  Google Scholar 

  124. Gualco P, Mallet-Ladeira S, Kameo H, Nakazawa H, Mercy M, Maron L, Amgoune A, Bourissou D (2015) Organometallics 34:1449–1453

    Article  CAS  Google Scholar 

  125. Wagler J, Brendler E (2010) Angew Chem Int Ed 49:624–627

    Article  CAS  Google Scholar 

  126. Wagler J, Hill AF, Heine T (2008) Eur J Inorg Chem 4225–4229

    Google Scholar 

  127. Brendler E, Wächtler E, Heine T, Zhechkov L, Langer T, Pöttgen R, Hill AF, Wagler J (2011) Angew Chem Int Ed 50:4696–4700

    Article  CAS  Google Scholar 

  128. Truflandier LA, Brendler E, Wagler J, Autschbach J (2011) Angew Chem Int Ed 50:255–259

    Article  CAS  Google Scholar 

  129. Autschbach J, Sutter K, Truflandier LA, Brendler E, Wagler J (2012) Chem Eur J 18:12803–12813

    Article  CAS  Google Scholar 

  130. Kano N, Yoshinari N, Shibata Y, Miyachi M, Kawashima T, Enomoto M, Okazawa A, Kojima N, Guo JD, Nagase S (2012) Organometallics 31:8059–8062

    Article  CAS  Google Scholar 

  131. Heitmann D, Pape T, Hepp A, Mück-Lichtenfeld C, Grimme S, Hahn FE (2011) J Am Chem Soc 133:11118–11120

    Article  CAS  Google Scholar 

  132. Braunschweig H, Damme A, Dewhurst RD, Hupp F, Jimenez-Halla JO, Radacki K (2012) Chem Commun 48:10410–10412

    Article  CAS  Google Scholar 

  133. Hupp F, Ma M, Kroll F, Jimenez-Halla JO, Dewhurst RD, Radacki K, Stasch A, Jones C, Braunschweig H (2014) Chem Eur J 20:16888–16898

    Article  CAS  Google Scholar 

  134. Braunschweig H, Celik MA, Dewhurst RD, Heid M, Hupp F, Sen SS (2015) Chem Sci 6:425–435

    Article  CAS  Google Scholar 

  135. Dalton DM, Rappe AK, Rovis T (2013) Chem Sci 4:2062–2070

    Article  CAS  Google Scholar 

  136. Tschersich C, Limberg C, Roggan S, Herwig C, Ernsting N, Kovalenko S, Mebs S (2012) Angew Chem Int Ed 51:4989–4992

    Article  CAS  Google Scholar 

  137. Lin TP, Ke IS, Gabbaï FP (2012) Angew Chem Int Ed 51:4985–4988

    Article  CAS  Google Scholar 

  138. Ke IS, Gabbaï FP (2013) Inorg Chem 52:7145–7151

    Article  CAS  Google Scholar 

  139. Wade CR, Gabbaï FP (2011) Angew Chem Int Ed 50:7369–7372

    Article  CAS  Google Scholar 

  140. Wade CR, Ke IS, Gabbai FP (2012) Angew Chem Int Ed 51:478–481

    Article  CAS  Google Scholar 

  141. Jones JS, Wade CR, Gabbaï FP (2015) Organometallics 34:2647–2654

    Article  CAS  Google Scholar 

  142. Ke IS, Jones JS, Gabbaï FP (2014) Angew Chem Int Ed 53:2633–2637

    Article  CAS  Google Scholar 

  143. Jones JS, Wade CR, Gabbaï FP (2014) Angew Chem Int Ed 53:8876–8879

    Article  CAS  Google Scholar 

  144. Rosenberg L (2012) Coord Chem Rev 256:606–626

    Article  CAS  Google Scholar 

  145. Hutchins LD, Duesler EN, Paine RT (1982) Organometallics 1:1254–1256

    Article  CAS  Google Scholar 

  146. Pan B, Xu Z, Bezpalko MW, Foxman BM, Thomas CM (2012) Inorg Chem 51:4170–4179

    Article  CAS  Google Scholar 

  147. Pan B, Bezpalko MW, Foxman BM, Thomas CM (2011) Organometallics 30:5560–5563

    Article  CAS  Google Scholar 

  148. Mingos DMP (1978) Transit Met Chem 3:1–15

    Article  CAS  Google Scholar 

  149. Ryan RR, Kubas GJ, Moody DC, Eller PG (1981) Struct Bond 46:47–100

    Article  CAS  Google Scholar 

  150. Hill AF (1994) Adv Organomet Chem 36:159–227

    CAS  Google Scholar 

  151. Mingos DM (2014) J Organomet Chem 751:153–173

    Article  CAS  Google Scholar 

  152. Mingos DM (2015) Coord Chem Rev 293–294:2–18

    Article  CAS  Google Scholar 

  153. Li J, Rogachev AY (2015) Phys Chem Chem Phys 17:1987–2000

    Article  CAS  Google Scholar 

  154. Albrecht M, Lutz M, Spek AL, van Koten G (2000) Nature 406:970–973

    Article  CAS  Google Scholar 

  155. Lin TP, Gabbaï FP (2012) J Am Chem Soc 134:12230–12238

    Article  CAS  Google Scholar 

  156. Lin TP, Gabbaï FP (2013) Angew Chem Int Ed 52:3864–3868

    Article  CAS  Google Scholar 

  157. Hill AF (2006) Organometallics 25:4741–4743

    Article  CAS  Google Scholar 

  158. Parkin G (2006) Organometallics 25:4744–4747

    Article  CAS  Google Scholar 

  159. Karen P (2015) Angew Chem Int Ed 54:4716–4726

    Article  CAS  Google Scholar 

  160. Pauling L (1948) J Chem Soc 1461–1467

    Google Scholar 

  161. Haaland A (1989) Angew Chem Int Ed Engl 28:992–1007

    Article  Google Scholar 

  162. Bouhadir G, Bourissou D (2015) Chem Soc Rev 45:1065–1079

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Didier Bourissou .

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2016 Springer-Verlag Berlin Heidelberg

About this chapter

Cite this chapter

Bouhadir, G., Bourissou, D. (2016). Coordination of Lewis Acids to Transition Metals: Z-Type Ligands. In: Mingos, D. (eds) The Chemical Bond III. Structure and Bonding, vol 171. Springer, Cham. https://doi.org/10.1007/430_2015_201

Download citation

Publish with us

Policies and ethics