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Self- or Induced Organization of [60]Fullerene Hexakisadducts

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Fullerenes and Other Carbon-Rich Nanostructures

Part of the book series: Structure and Bonding ((STRUCTURE,volume 159))

Abstract

In the past few years, much attention has been devoted to the development of C60 multiadducts for high-added value materials. C60 fullerene can be considered as a versatile hard nanocore for globular systems due to its tuneable valency (1 to 6 based on cyclopropanation derivatization) and regioselective polyaddition. Therefore, hexakisadducts of C60 are becoming an important class of carbon-based macromolecules as they offer wider possibilities for structural variations than any other organic (or inorganic) scaffolds. For example, several types of molecular geometries can be designed and controlled, thanks to regioselective functionalization methodologies. This in turn leads to new building blocks for defined supramolecular organizations. In this review, an overview of the relationships between molecular architecture and self- or induced organization of C60 hexakisadducts is provided. This includes a description of thin films, liquid-crystalline mesophases, and nanospheres formed by such carbonaceous systems.

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Acknowledgments

I would like to thank, in particular, Drs. J.-L. Gallani and B. Donnio for many discussions. I would also like to thank my research colleagues, Drs. B. Heinrich, C. Bourgogne, D. Guillon for their collaboration, and N. Beyer, E. Couzigné and E. Voirin for their technical assistance.

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  1. Institut de Physique et Chimie des Matériaux de Strasbourg, UMR CNRS/UdS 7504, 23 rue du Loess BP 43, 67034, Strasbourg, France

    Delphine Felder-Flesch

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Correspondence to Delphine Felder-Flesch .

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  1. Ecole Européenne de Chimie, Polymères et Matériaux (ECPM), Université de Strasbourg et CNRS, Strasbourg Cedex 2, France

    Jean-François Nierengarten

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Felder-Flesch, D. (2013). Self- or Induced Organization of [60]Fullerene Hexakisadducts. In: Nierengarten, JF. (eds) Fullerenes and Other Carbon-Rich Nanostructures. Structure and Bonding, vol 159. Springer, Berlin, Heidelberg. https://doi.org/10.1007/430_2013_111

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