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Fullerenes and Other Carbon-Rich Nanostructures pp 145–191Cite as

Dual Role of Phthalocyanines in Carbon Nanostructure-Based Organic Photovoltaics

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Part of the book series: Structure and Bonding ((STRUCTURE,volume 159))

Abstract

Organic solar cells are based on the photoinduced separation of charges at donor–acceptor interfaces and on the transport of these charges to the electrodes through n-type and p-type materials. Carbon nanostructures, such as fullerenes and carbon nanotubes, are considered to be the most effective electron-acceptors, and their use is widely spread. Besides, proper electron-donor and light-harvesting molecules are also fundamental for organic photovoltaics. Phthalocyanines are excellent candidates to play the dual role of p-type materials and antennas. Moreover, their structural and synthetic versatility allows them to act as donors or acceptors depending on their counterpart materials in the device. Herein, such functional dualities will be reviewed with regard to the use of phthalocyanines in donor/acceptor systems for photovoltaic devices.

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Acknowledgment

This work has been supported by the Spanish MICINN and MEC (CTQ2011-24187/BQU and CONSOLIDER INGENIO 2010, CSD2007-00010 Nanociencia Molecular), and the Comunidad de Madrid (MADRISOLAR-2, S2009/PPQ/1533).

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  1. Departamento de Química Orgánica, Facultad de Ciencias, Universidad Autónoma de Madrid, Cantoblanco, 28049, Madrid, Spain

    Andrés de la Escosura, Olga Trukhina & Tomás Torres

  2. IMDEA-Nanociencia, Cantoblanco, 28049, Madrid, Spain

    Olga Trukhina & Tomás Torres

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  1. Andrés de la Escosura
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  2. Olga Trukhina
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  3. Tomás Torres
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Correspondence to Tomás Torres .

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  1. Ecole Européenne de Chimie, Polymères et Matériaux (ECPM), Université de Strasbourg et CNRS, Strasbourg Cedex 2, France

    Jean-François Nierengarten

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de la Escosura, A., Trukhina, O., Torres, T. (2013). Dual Role of Phthalocyanines in Carbon Nanostructure-Based Organic Photovoltaics. In: Nierengarten, JF. (eds) Fullerenes and Other Carbon-Rich Nanostructures. Structure and Bonding, vol 159. Springer, Berlin, Heidelberg. https://doi.org/10.1007/430_2013_113

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